Water Care A80023

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<p>MATERIAL SAFETY DATA SHEET
WATER CARE A80023, LIQUID
3. HAZARDS IDENTIFICATION
Corrosive! Toxic effects are principally related to its corrosive properties. Causes severe skin and eye 
burns. Mists or sprays are extremely irritating to eyes and respiratory tract. Toxic effects may be 
delayed. See "Other Health Effects" Section. Can decompose at high temperatures forming toxic gases. 
Contents may develop pressure on prolonged exposure to heat.
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS
Corrosive! Product may cause severe irritation of the nose, throat and respiratory tract.  Repeated 
and/or prolonged exposures may cause productive cough, running nose, bronchopneumonia, 
pulmonary oedema (fluid build-up in lungs), and reduction of pulmonary function. Airborne concentration 
of dust, mist or spray may cause damage to the lung tissue which could produce chemical pneumonia. 
Toxic effects may be delayed. See "Other Health Effects" Section.
Inhalation:
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON  (416) 226-6117                     Montreal, QC (514) 861-1211                     Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754                  Calgary, AB  (403) 263-8660                       Vancouver, BC (604) 685-5036
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Brenntag Canada Inc.
43 Jutland Rd.
Toronto, ON
M8Z 2G6
(416) 259-8231
Website:  http:\\www.brenntag.ca
WHMIS#:
00066481
Index: 
2007 July 13
PRODUCT IDENTIFICATION
Water Care A80023, Liquid.
Product Name:  
2007 July 13
Date of Revision:
Effective Date:
HCI5621/07C
Not available.
Chemical Name:
Not applicable.
Synonyms:
Inorganic salt.
Chemical Family:
Al2(OH)xCl6-x  (0 < x <6).
Molecular Formula:
Water treatment.
Product Use:
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
E:  Corrosive
Ingredient
CAS#
ACGIH TLV
% Concentration
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
Polyaluminum Chloride
1327-41-9
2 mg/m³ as Al 
soluble salts
10 - 30
Water Care A80023, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 July 13
WHMIS Number :
00066481
Page 2 of 7
4. FIRST AID MEASURES
FIRST AID PROCEDURES
Prompt removal of the material and obtaining medical attention are essential for all contact.  Remove all 
contaminated clothing and immediately wash the exposed areas with copious amounts of water.  
Continue the flushing during transportation to the emergency department.  Corrosive effects may be 
delayed (up to 72 hours), and damage may occur without the sensation or onset of pain.  Contact local 
poison control centre for further guidance.
General Guidelines:  
Move victim to fresh air.  Give artificial respiration ONLY if breathing has stopped.  Give 
cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse.  Oxygen administration may 
be beneficial in this situation but should only be administered by personnel trained in its use.  Obtain 
medical attention IMMEDIATELY.
Inhalation:
Prompt removal of the material from the skin is essential.  Remove all contaminated clothing and 
immediately wash the exposed areas with copious amounts of soap and water for a minimum of 30 
minutes or up to 60 minutes for critical body areas.  Immerse the exposed part immediately in ice water 
to relieve pain and to prevent swelling and blistering.  Place cold packs, ice or wet cloths on the burned 
area if immersion is not possible.  Cover the exposed part with a clean, preferably sterile, lint-free 
dressing.  Obtain medical attention IMMEDIATELY and monitor breathing and treat for shock for severe 
exposure.
Skin Contact:
Immediately flush eyes with running water for a minimum of 30 minutes, preferably up to 60 minutes.  
Hold eyelids open during flushing.  If irritation persists, repeat flushing.  Do not transport victim until the 
recommended flushing period is completed unless flushing can be continued during transport.
Eye Contact:
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not 
convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material.  DO NOT induce 
vomiting.  If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing 
in of vomitus, rinse mouth and administer more water.  Obtain medical attention IMMEDIATELY.
Ingestion:
Corrosive! Toxic effects may be delayed. Burns (chemical) can occur if not promptly removed. 
Prolonged, confined (especially under the finger nails, under rings or watch bands) or repeated 
exposure may cause skin irritation and possibly lead to (chemical) burns. Prolonged and repeated 
contact may lead to dermatitis.
Skin Contact:
Skin absorption is a secondary concern to the continual destruction of tissue while the product is in 
contact with the skin. Burns (chemical) can occur if not promptly removed.
Skin Absorption:
Extremely corrosive!  This product causes corneal scarring and clouding.  Glaucoma, cataracts and 
permanent blindness may occur.
Eye Contact:
Corrosive! This product causes severe burning and pain in the mouth, throat and abdomen.  Vomiting, 
diarrhea and perforation of the esophagus and stomach lining may occur.
Ingestion:
Human experience and animal studies indicate that acidic compounds (pH less than 3.5) may cause 
irritation and burns.  (3) Corrosive effects on the skin and eyes may be delayed, and damage may occur 
without the sensation or onset of pain.  Strict adherence to first aid measures following any exposure is 
essential.
May cause pulmonary oedema, ulcers of the upper respiratory tract, chemical pneumonitis, liver 
damage or kidney damage. Pulmonary oedema is the build-up of fluid in the lungs that might be fatal.  
Symptoms of pulmonary oedema, such as shortness of breath, may not appear until several hours after 
exposure and are aggravated by physical exertion. (4) Liver damage is characterized by the loss of 
appetite, jaundice (yellowish skin colour), and occasional pain in the upper left-hand side of the 
abdomen. Signs and symptoms of kidney damage generally progress from oliguria, to blood in the 
urine, to total renal failure.
Other Health Effects:
Water Care A80023, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 July 13
WHMIS Number :
00066481
Page 3 of 7
Immediate consultation with the local Poison Control Centre should be initiated.  Severe and sometimes 
delayed (up to 72 hours) local and systemic reactions can occur.
Due to the severely irritating or corrosive nature of the material, swallowing may lead to ulceration and 
inflammation of the upper alimentary tract with hemorrhage and fluid loss.  Also, perforation of the 
esophagus or stomach may occur, leading to mediastinitis or peritonitis and the resultant complications. 
(3)
Mucosal injury following ingestion of this corrosive material may contraindicate the induction of vomiting 
in the treatment of possible intoxication.  Similarly, if gastric lavage is performed, intubation should be 
done with great care.  If oral burns are present or a corrosive ingestion is suspected by the patient's 
history, perform esophagoscopy as soon as possible.  Scope should not be passed beyond the first 
burn because of the risk of perforation.
Medical conditions that may be aggravated by exposure to this product include neurological and 
cardiovascular disorders, diseases of the skin, eyes or respiratory tract, preexisting liver and kidney 
disorders.
Note to Physicians:
5. FIRE-FIGHTING MEASURES
Flashpoint (°C)
AutoIgnition 
Temperature (°C)
LEL
UEL
Flammability Limits in Air (%):  
Non-combustible (does not 
burn).
Not applicable.
Not applicable.
Not applicable.
Not regulated.
Flammability Class (WHMIS):
Thermal decomposition products are toxic and may include: chlorine, flammable hydrogen gas, 
corrosive hydrochloric acid gas, oxides of carbon, sulphur, aluminum and irritating gases.
Hazardous Combustion 
Products:
Reacts with most metals to produce hydrogen gas which could make an explosive mixture with air. 
Spilled material may cause floors and contact surfaces to become slippery. Contents may develop 
pressure on prolonged exposure to heat. Closed containers exposed to heat may burst.
Unusual Fire or Explosion 
Hazards:
Not expected to be sensitive to mechanical impact.
Sensitivity to Mechanical Impact:
Not available.
Rate of Burning:
Not available.
Explosive Power:
Not expected to be sensitive to static discharge.
Sensitivity to Static Discharge:
EXTINGUISHING MEDIA
Use media appropriate for surrounding fire and/or materials.
Fire Extinguishing Media:
FIRE FIGHTING 
INSTRUCTIONS
Isolate materials that are not involved in the fire and protect personnel.  Cool containers with flooding 
quantities of water until well after the fire is out. Spilled material may cause floors and contact surfaces 
to become slippery.
Instructions to the Fire Fighters:
Use self-contained breathing apparatus and protective clothing. Protective clothing for skin and eye 
protection should be worn to protect against corrosive materials.
Fire Fighting Protective 
Equipment:
6. ACCIDENTAL RELEASE MEASURES
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons, 
property and the environment.  There may be specific reporting requirements associated with spills, leaks or releases, which change from 
region to region.
See Section 13, "Deactivating Chemicals". In all cases of leak or spill contact vendor at Emergency 
Number shown on the front page of this MSDS. Wear respirator, protective clothing and gloves. Spilled 
material may cause floors and contact surfaces to become slippery. Collect product for recovery or 
disposal.  For release to land, or storm water runoff, contain discharge by constructing dykes or 
applying inert absorbent;  for release to water, utilize damming and/or water diversion to minimize the 
spread of contamination.  Ventilate enclosed spaces.  Notify applicable government authority if release 
is reportable or could adversely affect the environment. Replace damaged containers immediately to 
avoid loss of material and contamination of surrounding atmosphere.
Containment and Clean-Up 
Procedures:
Water Care A80023, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 July 13
WHMIS Number :
00066481
Page 4 of 7
7. HANDLING AND STORAGE
HANDLING
Use normal "good" industrial hygiene and housekeeping practices. Containers exposed to heat may be 
under internal pressure.  These should be cooled and carefully vented before opening.  A face shield 
and apron should be worn. Vent container frequently, and more often in warm weather, to relieve 
pressure.
Handling Practices:
See Section 8, "Engineering Controls".
Ventilation Requirements:
Use only with adequate ventilation and avoid breathing aerosols ( vapours or mists ). Avoid contact with 
eyes, skin or clothing.  Wash thoroughly with soap and water after handling.  Wash contaminated 
clothing thoroughly before re-use.
Other Precautions:
STORAGE
Ideal storage temperature is 10 to 30 °C. (3) The typical shelf life of this product is 12 months. (3)
Storage Temperature (°C):
Local exhaust ventilation required. Ventilation should be corrosion proof.
Ventilation Requirements:
Keep containers closed. Store in a clean, cool well ventilated area, away from organic chemicals, strong 
bases, strong acids, metal powders, carbides, sulfides, and any readily oxidizable material.  Protect 
from direct sunlight.  Protect against physical damage. Storage tanks should be in a contained area to 
control any spills or leaks. Storage area should be equipped with corrosion-resistant floors, sumps and 
should have controlled drainage to a recovery tank.
Corrosive residue is most likely to be deposited at process vents or storage tanks, especially during 
filling operations.  The use of compressed air to force corrosive materials from delivery trucks is of 
special concern.  Scrubbing the exhaust of these vents is highly recommended.  Jurisdictional 
regulations should be consulted to determine required practices.
Storage Requirements:
Reacts with most metals to produce hydrogen gas which could make an explosive mixture with air. 
Equipment for storage, handling or transport should NOT be made from the following material, or, 
where applicable, its alloys:   carbon steel, aluminum, brass, carbon or nylon. Confirm suitability of any 
material before using.
Special Materials to be Used for 
Packaging or Containers:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this 
product.  Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific 
protective devices at your workplace.
ENGINEERING CONTROLS
Local exhaust ventilation required.  Ventilation should be corrosion proof. Make up air should be 
supplied to balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas 
such as sumps or pits where dense vapours may collect.
For personnel entry into confined spaces (i.e. bulk storage tanks) a proper procedure must be followed.  
It must include consideration of, among other things, ventilation, testing of tank atmosphere, provision 
and maintenance of SCBA, and emergency rescue. Use the "buddy" system.  The second person 
should be in view and trained and equipped to execute a rescue.  (4)
Engineering Controls:
PERSONAL PROTECTIVE 
EQUIPMENT (PPE)
Use full face-shield and chemical safety goggles when there is potential for contact. Contact lenses 
should not be worn when working with this material.
Eye Protection:
Gloves and protective clothing made from neoprene, rubber or plastic should be impervious under 
conditions of use.   Do not use gloves or protective clothing made from leather. Discard contaminated 
gloves. User should verify impermeability under normal conditions of use prior to general use.
Skin Protection:
No specific guidelines available. Respiratory protection should not be necessary unless the material is 
heated or a mist created. A NIOSH/MSHA-approved full facepiece air-purifying respirator equipped with 
acid gas, dust, mist, fume cartridges for concentrations up to 1000 ppm. An air-supplied respirator if 
concentrations are higher or unknown.
Respiratory Protection:
Wear an impermeable apron and boots. Locate safety shower and eyewash station close to chemical 
handling area. Take all precautions to avoid personal contact.
Other Personal Protective 
Equipment:
EXPOSURE GUIDELINES
SUBSTANCE
ACGIH TLV
(STEL)
OSHA PEL
(TWA)                   (STEL)
NIOSH REL
(TWA)                      (STEL)    
Polyaluminum Chloride
— 
--- 
--- 
2 mg/m3 
--- 
Water Care A80023, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 July 13
WHMIS Number :
00066481
Page 5 of 7
Liquid.
Clear, colourless to amber liquid.
Strong, pungent odour.
Not available.
100 - 110.  (3)
-20 -  - 5.  (3)
18.  (3)
1.3.  (3)
1.15 - 1.40.  (3)
1 150 - 1 400 kg/m3.
Not available.
< 1.
Soluble in water.
Not available.
0.5 - 4.4 (neat).
Not available.
Not applicable.
Physical State:
Appearance:
Odour:
Odour Threshold (ppm):
Boiling Range (°C):
Melting/Freezing Point (°C):
Vapour Pressure (mm Hg at 20° C):
Vapour Density (Air = 1.0):
Relative Density (g/cc):
Bulk Density:
Viscosity:
Evaporation Rate (Butyl Acetate = 1.0):
Solubility:
% Volatile by Volume:
pH:
Coefficient of Water/Oil Distribution:
Volatile Organic Compounds (VOC):
9. PHYSICAL AND CHEMICAL PROPERTIES  (Not intended as Specifications)
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL DATA:
SUBSTANCE
LD50 (Oral, Rat)
LD50 (Dermal, Rabbit)
LC50 (Inhalation, Rat, 4h)
Polyaluminum Chloride
12 800 mg/kg (3)
> 2 000 mg/kg (3)
20 mg/l (3)
The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP.
Carcinogenicity Data:
No adverse reproductive effects are anticipated.
Reproductive Data:
No adverse mutagenic effects are anticipated.
Mutagenicity Data:
No adverse teratogenic effects are anticipated.
Teratogenicity Data:
None known.
Respiratory / Skin Sensitization 
Data:
None known.
Synergistic Materials:
None known.
Other Studies Relevant to 
Material:
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY
Stable.
Under Normal Conditions:
Not flammable.
Under Fire Conditions:
Will not occur.
Hazardous Polymerization:
High temperatures, sparks, open flames and all other sources of ignition.
Conditions to Avoid:
Strong oxidizers. Reducing agents. Lewis or mineral acids. Alkalies. Organic Halides. Organic nitro 
compounds. Aldehydes. Organic materials. Strong bases. Perchloric Acid. Strong bases. Ammonia. 
Amines. Alkali metals and their hydroxides. Combustibles. Organic materials. Alkanol amines. 
Aldehydes. Nylon.
Reacts with most metals to produce hydrogen gas which could make an explosive mixture with air. 
Carbon steel. Brass. Carbon. Aluminum and its alloys. Copper and its alloys.
Materials to Avoid:
Thermal decomposition products are toxic and may include: chlorine, flammable hydrogen gas, 
corrosive hydrochloric acid gas, oxides of carbon, sulphur, aluminum and irritating gases.
Decomposition or Combustion 
Products:
Water Care A80023, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 July 13
WHMIS Number :
00066481
Page 6 of 7
12. ECOLOGICAL INFORMATION
Not available. May be harmful to aquatic life. Toxicity is primarily associated with pH. Acidic soil 
conditions can develop with product present.  Higher than normal toxic heavy metal concentrations can 
then occur in ground and surface waters.
Ecotoxicity:
Not available. May be harmful if allowed to enter drinking water intakes. Do not contaminate domestic or 
irrigation water supplies, lakes, streams, ponds, or rivers.
Environmental Fate:
13. DISPOSAL CONSIDERATIONS
Neutralize carefully with soda ash or sodium bicarbonate to a pH of 6 to 9. Neutralization is expected to 
be exothermic. Effervescence may result.
Deactivating Chemicals:
This information applies to the material as manufactured. Reevaluation of the product may be required 
by the user at the time of disposal since the product uses, transformations, mixtures and processes 
may influence waste classification. Dispose of waste material at an approved (hazardous) waste 
treatment/disposal facility in accordance with applicable local, provincial and federal regulations.  Do not 
dispose of waste with normal garbage, or to sewer systems.
Waste Disposal Methods:
See "Deactivating Chemicals".
Safe Handling of Residues:
Empty containers retain product residue (liquid and/or vapour) and can be dangerous. Empty drums 
should be completely drained, properly bunged and promptly returned to a drum reconditioner. Do not 
dispose of package until thoroughly washed out.
Disposal of Packaging:
14. TRANSPORTATION INFORMATION
CANADIAN TDG ACT SHIPPING DESCRIPTION:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Polyaluminum Hydroxychloride), Class 8, UN3264, PG III.
Label(s):  Corrosives.          Placard:  Corrosives.
ERAP Index: -----.
Exemptions: None known.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Polyaluminum Hydroxychloride), Class 8, UN3264, PG III.
Label(s):  Corrosive.          Placard:  Corrosive.
CERCLA-RQ: Not available.
Exemptions: None known.
15. REGULATORY INFORMATION
CANADA
All constituents of this product are included on the DSL.
CEPA - NSNR:
Not included.
CEPA - NPRI:
Not available.
CANADIAN FOOD AND DRUG 
ACT/REGULATIONS:
Controlled Products Regulations Classification (WHMIS):
E:  Corrosive
USA
All constituents of this product are included on the TSCA inventory.
Environmental Protection Act:
Corrosive.
OSHA HCS (29CFR 1910.1200):
Text22:
NFPA:  1 Health,   0 Fire,   0 Reactivity   (3)
Text22:
HMIS:  1 Health,   0 Fire,   0 Reactivity   (3)
INTERNATIONAL
Not available.
Water Care A80023, Liquid
Brenntag Canada Inc.
Date of Revision:
2007 July 13
WHMIS Number :
00066481
Page 7 of 7
16.  OTHER INFORMATION
REFERENCES
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS 
database.
1.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons, 
New York, 1981.
2.
Supplier's Material Safety Data Sheet(s).
3.
CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
4.
Guide to Occupational Exposure Values, 2005, American Conference of Governmental Industrial Hygienists, Cincinnati, 2005.
5.
Regulatory Affairs Group, Brenntag Canada Inc.
6.
The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical 
Association, Ottawa, 1981.
7.
____________________________________________________________________________________________________________
The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith 
by technically knowledgeable personnel.  It is not intended to be all-inclusive and the manner and conditions of use and handling may 
involve other and additional considerations.  No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for 
any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained 
herein.  This Material Safety Data Sheet is valid for three years.
____________________________________________________________________________________________________________
To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia:  20333-102B Avenue, Langley, BC, V1M 3H1
         Phone:  (604) 513-9009         Facsimile:  (604) 513-9010
Alberta:   6628 - 45 th. Street, Leduc, AB, T9E 7C9
         Phone:  (780) 986-4544         Facsimile:  (780) 986-1070
Manitoba:  681 Plinquet Street, Winnipeg, MB, R2J 2X2
         Phone:  (204) 233-3416         Facsimile:  (204) 233-7005
Ontario:  43 Jutland Road, Toronto, ON, M8Z 2G6
         Phone:  (416) 259-8231         Facsimile:  (416) 259-6175
Quebec:  2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8
         Phone:  (514) 636-9230         Facsimile:  (514) 636-0877
Atlantic:  A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7
         Phone:  (902) 468-9690         Facsimile:  (902) 468-3085
____________________________________________________________________________________________________________
Prepared By:  Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.
</p>