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SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 03/13/2008 Date Updated: 11/09/2007 Version 1.6 Section 1 - Product and Company Information Product Name ZEOLITE Product Number 96096 Brand FLUKA Company Sigma-Aldrich Canada, Ltd Address 2149 Winston Park Drive Oakville ON L6H 6J8 CA Technical Phone: 9058299500 Fax: 9058299292 Emergency Phone: 800-424-9300 Section 2 - Composition/Information on Ingredient Substance Name CAS # SARA 313 ZEOLITES 1318-02-1 No Synonyms Abscents 3000 * Agrolithe 15/25 * Aid Plus OCMA * Aluminosilicates, zeolites * Bactekiller BM 101A * Bactekiller BM 102A * Bactekiller BM 501A * Bactekiller MB * Baylith AC 6184 * Calsit * Coratyl G * Crystal structure types, zeolites * CS 100 * CS 100 (zeolite) * CS 100S * EZA Zeolite A * GRZ 1 * Harmony 70 * Ionsiv * JE 15P * KC-Perlkator D 10E * KKh 100 * LM 104 * LM 108 * LM 204 * LM 208 (zeolite) * LMS 9611 * Microzeokan 8 * MZ 3 * NA 100 * NC 300 * Neuronizeon SP 3000 * Radiolite * SGK 1 * Siliporite NK 10 * Silton B 50 * Silton B-MZ 260 * Silton CPT 30 * Silton LP 75 * SK 40 * Spansorb C * SSZ 37 * Sylosiv 100 * T 134 * Tomix 550 * TSZ 300 * Ukazil X 100 * Wessalith 80 * XH 9 * XH 600 * Y-SK 40 * Z 3125 * ZB 200 * ZB 400 * Zeofill * Zeokar * Zeokar 2 * Zeokar 3 * Zeolite 1014 * Zeolite 1424 * Zeolite 24P * Zeolite particles * Zeolith * Zeolith 225 * Zeolith Taylor * Zeolum * Zeolum SA * Zeomic * Zeosorb * Zeostar CA 100P * Zeostar CA 110P RTECS Number: ZG6800000 Section 3 - Hazards Identification EMERGENCY OVERVIEW Caution: Avoid contact and inhalation. Target organ(s): Lungs. HMIS RATING HEALTH: 1* FLAMMABILITY: 0 REACTIVITY: 0 NFPA RATING HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0 *additional chronic hazards present. For additional information on toxicity, please refer to Section 11. Section 4 - First Aid Measures ORAL EXPOSURE If swallowed, wash out mouth with water provided person is conscious. Call a physician. INHALATION EXPOSURE If inhaled, remove to fresh air. If breathing becomes difficult, call a physician. DERMAL EXPOSURE In case of contact, immediately wash skin with soap and copious amounts of water. EYE EXPOSURE In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician. Section 5 - Fire Fighting Measures FLASH POINT N/A AUTOIGNITION TEMP N/A FLAMMABILITY N/A EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. FIREFIGHTING Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits toxic fumes under fire conditions. Section 6 - Accidental Release Measures PROCEDURE(S) OF PERSONAL PRECAUTION(S) Exercise appropriate precautions to minimize direct contact with skin or eyes and prevent inhalation of dust. METHODS FOR CLEANING UP Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete. Section 7 - Handling and Storage HANDLING User Exposure: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. FLUKA - 96096 www.sigma-aldrich.com Page 2 STORAGE Suitable: Keep tightly closed. SPECIAL REQUIREMENTS Hygroscopic. Section 8 - Exposure Controls / PPE ENGINEERING CONTROLS Safety shower and eye bath. Mechanical exhaust required. PERSONAL PROTECTIVE EQUIPMENT Respiratory: Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks. Hand: Protective gloves. Eye: Chemical safety goggles. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Section 9 - Physical/Chemical Properties Appearance Physical State: Solid Property Value At Temperature or Pressure Molecular Weight N/A pH N/A BP/BP Range N/A MP/MP Range N/A Freezing Point N/A Vapor Pressure N/A Vapor Density N/A Saturated Vapor Conc. N/A SG/Density N/A Bulk Density N/A Odor Threshold N/A Volatile% N/A VOC Content N/A Water Content N/A Solvent Content N/A Evaporation Rate N/A Viscosity N/A Surface Tension N/A Partition Coefficient N/A Decomposition Temp. N/A Flash Point N/A Explosion Limits N/A Flammability N/A Autoignition Temp N/A Refractive Index N/A Optical Rotation N/A Miscellaneous Data N/A Solubility N/A N/A = not available Section 10 - Stability and Reactivity FLUKA - 96096 www.sigma-aldrich.com Page 3 STABILITY Stable: Stable. Conditions to Avoid: Moisture. Materials to Avoid: Strong acids, Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Nature of decomposition products not known. HAZARDOUS POLYMERIZATION Hazardous Polymerization: Will not occur Section 11 - Toxicological Information ROUTE OF EXPOSURE Skin Contact: May cause skin irritation. Skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure can cause: Damage to the lungs. TOXICITY DATA Oral Rat > 10,000 mg/kg LD50 Skin Rabbit > 2,000 mg/kg LD50 4 H Inhalation Rat > 5,300 mg/m3 LC50 1 H Inhalation Rat 2,400.0 - 18,300.0 mg/m3 LC50 IRRITATION DATA Skin Rabbit Remarks: Mild irritation effect Skin Human Remarks: No irritation effect Eyes Rabbit Remarks: Mild irritation effect Eyes Rabbit Remarks: No irritation effect FLUKA - 96096 www.sigma-aldrich.com Page 4 CHRONIC EXPOSURE - MUTAGEN Species: Human Dose: 50 MG/L Cell Type: lymphocyte Mutation test: Cytogenetic analysis Species: Mouse Route: Intraperitoneal Dose: 50 MG/KG Mutation test: Cytogenetic analysis Section 12 - Ecological Information No data available. Section 13 - Disposal Considerations APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations. Section 14 - Transport Information DOT Proper Shipping Name: None Non-Hazardous for Transport: This substance is considered to be non-hazardous for transport. IATA Non-Hazardous for Air Transport: Non-hazardous for air transport. Section 15 - Regulatory Information US CLASSIFICATION AND LABEL TEXT US Statements: Caution: Avoid contact and inhalation. Target organ(s): Lungs. UNITED STATES REGULATORY INFORMATION SARA LISTED: No CANADA REGULATORY INFORMATION WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR. DSL: No NDSL: No Section 16 - Other Information DISCLAIMER For R&D use only. Not for drug, household or other uses. WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our FLUKA - 96096 www.sigma-aldrich.com Page 5 knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Inc., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Copyright 2008 Sigma-Aldrich Co. License granted to make unlimited paper copies for internal use only. FLUKA - 96096 www.sigma-aldrich.com Page 6
