EN0454.pdf

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Product contact hazard skin Eye Section water respiratory tract
Conforms to 93/112/EC and ISO 11014-1
Material Safety Data Sheet
HFBI
0454
0044211 0044210
CALL CHEMTREC:
800.424.9300
OUTSIDE US:
202.483.7616
11/4/2002
11/8/2002
Product name
Supplier
Manufacturer
Product No.
MSDS#
Validation Date
Print Date
In Case of Emergency
Section 1. Chemical Product and Company Identification
Responsible Name Pierce Administration
Synonyms Heptafluorobutyrylimidazole
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
1-(2,2,3,3,4,4,4-HEPTAFLUORO-1-OXOBUTYL)-1H-IMIDAZOLE
Chemical name
Eng
In USA: 
 In Europe:
Pierce 
 Perbio Science
P.O. Box 117 
 Industriezone III
Rockford, IL 61105  Industrielaan 27
USA 
 9320 Erembodegem-Aalst
815.968.0747 or
 Belgium
1.800.874.3723
 Tel:+32 53 83 44 04
 
 Fax:+32 53 83 76 38
Pierce Biotechnology
P.O. Box 117
Rockford, IL 61105
USA
815.968.0747 or
1.800.874.3723
1) HFBI
32477-35-3
98-100
251-063-8
C
R14, R34
Ingredient Name
EC Number
CAS No.
R-Phrases
Substance/Preparation
Substance
%
Symbol
:
Section 2. Composition, Information on Ingredients
Absorbed through skin.  Dermal contact.  Eye contact.  Inhalation.  Ingestion.
Emergency Overview
Medical Conditions Aggravated
by Overexposure:
Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation.  Repeated or
prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.
Not available.
Overexposure /Signs/Symptoms
Section 3. Hazards Identification
Routes of Entry
Potential Acute Health Effects
Carcinogenic Effects Data
Do not get in eyes, on skin or on clothing.  Do not breathe vapor or mist.  Keep container closed.  Use only with
adequate ventilation.  Wash thoroughly after handling.
Very hazardous in case of ingestion, .  Hazardous in case of skin contact (irritant), of eye contact (corrosive), of
inhalation (lung corrosive).  Corrosive to skin and eyes on contact.  Liquid or spray mist may produce tissue damage
particularly on mucous membranes of eyes, mouth and respiratory tract.  Skin contact may produce burns.  Inhalation
of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of
breath.
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
Review the most current and approved institutional guideline, protocol, standard operating procedure(s) and MSDS(s)
for the proper handling of institutional materials/equipment associated with the use of this product.
DANGER!
CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS.
CAUSES DAMAGE TO THE FOLLOWING ORGANS: MUCOUS MEMBRANES,
RESPIRATORY TRACT, SKIN, EYES.
Spillage may cause fire or liberate poisonous gas.
United States
Europe
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Physical/chemical hazards
Human health hazards
Environmental hazards Not applicable.
Causes burns.
Reacts violently with water.
See Toxicological Information (section 11)
Classification R14, R34
Do NOT induce vomiting unless directed to do so by medical personnel.  Never give anything by mouth to an unconscious
person.  If large quantities of this material are swallowed, call a physician immediately.  Loosen tight clothing such as a
collar, tie, belt or waistband.
Skin Contact
Ingestion
Check for and remove any contact lenses.  In case of contact, immediately flush eyes with plenty of water for at least 15
minutes.  Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes.  Cover the irritated skin with an emollient.  Wash clothing before reuse.  Thoroughly clean shoes before reuse.
Get medical attention immediately.
Hazardous in case of inhalation (lung corrosive).  Inhalation of the spray mist may produce severe irritation of respiratory
tract, characterized by coughing, choking, or shortness of breath.  Over-exposure by inhalation may cause respiratory
irritation.
Very hazardous in case of ingestion.  May be fatal if swallowed.  May cause burns to mouth, throat, and stomach.
Hazardous in case of skin contact (irritant).  Corrosive to skin on contact.  Skin contact may produce burns.  Skin
inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Skin Contact
Hazardous in case of eye contact (corrosive).
Eye Contact
Inhalation
Aggravating conditions Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation.  Repeated or
prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.
First-Aid Measures
If inhaled, remove to fresh air.  If not breathing, give artificial respiration.  If breathing is difficult, give oxygen.  Get medical
attention immediately.
Notes to Physician Not available.
Not available.
Protection of first-aiders
Ingestion
Effects and symptoms
Inhalation
Eye Contact
Section 4. First Aid Measures
Notice to Reader Get immediate medical attention.
Hazardous thermal (de)composition
products
These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), halogenated compounds.
Flammable.
  OPEN CUP: 77.22°C (171°F).
Flammable liquid.
SMALL FIRE:  Use DRY chemical powder.
LARGE FIRE:  Use alcohol foam, water spray or fog.
Not available.
Section 5. Fire Fighting Measures
Flammability of the Product
Flash Points
Fire Hazards in Presence of Various
Substances
Fire Fighting Media
and Instructions
Be sure to use an approved/certified respirator or equivalent.
Protective Clothing (Fire)
Flammable liquid.  Corrosive liquid.
Keep away from heat.  Keep away from sources of ignition.  Stop leak if without risk.  Absorb with DRY earth, sand or other
non-combustible material.  Do not get water inside container.  Do not touch spilled material.  Use water spray curtain to divert
vapor drift.  Prevent entry into sewers, basements or confined areas; dike if needed.  Call for assistance on disposal.
Section 6. Accidental Release Measures
Small Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Environmental Precautions and
Clean-up Methods
Personal precautions Face shield.  Full suit.  Vapor respirator.  Be sure to use an approved/certified respirator or equivalent.  Gloves.  Boots.
Continued on Next Page
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Keep container tightly closed.  Keep container in a cool, well-ventilated area.  Keep from any possible contact with
water.  Do not allow water to get into container because of violent reaction.
Do not breathe vapor or mist.  Keep container closed.  Use only with adequate ventilation.  Wash thoroughly after
handling.
Section 7. Handling and Storage
Handling
Storage
Suitable /  Not suitable
Packaging materials
Use original container.
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
1) HFBI
Not available.
Germany
1) HFBI
Not available.
Netherlands
1) HFBI
Not available.
France
1) HFBI
Not available.
Norway
1) HFBI
Not available.
Denmark
1) HFBI
Not available.
Sweden
1) Heptafluorobutyrylimidazole
Not available.
United States
Ingredient Name
Occupational Exposure Limits
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value.  Ensure that eyewash stations and safety showers are proximal to the work-station
location.
Section 8. Exposure Controls/Personal Protection
Exposure Limit Values
Boots.
Personal Protection
Eyes
Body
Hands
Feet
Protective Clothing
(Pictograms)
Gloves.
Lab coat.
Splash goggles.
Respiratory Respirator is not needed under normal and intended conditions of use, if exposures are kept below established limits.
Continued on Next Page
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161°C (321.8°F)
Liquid.
1.5625 (Water = 1)
Not available.
Not available.
264.1 g/mole
Not available.
Not available.
Not available.
Boiling/Condensation Point
Physical State  and
Appearance
Molecular Weight
Specific Gravity
Dispersion Properties
Solubility
Odor
Taste
Color
C7H3F7N2O
Molecular Formula
Section 9. Physical and Chemical Properties
The product is stable.
Highly reactive with moisture.
Reactive with oxidizing agents.
The product reacts violently with water to emit flammable but non toxic gases.
Will not occur.
Not available.
Section 10. Stability and Reactivity
Stability and Reactivity
Conditions to avoid
Materials to avoid
Hazardous Polymerization
Hazardous Decomposition
Products
These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), halogenated compounds.
LD50: Not available.
LC50: Not available.
Hazardous in case of eye contact (corrosive), of inhalation (lung corrosive).
Causes damage to the following organs: mucous membranes, upper respiratory tract, skin, eyes.
Not available.
Not available.
Not available.
Section 11. Toxicological Information
Toxicity to Animals
Chronic Effects on Humans
Other Toxic Effects on Humans
Special Remarks on Toxicity to
Animals
Special Remarks on Chronic
Effects on Humans
Special Remarks on Other Toxic
Effects on Humans
Ecotoxicity Not available.
Mobility
Germany water class
Not available.
Not available.
Not available.
Persistence/degradability
Bioaccumulative potential
VCI WGK: No products were found.
Section 12. Ecological Information
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Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Not available.
Waste Information
Waste Stream
Section 13. Disposal Considerations
Consult your local or regional authorities.
Contact the supplier for all information regarding the proper transportation method for this material.
Section 14. Transport Information
U.S. Federal Regulations
No products were found.
Water reactive material
Irritating substance.
Combustible liquid having a flash point between 37.8°C (100°F) and 93.3°C (200°F).
Corrosive material
HCS Classification
Section 15. Regulatory Information
California prop. 65:  No products were found.
TSCA: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
State Regulations
No products were found.
No products were found.
WHMIS (Canada) CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F).
CLASS E: Corrosive liquid.
R14- Reacts violently with water.
R34- Causes burns.
DSCL (EEC)
International Regulations
Not available.
EINECS
International Lists
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found.
SARA 313 toxic chemical notification and release reporting: No products were found.
R14- Reacts violently with water.
R34- Causes burns.
S8- Keep container dry.
S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Corrosive
Label Requirements
(Europe)
1
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Version
0.01
Date of Previous Issue No Previous
Validation
Not available.
Section 16. Other Information
References
Validated by Pierce Administration on 11/4/2002.
Verified by Pierce Administration.
Printed 11/8/2002.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate.  However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Hazardous Material
Information System
(U.S.A.)
3
3
2
2
3
3
*
National Fire Protection
Association (U.S.A.)
Health
Specific Hazard
Reactivity
Fire Hazard
Health
Fire Hazard
Reactivity
Personal Protection
History of Document Changes Any information changes since last document version are marked with a triangle symbol.
Causes burns.
Full text of R-Phrases
referenced under headings 2 and 3:
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.