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hazard Product contact skin toxic effects Eye water Material
Conforms to 93/112/EC and ISO 11014-1
Material Safety Data Sheet
PFPI
460
0044300
CHEMTREC:
800.424.9300
OUTSIDE US:
202.483.7616
3/3/2005
3/3/2005
Product name
Supplier
Manufacturer
Product No.
MSDS#
Validation Date
Print Date
In Case of Emergency
Section 1. Chemical Product and Company Identification
Responsible Name Company2
Synonyms Pentafluoropropionylimidazole
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
Eng
In USA: 
 In Europe:
Pierce 
 Perbio Science
P.O. Box 117 
 Industriezone III
Rockford, IL 61105  Industrielaan 27
USA 
 9320 Erembodegem-Aalst
815.968.0747 or
 Belgium
1.800.874.3723
 Tel:+32 53 83 44 04
 
 Fax:+32 53 83 76 38
Pierce Biotechnology
P.O. Box 117
Rockford, IL 61105
USA
815.968.0747 or
1.800.874.3723
Substance/Preparation
Substance
:
Section 2. Composition, Information on Ingredients
CAS number
Ingredient name
%
EC number
Classification
PFPI
71735-32-5
98 - 100
R14
T; R23/24/25
C; R34
Dermal contact.  Eye contact.  Inhalation.  Ingestion.
Emergency Overview
Section 3. Hazards Identification
Routes of Entry
Do not ingest.  Do not get in eyes, on skin or clothing.  Do not breathe vapor or mist.  Keep away from heat, sparks and
flame.  Will react with water or steam to produce heat and toxic fumes.  Keep container closed.  Use only with adequate
ventilation.  Wash thoroughly after handling.
Review the most current and approved institutional guideline, protocol, standard operating procedure(s) and MSDS(s)
for the proper handling of institutional materials/equipment associated with the use of this product.
Danger!
CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS.
SPILLAGE MAY CAUSE FIRE OR LIBERATE POISONOUS GAS.
CONTACT WITH WATER WILL PRODUCE HEAT,
IMIDAZOLE AND PERFLUOROPROPRIONIC ACID
HARMFUL IF INHALED, ABSORBED THROUGH SKIN OR SWALLOWED.
CAUSES DAMAGE TO THE FOLLOWING ORGANS: MUCOUS MEMBRANES, SKIN,
EYES.
United States
Potential acute health effects
Toxic by inhalation.  Corrosive to the respiratory system.
Corrosive to eyes.
Toxic if swallowed.  May cause burns to mouth, throat and stomach.
Toxic in contact with skin.  Corrosive to the skin.
Eyes
Skin
Inhalation
Ingestion
Potential chronic health effects
Target organs Causes damage to the following organs: mucous membranes, skin, eyes.
Continued on Next Page
PFPI
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Physical/chemical hazards
Human health hazards
Environmental hazards Not applicable.
Toxic by inhalation, in contact with skin and if swallowed.
Causes burns.
Reacts violently with water.
Medical Conditions Aggravated
by Overexposure:
Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation.  Repeated or
prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.
Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or
many human organs.
Not available.
Overexposure /Signs/Symptoms
Carcinogenic Effects Data
See Toxicological Information (section 11)
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
Classification R14
T; R23/24/25
C; R34
Europe
Do NOT induce vomiting unless directed to do so by medical personnel.  Never give anything by mouth to an unconscious
person.  Get medical attention immediately.
Skin Contact
Ingestion
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.  Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes.  Wash clothing before reuse.  Thoroughly clean shoes before reuse.  Get medical attention immediately.
Hazardous in case of inhalation (lung irritant, lung corrosive).  Inhalation of the spray mist may produce severe irritation of
respiratory tract, characterized by coughing, choking, or shortness of breath.  Over-exposure by inhalation may cause
respiratory irritation.
May be fatal if swallowed.  May cause burns to mouth, throat and stomach.
Hazardous in case of skin contact (corrosive, irritant).  Skin contact may produce burns.  Severe over-exposure can result in
death.  Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Skin Contact
Hazardous in case of eye contact (irritant, corrosive).
Eye Contact
Inhalation
Aggravating conditions Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation.  Repeated or
prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.
Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many
human organs.
First-Aid Measures
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.  Get medical attention immediately.
Notes to Physician Not available.
Not available.
Protection of first-aiders
Ingestion
Effects and symptoms
Inhalation
Eye Contact
Section 4. First Aid Measures
Notice to Reader Get immediate medical attention.
Non-flammable.
Not applicable.
Use dry chemical or CO2.  Do not use water or foam.
Not applicable.
Section 5. Fire Fighting Measures
Flammability of the Product
Flash Points
Fire Hazards in Presence of Various
Substances
Fire Fighting Media
and Instructions
Not applicable.
Protective Clothing (Fire)
Not available.
Continued on Next Page
PFPI
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Hazardous thermal (de)composition
products
These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), halogenated compounds, hydrogen fluoride.
Stop leak if without risk.  Absorb with DRY earth, sand or other non-combustible material.  Do not get water inside
container.  Do not touch spilled material.  Use water spray curtain to divert vapor drift.  Use water spray to reduce
vapors.  Prevent entry into sewers, basements or confined areas; dike if needed.  Call for assistance on disposal.
Section 6. Accidental Release Measures
Small Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal.Never add water to the
product.
Environmental Precautions and
Clean-up Methods
Personal precautions Face shield.  Full suit.  Vapor respirator.  Be sure to use an approved/certified respirator or equivalent.  Gloves.  Boots.
Store in a segregated and approved area.  Keep container in a cool, well-ventilated area.  Keep container tightly closed
and sealed until ready for use.
Do not ingest.  Do not get in eyes, on skin or on clothing.  Keep container closed.  Use only with adequate ventilation.
Do not breathe vapor or mist.  Keep away from heat, sparks and flame.  Will react with water or steam to produce heat
and toxic fumes.  Wash thoroughly after handling.
Section 7. Handling and Storage
Handling
Storage
Suitable /  Not suitable
Packaging materials
Use original container.
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
United States
Ingredient Name
Occupational Exposure Limits
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective occupational exposure limits.  Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Section 8. Exposure Controls/Personal Protection
Exposure Limit Values
Boots.
Personal Protection
Eyes
Body
Hands
Feet
Protective Clothing
(Pictograms)
Gloves.
Lab coat.
Splash goggles.
Respiratory Respirator is not needed under normal and intended conditions of use, if exposures are kept below established limits.
39°C (102.2°F)
Liquid.
214.09 g/mole
Not available.
Not available.
Clear
Boiling/Condensation Point
Physical State  and
Appearance
Molecular Weight
Dispersion Properties
Odor
Taste
Color
C6H3ON2F5
Molecular Formula
Section 9. Physical and Chemical Properties
Continued on Next Page
PFPI
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Not available.
Not available.
Solubility
Product reacts with water vigorously. Reaction is exothermic (evolves heat quickly).
Reaction products include imidazole and perfluoroproprionic acid.
Reactive with moisture.
Will not occur.
Section 10. Stability and Reactivity
Stability and Reactivity
Conditions to avoid
Materials to avoid
Hazardous Polymerization
Hazardous Decomposition
Products
These products are halogenated compounds, hydrogen fluoride.
PFPI
  LD50: Not available.
  LC50: Not available.
Hazardous in case of eye contact (irritant, corrosive), of ingestion, of inhalation (lung irritant, lung corrosive).
Causes damage to the following organs: mucous membranes, skin, eyes.
Not available.
Not available.
Not available.
Section 11. Toxicological Information
Toxicity to Animals
Chronic Effects on Humans
Other Toxic Effects on Humans
Special Remarks on Toxicity to
Animals
Special Remarks on Chronic
Effects on Humans
Special Remarks on Other Toxic
Effects on Humans
Skin
Ingestion
Inhalation No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Over-exposure
signs/symptoms
Target organs Causes damage to the following organs: mucous membranes, skin, eyes.
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Mutagenicity
No known significant effects or critical hazards.
Reproductive toxicity
Ecotoxicity Not available.
Mobility
Germany water class
Not available.
Not available.
Not available.
Persistence/degradability
Bioaccumulative potential
VCI WGK: No products were found.
Section 12. Ecological Information
Species
Period
Ecotoxicity data
Ingredient name
Persistence/degradability
Other ecological information
Continued on Next Page
PFPI
Page: 5/7
Mobility
Not available.
:
LogPow
BCF
Bioaccumulative potential
Other adverse effects
: No known significant effects or critical hazards.
Ingredient name
Ingredient name
BOD5
COD
Ingredient name
Aquatic half-life
Photolysis
Not available.
Waste Stream
Section 13. Disposal Considerations
Denmark – Carcinogenic waste Not available.
Not available.
Sweden - thermoset plastic
waste
Not available.
European waste catalogue
(EWC)
The classification of the product may meet the criteria for a hazardous waste
Hazardous waste
Austria  -  Waste catalogue Not available.
Denmark  -  Waste card number Not available.
Denmark  -  Waste group Not available.
Sweden  -  Waste group Not available.
Norway  -  Waste number Not available.
Switzerland  -  Waste code Not available.
The generation of waste should be avoided or minimized wherever possible.  Avoid dispersal of
spilled material and runoff and contact with soil, waterways, drains and sewers.  Disposal of this
product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements.
Methods of disposal
Norway  - Hazardous waste The classification of the product may meet the criteria for a hazardous waste
Contact the supplier for all information regarding the proper transportation method for this material.
Section 14. Transport Information
Section 15. Regulatory Information
R14- Reacts violently with water.  R23/24/25- Toxic by inhalation, in contact with skin and if swallowed.
R34- Causes burns.
S1/2- Keep locked up and out of the reach of children.  S26- In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice.  S36/37/39- Wear suitable protective clothing,
gloves and eye/face protection.  S45- In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).  S63- In case of accident by inhalation: remove casualty to
fresh air and keep at rest.
Label Requirements
(Europe)
1
Continued on Next Page
PFPI
Page: 6/7
U.S. Federal Regulations
No products were found.
Water reactive material
Toxic material
Corrosive material
Target organ effects
HCS Classification
TSCA: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
State Regulations
No products were found.
No products were found.
WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (TOXIC).
Class E: Corrosive liquid.
R14- Reacts violently with water.
R23/24/25- Toxic by inhalation, in contact with skin and if swallowed.
R34- Causes burns.
DSCL (EEC)
International Regulations
Not available.
EINECS
International Lists
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found.
Toxic
No products were found.
State regulations
Date of Previous Issue No Previous
Validation
Not available.
Section 16. Other Information
References
Validated by Company2 on 3/3/2005.
Verified by Company2.
Hazardous Material
Information System
(U.S.A.)
National Fire Protection
Association (U.S.A.)
History of Document Changes Any information changes since last document version are marked with a triangle symbol.
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
Full text of classifications
referred to in sections 2 and 3
-  Europe
Full text of R phrases referred
to in sections 2 and 3  -
Europe
T - Toxic
C - Corrosive
R14- Reacts violently with water.
R23/24/25- Toxic by inhalation, in contact with skin and if swallowed.
R34- Causes burns.
3
0
2
C
*
Health
Fire hazard
Reactivity
Personal protection
2
0
3
Health
Special
Instability
Flammability
Continued on Next Page
PFPI
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Version
0.03
Printed 3/3/2005.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate.  However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and
should be used with caution.  Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.