3M-9001X-9002X-9003X-9004X-Respirators.pdf

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SECTION Hazard modified SECTION Applicable information MATERIAL SAFETY DATA
3M MATERIAL SAFETY DATA SHEET  3M 9001X, 9002X, 9003X,  9004X  RESPIRATORS      02/08/2006
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Material Safety Data Sheet
Copyright, 2006, 3M Company.  All rights reserved.  Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
This material safety data sheet (MSDS) is provided as a courtesy in response to a customer request.  This product is not regulated
under, and a MSDS is not required for this product by the OSHA Hazard Communication Standard (29 CFR 1910.1200) because,
when used as recommended or under ordinary conditions, it should not present a health and safety hazard.  However, use or
processing of the product not in accordance with the product's recommendations or not under ordinary conditions may affect the
performance of the product and may present potential health and safety hazards.
 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME:
 3M 9001X, 9002X, 9003X,  9004X  RESPIRATORS
MANUFACTURER:
 3M
DIVISION:
 Occupational Health & Environ. Safety
ADDRESS:
 3M Center
 St. Paul, MN  55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date:
 02/08/2006
Supercedes Date:
 02/03/2003
Document Group:
 11-8839-0
Product Use:
Intended Use:
Respiratory Protection
 SECTION 2: INGREDIENTS
Ingredient
C.A.S. No.
% by Wt
 POLYPROPYLENE
 Unknown
   45 -  85
 POLYISOPRENE
 Unknown
   14 -  26
 ALUMINUM
 Unknown
   5 -  15
 CADMIUM-FREE STEEL
 Unknown
   5 -  10
 TITANIUM DIOXIDE
 Unknown
  < 1
 ETHYLENE-ACRYLIC ACID POLYMER
 Unknown
  < 1
 ACRYLONITRILE-BUTANIDIENE POLYMER
 Unknown
  < 1
  
 SECTION 3: HAZARDS IDENTIFICATION
3.1  EMERGENCY OVERVIEW
Odor, Color, Grade:   Bi-fold, non-woven material, white, with aluminum noseclip and white headbands. No odor.
3M MATERIAL SAFETY DATA SHEET  3M 9001X, 9002X, 9003X,  9004X  RESPIRATORS      02/08/2006
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General Physical Form:  Solid
Immediate health, physical, and environmental hazards:                           This product, when used under reasonable conditions and
in accordance with the 3M directions for use, should not present a health hazard. However, use or processing of the product in a
manner not in accordance with the product's directions for use may affect the performance of the product and may present potential
health and safety hazards.
3.2  POTENTIAL HEALTH EFFECTS
Eye Contact:
No health effects are expected.
Skin Contact:
No health effects are expected.
Inhalation:
No health effects are expected.
Ingestion:
No health effects are expected.
 
3.3    POTENTIAL ENVIRONMENTAL EFFECTS
 Not determined.
 SECTION 4:  FIRST AID MEASURES
4.1   FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact:          No need for first aid is anticipated.
Skin Contact:           No need for first aid is anticipated.
Inhalation:          No need for first aid is anticipated.
If Swallowed:            No need for first aid is anticipated.            
 SECTION 5: FIRE FIGHTING MEASURES
5.1   FLAMMABLE PROPERTIES
 Autoignition temperature
 Not Applicable
 Flash Point
 Not Applicable
 Flammable Limits - LEL
 Not Applicable
 Flammable Limits - UEL
 Not Applicable
3M MATERIAL SAFETY DATA SHEET  3M 9001X, 9002X, 9003X,  9004X  RESPIRATORS      02/08/2006
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5.2   EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3   PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures:     Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards:     Not applicable.  No unusual fire or explosion hazards are anticipated.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
 SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Not applicable.
 SECTION 7: HANDLING AND STORAGE
7.1   HANDLING
This product is considered to be an article which does not release or otherwise result in exposure to a hazardous chemical under
normal use conditions.
7.2   STORAGE
Not applicable.
 SECTION 8:  EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1   ENGINEERING CONTROLS
Not applicable.
8.2   PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1   Eye/Face Protection
Not applicable.
8.2.2   Skin Protection
Not applicable.
8.2.3   Respiratory Protection
Not applicable.
8.2.4   Prevention of Swallowing
Not applicable.
8.3   EXPOSURE GUIDELINES
3M MATERIAL SAFETY DATA SHEET  3M 9001X, 9002X, 9003X,  9004X  RESPIRATORS      02/08/2006
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None Established
 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
 Odor, Color, Grade:
 Bi-fold, non-woven material, white, with aluminum noseclip and
white headbands. No odor.
 General Physical Form:
 Solid
 Autoignition temperature
 Not Applicable
 Flash Point
 Not Applicable
 Flammable Limits - LEL
 Not Applicable
 Flammable Limits - UEL
 Not Applicable
 Boiling point
 Not Applicable
 Density
 Not Applicable
 Vapor Density
 Not Applicable
 Vapor Pressure
 Not Applicable
 Specific Gravity
 pH
 Not Applicable
 Melting point
 No Data Available
 Solubility In Water
 Not Applicable
 Evaporation rate
 Not Applicable
 Volatile Organic Compounds
 Not Applicable
 Percent volatile
 Not Applicable
 VOC Less H2O & Exempt Solvents
 Not Applicable
 Viscosity
 Not Applicable
 SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid:  None known
Hazardous Polymerization:  Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance
Condition
 Aldehydes
 Not Specified
 Hydrocarbons
 Not Specified
 Methane
 Not Specified
 Carbon monoxide
 Not Specified
 Carbon dioxide
 Not Specified
 Ketones
 Not Specified
 Toxic Vapor, Gas, Particulate
 Not Specified
Hazardous Decomposition:  Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous
decomposition products may occur as a result of oxidation, heating, or reaction with another material.
3M MATERIAL SAFETY DATA SHEET  3M 9001X, 9002X, 9003X,  9004X  RESPIRATORS      02/08/2006
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 SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
 SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not applicable.
CHEMICAL FATE INFORMATION
Not applicable.
 SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method:  Reclaim if feasible.   Dispose of used product by the same method as recommended for the disposal of the
substance the respirator was used for.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
 SECTION 14:TRANSPORT INFORMATION
ID Number(s):
78-8124-1732-3,  78-8124-1736-4,  MT-9001-1947-0,  XC-0038-1083-2,  XC-0038-1084-0,  XC-0038-1086-5,  XC-0038-1087-3
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
 SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
 Contact 3M for more information.
311/312 Hazard Categories:
  Fire Hazard - No    Pressure Hazard - No    Reactivity Hazard - No     Immediate Hazard - No    Delayed Hazard - No
    
STATE REGULATIONS
 Contact 3M for more information.
3M MATERIAL SAFETY DATA SHEET  3M 9001X, 9002X, 9003X,  9004X  RESPIRATORS      02/08/2006
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CHEMICAL INVENTORIES
This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.
Contact 3M for more information.
 
INTERNATIONAL REGULATIONS
Contact 3M for more information.
      
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
 SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
 Health:  0    Flammability:  1     Reactivity:  0    Special Hazards:  None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
     
Revision Changes:
Section 16: NFPA hazard classification heading was modified.
Section 3: Potential environmental effects heading was modified.
Copyright was modified.
Section 3: Potential effects from skin contact information was modified.
Section 5: Fire fighting procedures information was modified.
Section 5: Unusual fire and explosion hazard information was modified.
Section 15: 311/312 hazard categories heading was modified.
Section 15: International regulations information was modified.
Section 15: State regulations information was modified.
Section 15: US federal regulations information was modified.
Section 10: Hazardous polymerization heading was modified.
Section 2: Ingredient table was modified.
Section 16: NFPA explanation was modified.
Section 15: Inventories information was modified.
Article disclaimer text (following the copyright) was modified.
Section 12: Ecotoxicological information heading was modified.
Section 12: Chemical fate information heading was modified.
Section 16: NFPA hazard classification for special hazards was modified.
Section 8: Exposure guidelines information - none - was modified.
Section 10: Hazardous decompostion heading was modified.
3M MATERIAL SAFETY DATA SHEET  3M 9001X, 9002X, 9003X,  9004X  RESPIRATORS      02/08/2006
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Section 12: Ecotoxicological phrase was modified.
Section 12: Chemical Fate phrase was modified.
Section 2: Ingredient phrase was added.
Section 4: First aid for skin contact - medical assistance - was deleted.
Section 3: Immediate other hazard(s) comment was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued.  3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE.  User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application.  Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.  Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
 3M MSDSs are available at www.3M.com