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Jun05/03 MATERIAL SAFETY DATA SHEET : LA8091 PAGE:1 STOCHEM SPECIALTY CHEMICALS DIVISION OF UNIVAR CANADA LTD. 9800 VAN HORNE WAY RICHMOND, BC, CANADA V6X 1W5 1-866-686-4827 PRODUCT : ACRONAL 700 L SECTION 01: PRODUCT INFORMATION MANUFACTURER.....................BASF CANADA INC. 345 CARLINGVIEW DRIVE TORONTO, ONTARIO M9W 6N9 (416) 675-3611 CANUTEC (613) 996-6666 - COLLECT PRODUCT IDENTIFIER...............ACRONAL 700 L TRADE NAME(S)....................ACRONAL 700 L;ACRONAL 700 L - 50 KG/DRUM; CEPA STATUS......................ALL OF THE INGREDIENTS OF THIS PRODUCT ARE LISTED ON THE DOMESTIC SUBSTANCES LIST (DSL). WHMIS CLASSIFICATION.............CLASS B, DIVISION 2, FLAMMABLE LIQUID. CLASS D, DIVISION 2, SUBDIVISION B T.D.G. CLASSIFICATION............RESIN SOLUTION; 3; UN1866; II CHEMICAL NAME....................COPOLYMER OF BUTYLACRYLATE AND VINYLISOBUTYLETHER IN ETHYLACETATE. MATERIAL USE.....................RESIN SECTION 02: HAZARDOUS INGREDIENTS HAZARDOUS INGREDIENTS % EXPOSURE LEVELS C.A.S. # LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES ETHYL ACETATE 30-60 400ppm - ACGIH/ONT 141-78-6 5620mg/Kg/RAT/ORAL 2263ppm/4H/RAT 5ppm SKIN - ONT SECTION 03: PHYSICAL DATA PHYSICAL STATE...................LIQUID ODOUR/APPEARANCE.................COLOURLESS LIQUID. ESTER ODOUR ODOUR THRESHOLD..................NOT AVAILABLE VAPOUR PRESSURE.................. 100 mbar @ 20 C VAPOUR DENSITY (AIR=1)...........NOT AVAILABLE % VOLATILE: BY VOLUME..................NOT DETERMINED BY WEIGHT.................. 50 EVAPORATION RATE.................FASTER THAN BUTYL ACETATE. BOILING POINT.................... 77 C FREEZING POINT...................NOT AVAILABLE pH...............................NOT AVAILABLE SPECIFIC GRAVITY................. 0.96 SOLUBILITY IN WATER (20 C).......INSOLUBLE COEFFICIENT WATER/OIL DIST.......NOT AVAILABLE SECTION 04: FIRE & EXPLOSION DATA FLAMMABILITY.....................FLAMMABLE LIQUID. MEANS OF EXTINCTION..............CARBON DIOXIDE. DRY CHEMICAL. FOAM. WATER FOG SPECIAL PROCEDURES...............KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. WEAR SELF CONTAINED BREATHING APPARATUS IN CONFINED AREAS OR WHEN EXPOSED TO COMBUSTION PRODUCTS. FLASH POINT AND METHOD........... -4 C (DIN 51755) AUTO IGNITION TEMPERATURE........ 460 C T.D.G. FLAMMABILITY CLASS........CLASS 3, FLAMMABLE LIQUIDS UPPER EXPLOSION LIMIT............ 11.5 LOWER EXPLOSION LIMIT............ 2.1 HAZARDOUS COMBUSTION PRODUCTS....NOT AVAILABLE EXPLOSION DATA SENSITIVITY TO STATIC............NOT AVAILABLE DISCHARGE SENSITIVITY TO IMPACT......NONE RATE OF BURNING............NOT AVAILABLE EXPLOSIVE POWER............CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. SECTION 05: REACTIVITY DATA CHEMICAL STABILITY: STABLE ?...................YES CONDITIONS TO AVOID........HEAT, SPARKS, FLAMES INCOMPATIBLE MATERIALS...........STRONG ACIDS. STRONG BASES. STRONG OXIDIZING AGENTS REACTIVITY, UNDER WHAT...........HAZARDOUS POLYMERIZATION WILL NOT OCCUR. CONDITIONS? HAZARDOUS PRODUCTS OF............OXIDES OF CARBON (CO,CO2). OXIDES OF NITROGEN DECOMPOSITION SECTION 06: TOXICOLOGICAL PROPERTIES ROUTE OF ENTRY: SKIN CONTACT...............IRRITATING. Jun05/03 MATERIAL SAFETY DATA SHEET : 00000784 PAGE:2 PRODUCT : ACRONAL 700 L SECTION 06: TOXICOLOGICAL PROPERTIES SKIN ABSORPTION............NONE KNOWN EYE CONTACT................IRRITATING. INHALATION, ACUTE..........INHALATION MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT. INHALATION, CHRONIC........REFER TO INHALATION ACUTE. INGESTION..................INGESTION MAY CAUSE ADVERSE HEALTH EFFECTS. EFFECTS OF ACUTE EXPOSURE........REFER TO ROUTE OF ENTRY. EFFECTS OF CHRONIC EXPOSURE......NONE KNOWN LD 50 OF MATERIAL, SPECIES &..... 5600 mg/kg/RAT/ORAL/ETHYL ACETATE ROUTE LC 50 OF MATERIAL, SPECIES &.....REFER TO HAZARDOUS INGREDIENTS SECTION ROUTE EXPOSURE LIMIT OF MATERIAL.......ETHYLACETATE = 400 ppm, 1440mg/m3 IRRITATION CAUSED BY MATERIAL....IRRITANT SENSITIZING CAPABILITY OF........NONE KNOWN MATERIAL CARCINOGENICITY OF MATERIAL......NONE KNOWN. REPRODUCTIVE EFFECTS.............NONE KNOWN SYNERGISTIC MATERIALS............NONE KNOWN SECTION 07: PREVENTIVE MEASURES PROTECTIVE EQUIPMENT GLOVES/TYPE................BUTYL RUBBER OR NEOPRENE GLOVES. RESPIRATORY/TYPE...........APPROVED RESPIRATOR IF TLV IS EXCEEDED. EYE/TYPE...................GOGGLES. FOOTWEAR/TYPE..............IMPERVIOUS FOOTWEAR. CLOTHING/TYPE..............IMPERMEABLE APRON. OTHER/TYPE.................EYE BATH AND SAFETY SHOWER ENGINEERING CONTROLS.............ADEQUATE GENERAL AND LOCAL EXHAUST. SPILL/LEAK SPILL/LEAK............ELIMINATE ALL SOURCES OF IGNITION. CONTAIN LARGE SPILLS AND PUMP AWAY. SMALL SPILLS CAN BE COVERED WITH ABSORBENT MATERIAL. WASTE DISPOSAL, METHOD AND.......INCINERATE IN APPROVED FACILITY. IN ACCORDANCE WITH MUNICIPAL, PROVINCIAL EQUIPMENT. AND FEDERAL REGULATIONS HANDLING PROCEDURES AND..........USE NON-METALLIC TOOLS. EQUIPMENT MUST BE GROUNDED. USE EXPLOSION PROOF EQUIPMENT ELECTRICALS. KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. AVOID ALL SKIN CONTACT. AVOID CONTACT WITH EYES. AVOID INHALING. STORAGE NEEDS....................STORE AWAY FROM HEAT AND IGNITION SOURCES. GROUND ALL CONTAINERS DURING TRANSFER. STORE IN A COOL AND DRY PLACE. STORE IN A WELL VENTILATED AREA. SPECIAL SHIPPING INSTRUCTIONS....SHIPMENTS OF THIS PRODUCT MUST BE IN COMPLIANCE WITH ALL APPLICABLE FEDERAL, PROVINCIAL AND INTERNATIONAL TRANSPORTATION REGULATIONS. SECTION 08: FIRST AID MEASURES EYE CONTACT:.....................FLUSH IMMEDIATELY WITH WATER FOR 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. INGESTION: INGESTION:............ADMINISTER PLENTY OF WATER. DO NOT INDUCE VOMITING. CALL A PHYSICIAN. IF VICTIM IS UNCONSCIOUS, NEVER INDUCE VOMITING NOR GIVE LIQUIDS. PLACE VICTIM IN A STABLE SIDE POSITION AND KEEP WARM. INHALATION:......................REMOVE TO FRESH AIR. ASSIST BREATHING IF NECESSARY. CONSULT A PHYSICIAN. SKIN CONTACT:....................WASH THOROUGHLY WITH SOAP AND WATER AND RINSE WELL FOR 15 MINUTES. CONSULT A PHYSICIAN IF IRRITATION DEVELOPS. SECTION 09: PREPARATION INFORMATION PHONE #..........................(905) 458-6888 PREPARED BY......................JACKIE FOSTER PREPARATION DATE.................NOV 27/2002
