Loading ...
Global Do...
News & Politics
148
0
Try Now
Log In
Pricing
MATERIAL SAFETY DATA SHEET Print date: 27-Apr-2005 ELECTROPURE COPPER SULFATE SOL Revision Number: 1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product code: 2200364-0055-4-000 Product name: ELECTROPURE COPPER SULFATE SOL Synonyms: No information available Chemical characterisation: Aqueous solution of inorganic acid salt. Emergency telephone number SPILLS AND TRANSPORT CHEMTREC: 800-424-9300 CANUTEC: 613-996-6666 TRANSPORT MEDICAL ROCKY MOUNTAIN POISON CONTROL CENTER: 303-623-5716 2. HAZARDS IDENTIFICATION This material is considered to be hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). This material is a controlled product under WHMIS. Potential health & environmental effects Properties affecting health: Causes irritation. Principle routes of exposure: Eyes. Skin. Respiratory system. Gastrointestinal tract. Skin contact: Irritating to skin. Repeated contact may cause dermatitis. Eye contact: Severe eye irritation. May cause burns. May cause damage. Inhalation: May cause irritation of respiratory tract. Ingestion: Causes irritation of the mouth, throat, and stomach. Harmful if swallowed.. Potential environmental effects: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment 3. COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS (BY WEIGHT PERCENT) Components CAS-No Weight % Copper (II) sulfate pentahydrate (1:1:5) 7758-99-8 20 - 30 Sulfuric acid 7664-93-9 0.1 - 1.0 ATOTECH CANADA LTD. 1180 CORPORATE DRIVE BURLINGTON, ONTARIO L7L 5R6 TELEPHONE: 905-332-0111 HOURS: 9:00am - 5:00pm EST Supplier: ATOTECH USA INC 1750 OVERVIEW DRIVE ROCK HILL, SC 29730 TELEPHONE: 803-817-3500 HOURS: 9:00am - 5:00pm EST SAP Number: 2200364-0055-4-000 Product name: ELECTROPURE COPPER SULFATE SOL EMERGENCY OVERVIEW CAUTION IRRITANT PAGE 1 OF 7 Product name: ELECTROPURE COPPER SULFATE SOL 4. FIRST AID MEASURES General advice: Consult a physician Skin contact: Rinse immediately with plenty of water and seek medical advice. Inhalation: Move to fresh air. If symptoms persist, call a physician. Eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Ingestion: Call a physician or Poison Control Center immediately. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Notes to physician: Treat symptomatically. Protection of first-aiders: Avoid contact with skin and eyes. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Extinguishing media which must not be used for safety reasons: No information available Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA / NIOSH (approved or equivalent) and full protective gear. Specific hazards: In the event of fire, the following can be released, copper oxides, sulfur oxides. Unusual hazards: May react with magnesium to evolve flammable hydrogen gas. Specific methods: In the event of fire, cool tanks with water spray Flash Point: Not determined. Flash point test method: Not applicable. Autoignition temperature: Not applicable. Flammability Limits in Air: - Lower: Not applicable. - Upper: Not applicable. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Isolate area and deny entry to unauthorized and/or unprotected personnel. See Section 8 for complete Personal Protective Equipment (PPE) recommendations. Environmental precautions: Do not release into the environment or public sewage without consulting local authorities and obtaining all applicable permits and notification requirements. Methods for containment: Prevent further leakage or spillage if safe to do so. Methods for cleaning up: Spills should be cleaned up immediately to prevent dispersion of airborne mists and dusts. For a spill involving a solid material, clean up promptly by scoop or vacuum. Avoid dust formation. Use approved industrial vacuum cleaner for removal. Keep in suitable, closed containers for disposal. Dike spilled liquid material with suitable inert absorbent (ex: sand, soil, vermiculite) and place in a clean dry container for later recycle or disposal. Flush with water. Clean contaminated surface thoroughly. Dispose of in accordance with all local, state, provincial, and federal regulations. Revision date: 27-Apr-2005 PAGE 2 OF 7 SAP Number: 2200364-0055- 4-000 Product name: ELECTROPURE COPPER SULFATE SOL Product name: ELECTROPURE COPPER SULFATE SOL 7. HANDLING AND STORAGE Handling Technical measures/precautions: Use only in area provided with appropriate exhaust ventilation. Safe handling advice: Do not contact with skin, eyes, or clothing. Do not breathe vapors or spray mist. Do not ingest. Storage Technical measures/storage conditions: Keep containers tightly closed in a dry, cool and well-ventilated place. May be corrosive to steel; do not store in steel containers. Do not freeze. Incompatible products: Magnesium. Reducing agents. Strong bases. Cyanides. Sulfides. Shelf Life (days): Not determined Storage Temperature Do not store below: 45 °F / 7 °C 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment Respiratory protection: Use NIOSH approved respiratory equipment when airborne concentrations are equal to or may exceed exposure limits. For emergency or other conditions where exposure levels are not known or may be uncontrolled, use a positive pressure air-supplied or self-contained breathing apparatus (SCBA). Hand protection: Consult glove manufacturer to determine the most suitable chemical resistant glove for user's application. Consideration must be given to durability and permeation resistance. Skin and body protection: Chemical resistant apron. Long sleeved clothing. Boots. Eye protection: Tightly fitting safety goggles. Face-shield. An emergency eye wash must be readily accessible to the work area. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and immediately after handling the product. When using, do not eat, drink or smoke. Components TWA STEL Ceilings TWA STEL Ceilings TWA STEL Ceilings Copper (II) sulfate pentahydrate (1:1:5) 7758-99-8 1 mg/m³ 1 mg/m³ 1 mg/m³ Sulfuric acid 7664-93-9 0.2 mg/m³ 3 mg/m³ 1 mg/m³ 1 mg/m³ 9. PHYSICAL AND CHEMICAL PROPERTIES ACGIH OSHA SAP Number: 2200364-0055- 4-000 Product name: ELECTROPURE COPPER SULFATE SOL Revision date: 27-Apr-2005 NIOSH PAGE 3 OF 7 Exposure limits Product name: ELECTROPURE COPPER SULFATE SOL Explosion limits: - Upper: Not applicable. - Lower: Not applicable. 10. STABILITY AND REACTIVITY Stability: Stable under recommended storage conditions. Materials to avoid: Magnesium. Reducing agents. Strong bases. Cyanides. Sulfides. Conditions to avoid: Keep away from open flames, hot surfaces and sources of ignition. Extremes of temperature and direct sunlight. Do not store in steel containers. Do not freeze. Incompatible products. Hazardous decomposition products: Thermal decomposition can lead to the release of irritating gases and vapors which may include (but are not limited to), copper oxides, sulfur oxides. Possibility of hazardous reactions: None under normal processing. May react with magnesium to evolve flammable hydrogen gas. 11. TOXICOLOGICAL INFORMATION Acute toxicity Component Information Components LD50/oral/rat LC50/inhalation/8h/rat LD50/dermal/rabbit Copper (II) sulfate pentahydrate (1:1:5) - 7758-99-8 300 mg/kg No information available No information available Sulfuric acid - 7664-93-9 2140 mg/kg 510 mg/m³ No information available Product Information LC50/inhalation/4h/rat = No information available LD50/dermal/rabbit = No information available LD50/oral/rat = No information available Local effects Skin irritation: Irritating to skin. Repeated contact may cause dermatitis. May cause localized skin discoloration. Eye irritation: Severe eye irritation. May cause burns. May cause damage. Inhalation: May cause irritation of respiratory tract. Ingestion: Ingestion causes irritation to the mouth, throat, and stomach. May be harmful if swallowed. May cause kidney and/or liver damage. Specific effects Carcinogenic effects: The IARC has classified "Strong inorganic acid mists containing sulfuric acid" as a Category 1 carcinogen, a substance that is "carcinogenic to humans". This classification is for strong inorganic acid mists only and does not apply to sulfuric acid or sulfuric acid solutions. Specific gravity: VOC content(%): Not applicable. 1.160 - 1.185 Solubility in water: Complete Color: Solubility in other solvents: No information available pH: 1.0 - 3.5 Blue Boiling point: Not applicable. Flash Point: Not determined. Liquid Flash point test method: Not applicable. Autoignition temperature: Not applicable. Melting point: 35 °F 2 °C Decomposition temperature: Not applicable. Odor: Evaporation rate: Not applicable. None Vapor density: Not applicable. SAP Number: 2200364-0055- 4-000 Physical state: Product name: ELECTROPURE COPPER SULFATE SOL Revision date: 27-Apr-2005 Vapor pressure: PAGE 4 OF 7 Not applicable. Product name: ELECTROPURE COPPER SULFATE SOL Mutagenic effects: No information available Reproductive toxicity: No information available Target organ effects: Kidneys. Liver. Skin. Carcinogens Components NTP: IARC: OSHA ACGIH Sulfuric acid 1 Present 12. ECOLOGICAL INFORMATION Environmental Hazards Ecotoxicity effects: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Aquatic toxicity: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Mobility: This product is soluble in water. Bioaccumulative potential: Not determined. Components Freshwater Algae Freshwater Fish Species Copper (II) sulfate pentahydrate (1:1:5) - 7758-99-8 96 h LC50 (goldfish) = 0.1 mg/L 96 h LC50 (harlequin fish) = 0.1 mg/L 96 h LC50 (rainbow trout) = 0.1 mg/L Components Microtoxicity Water Flea Copper (II) sulfate pentahydrate (1:1:5) 7758-99-8 30 min EC50 Photobacterium phosphoreum < 0.25 mg/L 15 min EC50 Photobacterium phosphoreum = 0.25 mg/L 5 min EC50 Photobacterium phosphoreum = 1.3 mg/L 48 h EC50 = 0.24 mg/L 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of in accordance with federal, provincial, state, and local regulations Contaminated packaging: Empty containers should be taken for local recycling, recovery or waste disposal 14. TRANSPORT INFORMATION DOT Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class: 9 UN-No: UN3082 Packing group: III ERG No: 171 Description: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., ( COPPER SULFATE ) , 9, UN3082, PGIII, MARINE POLLUTANT, RQ TDG (Canada) Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.( COPPER SULFATE ) Hazard Class: 9 UN-No: UN3082 Packing group: III Description: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., ( COPPER SULFATE ) , 9, UN3082, PGIII, MARINE POLLUTANT Revision date: 27-Apr-2005 PAGE 5 OF 7 SAP Number: 2200364-0055- 4-000 Product name: ELECTROPURE COPPER SULFATE SOL Product name: ELECTROPURE COPPER SULFATE SOL IMO / IMDG Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class: 9 UN-No: UN3082 Packing group: III Description: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., ( COPPER SULFATE ) , 9, UN3082, PGIII, MARINE POLLUTANT IATA Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class: 9 UN-No: UN3082 Packing group: III Description: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., ( COPPER SULFATE ) , 9, UN3082, PGIII, MARINE POLLUTANT 15. REGULATORY INFORMATION International Inventories All of the components in this product are on or exempt from the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Australia (AICS), China (IECSC), Philippines (PICCS). International Inventory Legend TSCA: Toxic Substance Control Act DSL: Domestic Substance List NDSL: Non-Domestic Substance List EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: EU List of Notified Chemical Substances ECL: Existing Chemicals List aka Existing and Evaluated Chemical Substances AICS: Inventory of Chemical Substances ENCS: Existing and New Chemical Substances PICCS: Phillipines Inventory of Chemicals and Chemical Substances U.S. Regulations: HAZARDOUS COMPONENTS Components CA PROP 65 SARA 302 SARA 313 CERCLA RQ TSCA 12(b) CWC DEA Copper (II) sulfate pentahydrate (1:1:5) X 5000 lb Sulfuric acid X X 1000 lb Essential List II Canada This product has been classified in accordance with the criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. SARA 311 Chronic Health Hazard YES U.S. Regulations Legend CA PROP 65: California Proposition 65 - Carcinogens List TSCA 12(b): TSCA Section 12(b) - Export Notification SARA 302: CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA RQs and TPQs SARA 313: CERCLA/SARA - Section 313 - Emission Reporting CERCLA RQ: CERCLA/SARA - Hazardous Substances and Their Reportable Quantities CWC: Chemical Weapons Convention - Annex on Chemicals DEA LISTED: DEA (Drug Enforcement Administration) - DEA Controlled, Precursors, and / or Essential Chemicals Fire Hazard NO Acute Health Hazard Sudden Release of Pressure Hazard NO SAP Number: 2200364-0055- 4-000 YES Product name: ELECTROPURE COPPER SULFATE SOL Revision date: 27-Apr-2005 PAGE 6 OF 7 Reactive Hazard NO Product name: ELECTROPURE COPPER SULFATE SOL WHMIS Controlled List HAZARDOUS COMPONENTS Components CAS-No WHMIS Call out threshold Copper (II) sulfate pentahydrate (1:1:5) 7758-99-8 1 % Sulfuric acid 7664-93-9 1 % WHMIS hazard class: • D2A Very toxic materials • D2B Toxic materials 16. OTHER INFORMATION NFPA: Health: 2 Flammability: 0 Instability: 0 CAREFULLY READ THE FOLLOWING: The identification of ingredients in this document meets or exceeds the requirements set forth in 29 CFR, 40 CFR, et al. at the date of publication. Ingredients present in a mixture or solution which are generically identified or not referenced in this document are not regulatorily required to be specifically identified or referenced. The information contained herein should be provided to all those who will use, handle, store, transport, or may otherwise be exposed to this product. THE INFORMATION CONTAINED HEREIN, TO THE BEST OF OUR KNOWLEDGE, IS CONSIDERED TO BE ACCURATE. SUCH INFORMATION IS OFFERED SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION, AND WE DO NOT SUGGEST OR GUARANTEE THAT ANY PRECAUTIONS, PROCEDURES, RECOMMENDATIONS ETC. ARE PREFERRED OR UNIQUE. ATOTECH USA INC. MAKES NO WARRANTIES, EXPRESS OR IMPLIED, INCLUDING THE WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, WITH RESPECT TO THE USE OF THIS INFORMATION OR THE USE OF MATERIAL IDENTIFIED HEREIN, IN COMBINATION WITH ANY OTHER MATERIAL OR PROCESS, AND ASSUMES NO RESPONSIBILITY THEREFORE. THIS DOCUMENT WAS DEVELOPED UNDER THE REQUIREMENTS OF THE UNITED STATES, AND AS SUCH MAY NOT SATISFY OTHER STATE OR REGIONAL REQUIREMENTS. Prepared by: H.E.S. Department Revision date: 27-Apr-2005 PAGE 7 OF 7 SAP Number: 2200364-0055- 4-000 Product name: ELECTROPURE COPPER SULFATE SOL
