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DOW CORNING CORPORATION Material Safety Data Sheet Page: 1 of 6 Version: 1.5 Revision Date: 2006/03/01 DOW CORNING(R) 4 ELECTRICAL INSULATING COMPOUND 1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY MSDS No.: 01903128 SUPPLIER: Dow Corning Canada Inc. 15-6400 Millcreek Drive, Suite 416 Mississauga, ON, Canada L5N 3E7 Prepared by Hazard Communication: CANUTEC: (800) 248-2481 (613) 996-6666 MANUFACTURER: Dow Corning Corporation South Saginaw Road Midland, Michigan 48686 24 Hour Emergency Telephone: (989) 496-5900 WHMIS CLASSIFICATION: Class D, Division 2, Subdivision A. Material Usage: Semiconductor coating 2. COMPOSITION / INFORMATION ON INGREDIENTS CAS Number Wt % Component Name 7631-86-9 7.0 - 13.0 Silica, amorphous 10043-35-3 0.1 - 1.0 Boric acid The ingredients listed above are controlled products as defined in CPR, am. SOR/88-555. 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Generic Description: Inorganic compound Physical Form: Grease Colour: Translucent white Odour: Very little ++++++++++++++++++++++++++++++++++++++++++++ POTENTIAL HEALTH EFFECTS Acute Effects Eye: Direct contact may cause temporary redness and discomfort. Skin: No significant irritation expected from a single short-term exposure. DOW CORNING CORPORATION Material Safety Data Sheet Page: 2 of 6 Version: 1.5 Revision Date: 2006/03/01 DOW CORNING(R) 4 ELECTRICAL INSULATING COMPOUND Inhalation: No significant effects expected from a single short-term exposure. Oral: Low ingestion hazard in normal use. Prolonged/Repeated Exposure Effects Skin: No known applicable information. Inhalation: No known applicable information. Oral: No known applicable information. Signs and Symptoms of Overexposure No known applicable information. Medical Conditions Aggravated by Exposure No known applicable information. The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions, component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information. 4. FIRST AID MEASURES Eye: Immediately flush with water. Skin: No first aid should be needed. Inhalation: No first aid should be needed. Oral: No first aid should be needed. Comments: Treat symptomatically. 5. FIRE FIGHTING MEASURES Flash Point: 212 °F / 100 °C (Closed Cup) Autoignition Temperature: Not available. Flammability Limits in Air: Not available. Extinguishing Media: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire exposed containers. Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool. DOW CORNING CORPORATION Material Safety Data Sheet Page: 3 of 6 Version: 1.5 Revision Date: 2006/03/01 DOW CORNING(R) 4 ELECTRICAL INSULATING COMPOUND Unusual Fire Hazards: None. Hazardous Decomposition Products Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Hydrogen. Formaldehyde. 6. ACCIDENTAL RELEASE MEASURES Containment/Clean up: Observe all personal protection equipment recommendations described in Sections 5 and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since spilled materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Local, provincial, federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. Note: See section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is required. 7. HANDLING AND STORAGE Use with adequate ventilation. Avoid eye contact. Use reasonable care and store away from oxidizing materials. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits Consult local authorities for acceptable provincial values. CAS Number Component Name Exposure Limits 7631-86-9 Silica, amorphous OSHA PEL (final rule): TWA 80mg/m3/%SiO2. NIOSH REL: TWA 6mg/m3. 10043-35-3 Boric acid ACGIH TLV: TWA 2 mg/m3 inhalable fraction, STEL 6 mg/m3 inhalable fraction. LD50: 3,450 mg/kg - Oral Mouse Engineering Controls Local Ventilation: None should be needed. General Ventilation: Recommended. DOW CORNING CORPORATION Material Safety Data Sheet Page: 4 of 6 Version: 1.5 Revision Date: 2006/03/01 DOW CORNING(R) 4 ELECTRICAL INSULATING COMPOUND Personal Protective Equipment for Routine Handling Eyes: Use proper protection - safety glasses as a minimum. Skin: Washing at mealtime and end of shift is adequate. Suitable Gloves: No special protection needed. Inhalation: No respiratory protection should be needed. Suitable Respirator: None should be needed. Personal Protective Equipment for Spills Eyes: Use proper protection - safety glasses as a minimum. Skin: Washing at mealtime and end of shift is adequate. Inhalation/Suitable Respirator: No respiratory protection should be needed. Precautionary Measures: Avoid eye contact. Use reasonable care. Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Grease Color: Translucent white Odor: Very little Odor Threshold: Not available. Specific Gravity @ 25°C: > 1 Viscosity: Not available. Freezing/Melting Point: Not available. Boiling Point: Not available. Vapor Pressure @ 25°C: Not available. Vapor Density: Not available. Evaporation Rate: Not available. Solubility in Water: Not available. Coefficient of Water/Oil Distribution: Not available. pH: Not available. Volatile Content: Not available. Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing specifications. 10. STABILITY AND REACTIVITY Chemical Stability: Stable. DOW CORNING CORPORATION Material Safety Data Sheet Page: 5 of 6 Version: 1.5 Revision Date: 2006/03/01 DOW CORNING(R) 4 ELECTRICAL INSULATING COMPOUND Hazardous Polymerization: Hazardous polymerization will not occur. Conditions to Avoid: None. Materials to Avoid: Oxidizing material can cause a reaction. 11. TOXICOLOGICAL INFORMATION Special Hazard Information on Components Reproductive Effects CAS Number Wt % Component Name 10043-35-3 0.1 - 1.0 Boric acid Evidence of reproductive effects in laboratory animals. 12. ECOLOGICAL INFORMATION Environmental Fate and Distribution Complete information is not yet available. Environmental Effects Complete information is not yet available. Fate and Effects in Waste Water Treatment Plants Complete information is not yet available. Ecotoxicity Classification Criteria Hazard Parameters (LC50 or EC50) High Medium Low Acute Aquatic Toxicity (mg/L) <=1 >1 and <=100 >100 Acute Terrestrial Toxicity <=100 >100 and <= 2000 >2000 This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993. This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the section concerning the overall ecological safety of this material. 13. DISPOSAL CONSIDERATIONS Can be incinerated in accordance with local regulations. Call local hazardous waste disposal company or provincial waste authorities for more information. 14. TRANSPORT INFORMATION DOW CORNING CORPORATION Material Safety Data Sheet Page: 6 of 6 Version: 1.5 Revision Date: 2006/03/01 DOW CORNING(R) 4 ELECTRICAL INSULATING COMPOUND Canada Road (Based on IMDG Regulations) Not subject to local road regulations. Ocean Shipment (IMDG) Not subject to IMDG code. Air Shipment (IATA) Not subject to IATA regulations. 15. REGULATORY INFORMATION This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR. WHMIS CLASSIFICATION: Class D, Division 2, Subdivision A. DSL STATUS: All chemical substances in this material are included on or exempted from the DSL. 16. OTHER INFORMATION Prepared by: Dow Corning Corporation These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. (R) indicates Registered Trademark