EN7276.pdf

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Sodium Azide hazard Product Effects critical hazard significant Effects Milli Q water waste Cell Enrichment Kit EasySep Cell Enrichment
Conforms to 93/112/EC and ISO 11014-1
Material Safety Data Sheet
EasySep® Cell Enrichment Kits
7276
CS003 CS004 CS005 CS006 CS007 CS008 CS009 CS010 CS011 1859821 1859822 1859823
1859824 1859825 1859826 1859861 1859862 1859863 1859864 1859865 1859866 1859867 1859868
1859869 1859870 1859871 1859880 1859881 1859882
CHEMTREC:
800.424.9300
OUTSIDE US:
202.483.7616
8/4/2005
8/23/2005
Product name
Supplier
Manufacturer
Product No.
MSDS#
Validation Date
Print Date
In Case of Emergency
Section 1. Chemical Product and Company Identification
Responsible Name Company2
Synonyms Kit Contents:
Human Cell Negative Selection Enrichment Cocktail
Magnetic Nanoparticles
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
Eng
In USA: 
 In Europe:
Pierce 
 Perbio Science
P.O. Box 117 
 Industriezone III
Rockford, IL 61105  Industrielaan 27
USA 
 9320 Erembodegem-Aalst
815.968.0747 or
 Belgium
1.800.874.3723
 Tel:+32 53 83 44 04
 
 Fax:+32 53 83 76 38
Pierce Biotechnology
P.O. Box 117
Rockford, IL 61105
USA
815.968.0747 or
1.800.874.3723
Substance/Preparation
Preparation
:
Section 2. Composition, Information on Ingredients
CAS number
Ingredient name
%
EC number
Classification
Monoclonal Antibodies
--
--
--
Magnetic nanoparticles
--
--
--
Sodium Azide
26628-22-8
0.09
247-852-1
T+; R28
R32
N; R50/53
Inhalation.  Ingestion.
Emergency Overview
Section 3. Hazards Identification
Routes of Entry
Carcinogenic Effects Data
Not applicable.
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
Review the most current and approved institutional guideline, protocol, standard operating procedure(s) and MSDS(s)
for the proper handling of institutional materials/equipment associated with the use of this product.
No specific hazard.
Not applicable.
United States
Potential acute health effects
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Eyes
Skin
Inhalation
Ingestion
Potential chronic health effects
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Physical/chemical hazards
Human health hazards
Environmental hazards Not applicable.
Not applicable.
Not applicable.
Medical Conditions Aggravated
by Overexposure:
Repeated or prolonged exposure is not known to aggravate medical condition.
Not available.
Overexposure /Signs/Symptoms
See Toxicological Information (section 11)
Classification Not classified.
Europe
Do NOT induce vomiting unless directed to do so by medical personnel.  Never give anything by mouth to an unconscious
person.  Get medical attention if symptoms appear.
Skin Contact
Ingestion
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.  Get medical attention if irritation
occurs.
In case of contact, immediately flush skin with plenty of water.  Remove contaminated clothing and shoes.  Wash clothing
before reuse.  Thoroughly clean shoes before reuse.  Get medical attention.
Slightly hazardous in case of inhalation (lung irritant).  Non-sensitizer for lungs.
Slightly hazardous in case of ingestion.
Slightly hazardous in case of skin contact (irritant, sensitizer).  Skin inflammation is characterized by itching, scaling,
reddening, or, occasionally, blistering.
Skin Contact
Slightly hazardous in case of eye contact (irritant).
Eye Contact
Inhalation
Aggravating conditions Repeated or prolonged exposure is not known to aggravate medical condition.
First-Aid Measures
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.  Get medical attention if irritation
occurs.
Notes to Physician Not available.
Not available.
Protection of first-aiders
Ingestion
Effects and symptoms
Inhalation
Eye Contact
Section 4. First Aid Measures
Hazardous thermal (de)composition
products
Not applicable.
Non-flammable.
Not applicable.
Use an extinguishing agent suitable for surrounding fires.
Not applicable.
Section 5. Fire Fighting Measures
Flammability of the Product
Flash Points
Fire Hazards in Presence of Various
Substances
Fire Fighting Media
and Instructions
Not applicable.
Protective Clothing (Fire)
Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Section 6. Accidental Release Measures
Small Spill and Leak Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Environmental Precautions and
Clean-up Methods
Personal precautions Safety glasses.  Lab coat.  Vapor respirator.  Be sure to use an approved/certified respirator or equivalent.  Gloves.
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Keep container tightly closed.  Keep container in a cool, well-ventilated area.
Wash thoroughly after handling.
Section 7. Handling and Storage
Handling
Storage
Suitable /  Not suitable
Packaging materials
Use original container.
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
Sodium Azide
ACGIH (United States, 0/2000).
  CEIL: 0.11 ppm
OSHA (United States, 0/1989).  Skin
  TWA: 0.1 ppm
  CEIL: 0.1 ppm
NIOSH (United States, 0/1994).  Skin
  TWA: 0.3 ppm
  CEIL: 0.1 ppm
United States
Ingredient Name
Occupational Exposure Limits
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective occupational exposure limits.
Section 8. Exposure Controls/Personal Protection
Exposure Limit Values
Personal Protection
Eyes
Body
Protective Clothing
(Pictograms)
Safety glasses.
Lab coat.
The lowest known value is 100°C (212°F) (Milli-Q Water).
Liquid.
7.2 to 7.6 [Neutral.]
May start to solidify at 0°C (32°F) based on data for: Milli-Q Water.
The only known value is 1 (Water = 1) (Milli-Q Water).
The highest known value is 0.62  (Air = 1)  (Milli-Q Water).
The highest known value is 2.3 kPa (17.5 mm Hg) (at 20°C) (Milli-Q Water).
See solubility in water.
Easily soluble in cold water, hot water.
Not applicable.
Not available.
Not available.
Clear.
Boiling/Condensation Point
Melting/Freezing Point
0.36 (Milli-Q Water) compared to Butyl acetate.
Physical State  and
Appearance
Molecular Weight
pH (1% Soln/Water)
Specific Gravity
Vapor Pressure
Vapor Density
Evaporation Rate
Dispersion Properties
Solubility
Odor
Taste
Color
Section 9. Physical and Chemical Properties
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The product is stable.
Not available.
Will not occur.
Sodium azide may react with lead or copper plumbing to form highly explosive metal azides.  (Sodium Azide)
Section 10. Stability and Reactivity
Stability and Reactivity
Conditions to avoid
Materials to avoid
Hazardous Polymerization
Hazardous Decomposition
Products
Not available.
Milli-Q Water:
  ORAL (LD50):
Acute:  >90000 mg/kg [Rat].
Sodium Azide:
  ORAL (LD50):
Acute:  27 mg/kg [Rat].  27 mg/kg [Mouse].
  DERMAL (LD50):
Acute:  20 mg/kg [Rabbit].
Slightly hazardous in case of eye contact (irritant), of ingestion, of inhalation (lung irritant).
Non-hazardous in case of ingestion.  Non-corrosive to the eyes.  Non-corrosive for lungs.
Not available.
Not available.
Not available.
Not available.
Section 11. Toxicological Information
Toxicity to Animals
Chronic Effects on Humans
Other Toxic Effects on Humans
Special Remarks on Toxicity to
Animals
Special Remarks on Chronic
Effects on Humans
Special Remarks on Other Toxic
Effects on Humans
Skin
Ingestion
Inhalation No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Over-exposure
signs/symptoms
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Mutagenicity
No known significant effects or critical hazards.
Reproductive toxicity
Ecotoxicity Not available.
Mobility
Germany water class
Not available.
Not available.
Not available.
Persistence/degradability
Bioaccumulative potential
VCI WGK: No products were found.
Section 12. Ecological Information
Species
Period
Ecotoxicity data
Ingredient name
Persistence/degradability
Other ecological information
Ingredient name
BOD5
COD
Ingredient name
Aquatic half-life
Photolysis
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Mobility
Not available.
:
LogPow
BCF
Bioaccumulative potential
Other adverse effects
: No known significant effects or critical hazards.
Ingredient name
Not available.
Waste Stream
Section 13. Disposal Considerations
Denmark – Carcinogenic waste Not available.
Not available.
Sweden - thermoset plastic
waste
Not available.
European waste catalogue
(EWC)
To present knowledge of the supplier, this product is not regarded as hazardous waste as defined
by EU Directive 91/689/EC.
Hazardous waste
Austria  -  Waste catalogue Not available.
Denmark  -  Waste card number Not available.
Denmark  -  Waste group Not available.
Sweden  -  Waste group Not available.
Norway  -  Waste number Not available.
Switzerland  -  Waste code Not available.
The generation of waste should be avoided or minimized wherever possible.  Avoid dispersal of
spilled material and runoff and contact with soil, waterways, drains and sewers.  Disposal of this
product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements.
Methods of disposal
Norway  - Hazardous waste To present knowledge of the supplier, this product is not regarded as hazardous waste as defined
by SFT’s Directive on special waste.
Contact the supplier for all information regarding the proper transportation method for this material.
Section 14. Transport Information
U.S. Federal Regulations
--
HCS Classification
Section 15. Regulatory Information
TSCA 8(b) inventory: Sodium Azide; Milli-Q Water
TSCA 8(d) H and S data reporting: Sodium Azide
Clean Water Act (CWA) 307: No products were found.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found.
This product is not classified according to the EU regulations.
Label Requirements
(Europe)
1
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Pennsylvania RTK: Sodium Azide: (environmental hazard, generic environmental hazard)
Florida: Sodium Azide
Minnesota: Sodium Azide
Massachusetts RTK: Sodium Azide
New Jersey: Sodium Azide
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
State Regulations
CEPA DSL: Sodium Azide; Milli-Q Water
CEPA NDSL: Sodium Azide
Australia (NICNAS): Sodium Azide; Milli-Q Water
Germany water class: Sodium Azide
Japan (METI): Sodium Azide; Milli-Q Water
Korea (TCCL): Sodium Azide; Milli-Q Water
Philippines (RA6969): Sodium Azide; Milli-Q Water
WHMIS (Canada) Not controlled under WHMIS (Canada).
This product is not classified according to the EU regulations.
DSCL (EEC)
International Regulations
Not available.
EINECS
International Lists
Pennsylvania RTK: Sodium Azide: (environmental hazard, generic environmental hazard)
Florida: Sodium Azide
Minnesota: Sodium Azide
Massachusetts RTK: Sodium Azide
New Jersey: Sodium Azide
State regulations
Version
0.03
Date of Previous Issue No Previous
Validation
Not available.
Section 16. Other Information
References
Validated by Company2 on 8/4/2005.
Verified by Company2.
Printed 8/23/2005.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate.  However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and
should be used with caution.  Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
Hazardous Material
Information System
(U.S.A.)
National Fire Protection
Association (U.S.A.)
History of Document Changes Any information changes since last document version are marked with a triangle symbol.
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
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Fire hazard
Reactivity
Personal protection
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Instability
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