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(I) 2012-13 12 Paper Code 15 D C , B , A - Note:- You have four choices for each objective type question as A, B, C and D. The choice which you think is correct; fill that circle in front of that question number. Use marker or pen to fill the circles. Cutting or filling two or more circles will result in zero mark in that question. ( D ) ( C ) ( B ) ( A ) QUESTIONS S.No 0.24 0.21 0.18 0.15 The number of CO2 8 moles in 8 grams of CO2 is equivlent to: 1 C2H5OH CH3OH C12H22O4 C6H12O6 CH2O CH2O is the empirical formula of: 2 32 18 8 2 N-Shell The maximum electrons in N-shell are: 3 Sr Hg Li Zn The lightest metal at room temperature is: 4 + 3 + 2 + 1 Zero The 18 Oxidation states of group 18 elements are 5 Five Four Three Two The number C2H2 of covalent bonds in C2H2 molecule are: 6 Nitrogen Hydrogen Boron Flourine A dative bond is formed between ammonia and Boron triflourides, the donor atom is: 7 10.3 gcm-3 19.3 gcm-3 7.86 gcm-3 2.70 gcm-3 The density of gold is: 8 Methyl alcohol Water Liquid Ammonia C2H5OH The universal solvent in the following is: 9 +7 +5 +3 +1 HNO3 The oxidation state of Nitrogen in HNO3 is: 10 Which of the following is reduction reaction? 11 Magnesium Potassium Silver Gold The most reactive metal reactive metal among the following is: 12 (I) 2012-13 63 2.45 Part ------------------------ I 2. Answer briefly any FIVE parts from the following 5x2=10 2 Relative atomic mass C-12 (i) (i) Define relative atomic mass based on C-12 scale. (ii) Calculate the formula mass of Potassium Sulphate. (ii) The atomic mass of elements are; K = 39 amu, S = 32 amu, O = 16 amu (iii) Differentiate between molecule and molecular ion. (iii) (iv) State four uses of isotope. (iv) (v) Differentiate between shell and sub shell. (v) (vi) Write the reaction of chlorine with hydrogen and water. (vi) (vii) Compare two physical properties of metals and non-metals. (vii) (viii) State two properties of positve rays viii 3. Answer briefly any SIX parts from the following 6x2=12 3 (i) Define electron affinity with an example. Electron Afinity (i) (ii) Distinguish between period and group in periodic table. (ii) (iii) State the four salient features of Periodic Law. (iii) (iv) Differentiate between lone pair and bond pair of electron. (iv) (v) State the Octet and Duplet rules. (v) (vi) Define ionic bond with an example. (vi) (vii) Describe melting and boiling point of solids. (vii) (viii) State the Charles's law. Also write its mathematical representation. (viii) (ix) Describe two factors on which evaporation depneds upon. Evaporation (ix) 4. Answer briefly any FIVE parts from the following 5x2=10 4 (i) (i) Justify with an example that the solubility of salt increases with the increase in temperature. (ii) Differentiate between true solution and colloidal solution. Colliodal Solution True Solution (ii) (iii) Define aqueous solution with an example. Aqueous Solution(iii) (iv) Calculate the oxidation number of chlorine in KClO3 . KClO3 (iv) (v) Differentiate between electrolytic cell and galvanic cell. Galvanic Cell Electrolytic Cell (v) (vi) Differentiate between valency and oxidation state. (vi) (vii) Differentiate between oxidizing and reducing agents. (vii) (viii) Define Saturated solution and give example viii P.T.O. ( 2 ) Part ------------------------------- II Note: Attempt any THREE questions. 7x3=21 4 6 (a) 5 5. (a) Define mole and molecule. Calculate number of moles, and number of molecules in 6 g of water.(1+1+1+1) 3 (b) (b) Describe Rutherford's atomic model . Also state two Observations made by Rutherford. (1+1+1) 4 a 6 6. (a) Define covalent bond. Explain single, double and triple covalent bond with example. (2+1+1+1) 3 Experimental (b) (b) Define the Boyle's law. Explain the experimental verification of Boyle's law. (1+2) 7. (a) Describe four rules for assigning oxidation number. ( 1 x 4 ) (a) 7 3 ! " (b) (b) Compare and contrast three chemical properties of Alkali metal and Alkaline earth metal. ( 1 x 3 ) 4 # a 8 (a) Define electron affinity. why it increases in a period and decrease in a group in the Periodic Table (1+1.5+1.5) NaOH 500Cm3 , 0.4M b (b) How much NaOH is required to prepare its 500cm3 of 0.4M solution. (a) Differentiate between the following 4 a 9 ii i (i) Molecular Mass and Molar Mass (ii) Chemical formula and Gram formula (b) Find out the Oxidration Numbers of the following: 3 b (i) S in Na2 SO4 (ii) Mn in K Mn O4 (iii) Cr in K2 Cr2 O7 Part ------------------------------- III Note:- Attempt any TWO questions. (Practical) 2 cm3 a 10 8. i) What is the volume of liquid, to the nearest cm3 in the measuring cylinder.(2) (ii) ii) Which materials are attracted by a magnet?1x3=(3) Material Attracted by magnet or not Yes/ No Plastic Copper Iron nails (i 11 1 2 2 i) You are preparing crystals of pure Copper Sulphate from impure Copper Sulphate. What will be the:- 1- Colour of pure Copper Sulphate crystals? 2- Shape of crystals & draw the diagram of crystals. 2 3 Non conductor Conductor HCl NaOH NaCl (ii ii) You are provided solution of NaCl , NaOH, HCl, demonstrate the conductivity of different given solution by filling the following table: 3 Observations Name of Solution Bulb glows/Not glows Result 1 NaCl 2 NaOH 3 HCl 2 Vapour Pressure i 12 i) Vapour pressure of which liquid will be higher at normal temperature , alcohol or water . 3 ii (ii) If you are provided few sugarcrystals and first heat gently and then strongly. Record your observations in the following table 1x3 Before Heating After Gentle Heating After Strong Heating Colour of Sugar Physical state of Sugar