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CAS# 67-63-0 Code AC-7830 Formula weight Supersedes 60.10 2-PROPANOL (CH3)2CHOH IPA, Isopropanol, Isopropyl alcohol, sec-Propyl alcohol, Dimethylcarbinol, AC-7830, AC-7830SC, AC-7830PG, AC-7830P, GD-7830, GD-7831, CD-7831, M-10589, M-10595, M-7832, M-11178, M-10204, 76400, 76403, 76406, 76415, 76395 For laboratory use only. Anachemia Canada. 255 Norman. Lachine (Montreal), Que H8R 1A3 Section II. Ingredients Material Safety Data Sheet Synonyms Chemical formula Material uses 3 WHMIS Protective Clothing TDG Road/Rail Section I. Product Identification and Uses Not available. Supplier CI# Product name 255 Norman. Lachine (Montreal), Que H8R 1A3 PIN: UN1219 PG: II WHMIS CLASS: B-2 D-2B TDG CLASS: 3 1) 2-PROPANOL 67-63-0 99-100 Exposure limits: ACGIH TWA 200 ppm (491.6 mg/m3); STEL 400 ppm (983 mg/m3) 2-PROPANOL: ORAL (LD50): Acute: 6410 mg/kg (Rabbit). 3600 mg/kg (Mouse). 5045 mg/kg (Rat). ORAL (LDLo): Acute: 3570 mg/kg (Human). DERMAL (LD50): Acute: 12800 mg/kg (Rabbit). VAPOR (LC50): Acute: 16000 ppm (Rat) (8 hour(s)). Toxicity values of the hazardous ingredients Name CAS # % EMERGENCY NUMBERS: (USA) CHEMTREC : 1(800) 424-9300 (24hrs) (CAN) CANUTEC : 1(613) 996-6666 (24hrs) (USA) Anachemia : 1(518) 297-4444 (CAN) Anachemia : 1(514) 489-5711 TLV Section V. Toxicological Properties Harmful by ingestion, inhalation, or skin absorption. Irritant. Target organs: cardiovascular system, gastrointestinal system, kidneys, eyes, skin, nerves, respiratory system. 2000 ppm (2-PROPANOL) is immediately dangerous to life or health. Section III. Physical Data Physical state and appearance / Odor Percent volatile pH (1% soln/water) Freezing point Boiling point Vapor pressure Odor threshold Specific gravity Vapor density Water/oil dist. coeff. Evaporation rate Solubility 100% (V/V) Not available. -86 to -89.5°C 82 to 83°C 0.79 (Water = 1) 2.1 (Air = 1) 45.4 mm Hg @ 25°C 0.34 1.7 (n-Butyl acetate = 1). Miscible in water. 40-200 ppm Colorless liquid with alcohol odor. 2-PROPANOL page 2/4 Auto-ignition temperature Fire degradation products Flash point Fire extinguishing procedures Flammable limits Fire and Explosion Hazards 399°C OPEN CUP: 12°C (Tag open cup) LOWER: 2% UPPER: 12.7% Use DRY chemical, carbon dioxide, or alcohol-resistant foam. Water may be ineffective to extinguish fires. Wear adequate personal protection to prevent contact with material or its combustion products. Self contained breathing apparatus with a full facepiece operated in a pressure demand or other positive pressure mode. Disperse vapors with water spray if they have not ignited. Cool containing vessels with flooding quantities of water. Flammable liquid. Vapors formed from this product may travel or be moved by air currents and ignited by pilot lights, other flames, sparks, heaters, electrical equipment, static discharges or other ignition sources at locations distant from handling point. Vapor forms explosive mixture with air. Container explosion may occur under fire conditions or when heated. Contact with oxidizers may cause fire and/or explosion. Sensitive to static discharge. Not expected to be sensitive to mechanical impact. Emits toxic fumes under fire conditions. Section IV. Fire and Explosion Data Effects of Acute Exposure Routes of entry Ingestion and inhalation. Eye contact. Skin contact. Skin absorption. Ingestion Inhalation Skin Eye Causes severe irritation. May cause severe burns and loss of vision. May cause permanent damage. IRRITATION: EYE-RABBIT 100 mg SEVERE Causes skin irritation. Defatting dermatitis with prolonged use. Readily absorbed through skin. Material is irritating to mucous membranes and upper respiratory tract. Exposure to high vapor concentrations may cause central nervous system depression ( headache, drowsiness, nausea, vomiting, stuper, dizziness, incoordination, unconsciousness, etc...), coma and death possible. May have anesthetic effect with prolonged use. Causes gastrointestinal irritation. May cause headache, nausea, dizziness, vomiting, fatigue, abdominal pain, diarrhea, gastritis and central nervous system depression. Lethal dose for humans is estimated at 250 mL. If a small amount of the liquid is aspirated into the lungs, very severe lung damage or death could result. Oxides of carbon (CO, CO2). Section VI. First Aid Measures Section V. Toxicological Properties Forms explosive peroxides on contact with air, if they become concentrated, these peroxides may present an explosion hazard. Hazardous polymerization will not occur. DO NOT induce vomiting. Guard against aspiration into lungs. Seek immediate medical attention. Never give anything by mouth to an unconscious or convulsing person. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing in of vomitus. Hazardous decomp. products Stability Incompatibility Stable. Conditions to avoid: High temperatures, sparks, open flames and all other sources of ignition, contamination. Not available. Oxidizing agents, acids, chlorine, trinitromethane, hydrogen peroxide, phosgene, halogens, acid anhydrides, oleum, iron salts, sulfuric acid, hydrogen-palladium, permanganates, potassium t-butoxide, nitroform, acetaldehyde, barium perchlorate, ethylene oxide, hexamethylene diisocyanate, hypochlorous acid, isocyanates, perchloric acid, permonosulfuric acid, halogenated compounds, amines, alkalies, aldehydes, ketones. Aluminum at high temperatures. Section VII. Reactivity Data Reaction Products 2-PROPANOL page 3/4 Immediately flush eyes with copious quantities of water for at least 15 minutes holding lids apart to ensure flushing of the entire surface. Seek immediate medical attention. Remove patient to fresh air. Administer approved oxygen supply if breathing is difficult. Administer artificial respiration or CPR if breathing has ceased. Seek immediate medical attention. Eye contact Skin contact Inhalation Ingestion Immediately flush skin with plenty of water and soap for at least 15 minutes while removing contaminated clothing and shoes. Call a physician. Wash contaminated clothing before reusing. Discard contaminated leather articles such as shoes and belt. Effects of Chronic Overexposure Repeated or prolonged skin contact can cause defatting and drying of the skin resulting in skin irritation and dermatitis. Prolonged or repeated exposure to high concentrations can produce severe or fatal central nervous system depression. Animal: liver and spleen damage. Detected in maternal milk in human. Carcinogenic effects: Not available. Mutagenic effects: Not available. Teratogenic effects: Not available. Toxicity of the product to the reproductive system: Not available. To the best of our knowledge, the chemical, physical, and toxicity of this substance has not been fully investigated. Medical conditions which may be aggravated: Individuals with preexisting diseases of the skin, eye, or respiratory system may be more susceptible to the toxicity of overexposure to this product. While the company believes the data set forth herein are accurate as of the date hereof, the company makes no warranty with respect thereto and expressly disclaims all liability for reliance thereon. Such data are offered solely for your consideration, investigation and verification. Section X. Other Information Waste disposal Storage and Handling Spill and leak Protective Clothing in case of spill and leak Burn in a chemical incinerator equipped with an after burner and scrubber. According to all applicable regulations. Harmful to aquatic life at high concentrations. Can be dangerous if allowed to enter drinking water intakes. Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds, or rivers. Evacuate the area. Eliminate all sources of ignition and ensure that all handling equipment is electrically grounded. Stay upwind: Keep out of low areas. Dyke the area with sand or a natural barrier. Absorb on sand or vermiculite and place in a closed container for disposal. Use non-sparking tools. Transport outdoors. Ventilate area and wash spill site after material pick up is complete. DO NOT empty into drains. DO NOT touch damaged container or spilled material. Runoff to sewer may create fire or explosion hazard. Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. Store in a cool place away from heated areas, sparks, and flame. Store in a well ventilated area. Store away from incompatible materials. Do not add any other material to the container. Do not wash down the drain. Do not breathe gas/fumes/vapor/spray. In case of insufficient ventilation, wear suitable respiratory equipment. Keep away from direct sunlight or strong incandescent light. Keep container tightly closed and dry. Manipulate under an adequate fume hood. Take precautionary measures against electrostatic discharges. Ground the container while dispensing. Ground all equipment containing material. Use only explosion proof equipment. Use non-sparking tools. Watch for accumulation in low confined areas. Empty containers may contain a hazardous residue. Do not use pressure to dispense. May develop pressure; vent periodically. Handle and open container with care. Take off immediately all contaminated clothing. This product must be manipulated by qualified personnel. Do not get in eyes, on skin, or on clothing. Wash well after use. In accordance with good storage and handling practices. Do not allow smoking and food consumption while handling. Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively. Product is highly hygroscopic. Section VIII. Preventive Measures page 4/4 2-PROPANOL Splash goggles. Impervious viton or nitrile gloves, apron, coveralls, and/or other resistant protective clothing. Sufficient to protect skin. Have available and use as appropriate: face shields, rubber suits, aprons, and boots. A OSHA/MSHA jointly approved respirator is advised in the absence of proper environmental controls. If more than TLV, do not breathe vapor. Wear self-contained breathing apparatus. Do not wear contact lenses. Make eye bath and emergency shower available. Ensure that eyewash station and safety shower is proximal to the work-station location. Section IX. Protective Measures Engineering controls Use only in a chemical fume hood to keep airborne levels below recommended exposure limits. Use explosion-proof ventilation equipment. Vapors are heavier than air and may travel along the ground or pool in low areas. Because vapor is heavy, ventilation must be provided at floor level as well as at higher levels. Do not use in unventilated spaces. Protective clothing Prepared by MSDS Department/Département de F.S.. Validated 22-Jun-2006 Telephone# (514) 489-5711 Flammable liquid! Irritant! Do not breathe vapor. Avoid all contact with the product. Avoid prolonged or repeated exposure. Use only in a chemical fume hood. Keep away from heat, sparks and flame. Take precautionary measures against static discharges. Use non-sparking tools. Bond and ground transfer containers and equipment to avoid static accumulation. May develop pressure; vent periodically. Handle and open container with care. Container should be opened only by a technically qualified person. Synergistic materials: Increases the hepatotoxicity of carbon tetrachloride, chloroform, trichloroethylene and 1,1,2-trichloroethane. RTECS NO: NT8050000 (2-Propanol). NOTE TO PHYSICIAN: If symptoms such as loss of gag reflex, convulsions, or unconsciousness occur before vomiting, gastric lavage with a cuffed endotracheal tube should be considered. Metabolism of 2-propanol forms acetone, which may be detected in the urine and expired air. In contact to diabetic acidosis, acidosis will occur in the absence of hyperglycemia. Hemodialysis should be considered in severe acute intoxications. Special Precautions or comments 1 3 0 NFPA
