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MATERIAL SAFETY DATA SHEET MSDS Name: THURMALOX 245C ZINC PRIMER MSDS Number: 245A VOC Version Number MSDS Date: MAR-10-2005 Page Number: 1 -------------------------------------------------------------------------------- ================================================================================ SECTION 1. PRODUCT AND COMPANY INFORMATION -------------------------------------------------------------------------------- Product Name: THURMALOX 245C ZINC PRIMER CAS Number N/A Hazard Rating: Health: 0 Fire: 0 Reactivity: 0 PPI: Company Identification: DAMPNEY CO INC. 85 PARIS ST EVERETT MA 02149-4411 Contact: Peter Barrett Telephone/Fax: (617) 389-2805 (617) 389-0484 Emergency Phone (24 Hour): EVENING ADMINISTRATOR (800) 424-9300 Chemtrec (24 Hour): (800) 424-9300 Product Class PART A OF A TWO PART SYSTEM Trade Name THURMALOX 245C ZINC Product Code 245C PART A ================================================================================ SECTION 2. INGREDIENT AND HAZARD INFORMATION -------------------------------------------------------------------------------- Ingredient Name CAS Number Percent TSCA XYLENE (HAPS) 1330-20-7 16.00 Y 4-METHYL-2-PENTANONE,(HAPS) METHYL 108-10-1 13.82 Y ISOBUTYL KETONE METHYL n-AMYL KETONE 110-43-0 7.62 Y CRYSTALLINE SILICA 14808-60-7 0.10 Y *** ALL Ingredients in this product are listed in the T.S.C.A. Inventory ** SPECIAL REMARKS ON ABOVE LISTED INGREDIENTS ** Technical grade xylene contains 18-20% ethyl benzene CAS # is 100-41-4 and is subject to reporting requirements of SECTION 313 of SARA TITLE III. ACGIH - short term exposure limit (STEL) for MIBK is 75 ppm. NIOSH recommends a limit of 50 ppm, 8-hour TWA. SPECIAL REMARKS SPECIFIC TO THIS RAW MATERIAL NTP and IARC concludes that crystalline silica, (respirable) may reasonably be anticipated to be a carcinogen. National Institute for Occupational Safety and Health (NIOSH) recommends maximum permissible concentration 0.05 mg/m3 as determined by a full shift sample up to 10 hour working day, 40 hour work week. NTP concludes that silica, crystalline (respirable) may be anticipated to be a carcinogen, IARC CLASS 2A. MATERIAL SAFETY DATA SHEET MSDS Name: THURMALOX 245C ZINC PRIMER MSDS Number: 245A VOC Version Number MSDS Date: MAR-10-2005 Page Number: 2 -------------------------------------------------------------------------------- ================================================================================ SECTION 3. PHYSICAL DATA -------------------------------------------------------------------------------- Form: DARK GRAY LIQUID pH Value: Not Applicable Boiling Range: 237.2°F - 304.°F Melting Point: Not Applicable Evaporation Rate: 0.073 times Faster than n-Butyl Acetate Vapor Density: Heavier than air Partition Coefficient Not Available % Volatile Weight 37.51% % Volatile 52.5% Specific Gravity: 1.165 Weight/Gallon: 9.32 lbs VOC 3.67 LBS/GAL Heavy Elements (ppm) 0. ================================================================================ SECTION 4. FIRE AND EXPLOSION HAZARD DATA -------------------------------------------------------------------------------- Flammability Class 1B Flash Range: 60.°F - 102.°F Explosive Range: 1.% 7.9% EXTINGUISHING MEDIA: Foam, alcohol foam, CO2, dry chemical, water fog may be ineffective but should be used to cool fire-exposed containers to prevent pressure build up and possible auto-ignition or explosion when exposed to extreme heat. SPECIAL FIREFIGHTING PROCEDURES: Use full protection equipment including self contained breathing apparatus(NIOSH approved) for respiratory protection in fighting fires in enclosed or confined spaces, or as otherwise needed. Minimize breathing gases, vapors, fumes or decomposition products. UNUSUAL FIRE & EXPLOSION HAZARDS: During emergency conditions, overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. ================================================================================ SECTION 5. HEALTH HAZARD DATA -------------------------------------------------------------------------------- Route Species Exposure and Dose 4-METHYL-2-PENTANONE,(HAPS) METHYL ISOBUTYL KETONE Inhalation Unknown LC50 4000. PPM Oral Unknown LD50 5.7 PPM Skin Unknown LD50 10. PPM Continued MATERIAL SAFETY DATA SHEET MSDS Name: THURMALOX 245C ZINC PRIMER MSDS Number: 245A VOC Version Number MSDS Date: MAR-10-2005 Page Number: 3 -------------------------------------------------------------------------------- ================================================================================ SECTION 5. HEALTH HAZARD DATA Continued -------------------------------------------------------------------------------- METHYL n-AMYL KETONE Inhalation Unknown LC50 4000. PPM Oral Unknown LD50 1600. PPM Skin Unknown LD50 12.6 PPM PERMISSIBLE EXPOSURE LEVEL: SEE SECTION VIII SEE SECTION VIII EFFECTS OF OVEREXPOSURE: Primary route(s) of entry: (X) Dermal (X) Inhalation ( ) Ingestion Acute (short term) exposure: Inhalation - excessive inhalation of vapors can cause nasal and respiratory irritation, cns effects including dizziness, weakness, nausea, headache, possible unconsciousness, and even death. Skin contact - prolonged or repeated contact can cause moderate irritation, defatting, and dermatitis. Eye contact - can cause severe irritation, redness, tearing, and blurred vision. Ingestion - can cause gastrointestinal irritation, nausea, vomiting, and diarrhea. Aspiration of material into the lungs can cause chemical pneumonitis which can be fatal. Pulmonary functions may be reduced by inhalation of respirable crystalline silica. Lung scarring produced by such inhalation may lead to progressive massive fibrosis of the lung which may aggravate other pulmonary conditions and diseases and which increased susceptibility to pulmonary tuberculosis. Progressive massive fibrosis may be accompanied by right heart enlargement, heart failure, and pulmonary failure. Smoking aggravates the effects of exposure. MIBK shortens the time of onset or worsens liver and kidney damage induced by other chemicals. MIBK shortens the time of onset of worsens the neurotoxic effects induced by other chemicals. EMERGENCY AND FIRST AID PROCEDURES: Eyes - flush thoroughly with running water for 15 minutes, including under eyelids. Get medical attention. Skin - promptly remove contaminated clothing and wash affected areas thoroughly with soap and water. If irritation occurs get medical attention. Wash contaminated clothing thoroughly before re-use. Continued MATERIAL SAFETY DATA SHEET MSDS Name: THURMALOX 245C ZINC PRIMER MSDS Number: 245A VOC Version Number MSDS Date: MAR-10-2005 Page Number: 4 -------------------------------------------------------------------------------- ================================================================================ SECTION 5. HEALTH HAZARD DATA Continued -------------------------------------------------------------------------------- Inhalation - if overcome by vapor, remove to an area free from risk of further exposure. If breathing is difficult, administer oxygen, or artificial respiration if breathing has stopped. Keep person warm and quiet and get medical attention. Ingestion - if swallowed, call a physician immediately. Only induce vomiting at the instructions of a physician. Never give anything by mouth to an unconscious person. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: Pre-existing eye, skin, liver and/or kidney disorders may be aggravated by exposure to this product. Chronic (long term) exposure: In laboratory animals - overexposure to this material (or its components) has been found to cause the following effects; anemia, liver abnormalities, kidney, lung and spleen damage. In humans - liver and cardiac abnormalities. Acute and chronic prolonged exposure to respirable crystalline quartz may cause delayed lung injury, (silicosis). Silicosis is a form of disabling pulmonary fibrosis which can be progressive and may lead to death. Chronic overexposure to xylene has been suggested to cause cardiac abnormality in humans. ================================================================================ SECTION 6. STABILITY AND REACTIVITY MEASURES -------------------------------------------------------------------------------- Stability: This product is stable Hazardous Polymerization: Hazardous polymerization will not occur INCOMPATIBILITY: Avoid contact with strong oxidizing agents, acids or bases. CONDITIONS TO AVOID: Avoid heat, open flames. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and unidentified organics may be formed. ================================================================================ SECTION 7. SPILL OR LEAK PROCEDURES -------------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Before attempting cleanup, refer to hazard caution information in other sections of this sheet. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Continued MATERIAL SAFETY DATA SHEET MSDS Name: THURMALOX 245C ZINC PRIMER MSDS Number: 245A VOC Version Number MSDS Date: MAR-10-2005 Page Number: 5 -------------------------------------------------------------------------------- ================================================================================ SECTION 7. SPILL OR LEAK PROCEDURES Continued -------------------------------------------------------------------------------- Large spills - notify safety personnel. Eliminate potential sources of ignition. Wear appropriate respirator and protective clothing. Soak up with an absorbent, I.E. sand, clay, or other suitable material. Place in non-leaking containers and seal tightly for proper disposal. Ventilate confined spaces. Minimize breathing vapors. Open all windows and doors. Minimize skin contact. Keep product out of sewers and water courses by diking and impounding. Observer precautions for volatile, combustible vapors from absorbed material. Small spills - take up with absorbent material and place in non-leaking containers for proper disposal. Use dustless methods (vacuum), or flush with water. Do not dry sweep. WASTE DISPOSAL METHOD: Assure conformity with applicable federal, state and local regulations. Dispose in accordance with Federal, State and Local Regulations. ================================================================================ SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION -------------------------------------------------------------------------------- Occupational Exposure Limits ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL XYLENE (HAPS) 100.00 PPM N/est 150.00 PPM 150.00 PPM 100.00 PPM 4-METHYL-2-PENTANONE,(HAPS) METHYL ISOBUTYL KETONE 50.00 PPM N/est 75.00 PPM 75.00 PPM 100.00 PPM METHYL n-AMYL KETONE 50.00 PPM N/est N/est N/est 100.00 PPM CRYSTALLINE SILICA 0.10 mg/M3 N/est 0.05 mg/M3 0.05 mg/M3 0.10 mg/M3 RESPIRATORY PROTECTION: Use NIOSH approved respirator as required to prevent overexposure. Unconfined spaces - use a vapor/particulate respirator such as NIOSH approved No. TC-23C. Confined spaces - use a constant flow air-line respirator such as NIOSH approved NO. TC-19C. Continued MATERIAL SAFETY DATA SHEET MSDS Name: THURMALOX 245C ZINC PRIMER MSDS Number: 245A VOC Version Number MSDS Date: MAR-10-2005 Page Number: 6 -------------------------------------------------------------------------------- ================================================================================ SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Continued -------------------------------------------------------------------------------- Up to 5 X PEL any dust respirator Up to 10 X PEL any fume respirator or efficiency particulate filter respirator. Up to 50 X PEL a high efficiency particulate filter respirator with full facepiece. Any air supplied respirator with full facepiece helmet or hood. Up to 500 X PEL a powered air purifying respirator with a high efficiency particulate filter. > than 500 X PEL a self contained breathing apparatus with a full facepiece operated in pressure demand or other positive pressure mode. VENTILATION: Provide sufficient ventilation to keep air contaminant concentration below current applicable OSHA permissible exposure limit or ACGIH's TLV limit. No smoking or open lights. PROTECTIVE GLOVES: Use chemical-resistant gloves to prevent skin contact. EYE PROTECTION: Use chemical splash goggles or face shield to prevent eye contact. WEAR PROTECTIVE SAFETY GLASSES WHEN EXPOSED TO DUST PARTICLES. OTHER PROTECTIVE EQUIPMENT: Use chemical-resistant or other protective outerwear to protect against clothing contamination and skin contact. ================================================================================ SECTION 9. SPECIAL PRECAUTIONS -------------------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN HANDLING,TRANSPORTATION,AND STORING: CAUTION! FLAMMABLE! Handling and storage conditions must be suitable for OSHA CLASS I flammable liquid. Store in cool, well-ventilated, fire resistant storage area. Protect containers against physical damage. Keep away from heat, flame, and strong oxidizing agents. Do not store above 100 degrees F. Use only with adequate ventilation. Keep containers closed when not in use. Do not breathe vapor or mist. Avoid contact with eyes, skin and clothing. Do not take internally. Bond and ground containers of this material when pouring to avoid static sparks which create a fire hazard. OTHER PRECAUTIONS: Contact lenses pose a special hazard; soft lenses may absorb and all lenses concentrate irritants. MATERIAL SAFETY DATA SHEET MSDS Name: THURMALOX 245C ZINC PRIMER MSDS Number: 245A VOC Version Number MSDS Date: MAR-10-2005 Page Number: 7 -------------------------------------------------------------------------------- ================================================================================ SECTION 10. REGULATORY INFORMATION -------------------------------------------------------------------------------- SARA TITLE III SECTION 313: This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right to Know Act of 1986 and of 40 CFR 372: Ingredient Name CAS Number Percent XYLENE (HAPS) 1330-20-7 16.00 4-METHYL-2-PENTANONE,(HAPS) METHYL 108-10-1 13.82 ISOBUTYL KETONE -PROP 65 (CARCINOGEN) WARNING: this product contains a chemical known to the state of California to cause cancer. Ingredient Name CAS Number Percent XYLENE (HAPS) 1330-20-7 16.00 CRYSTALLINE SILICA 14808-60-7 0.10 BENZENE 71-43-2 0.03 ====================================================================== The information and recommendation contained herein are based on data believed to be correct. However, Dampney makes no warranty expressed or implied regarding the accuracy of these data or results to be obtained from the use thereof. Dampney assumes no responsibility for personal injury or property damage caused by use of the material described herein. It is the responsibility of the purchaser or user to ensure that this material is properly and safely used. -------------------------------------------------------------------------------- Last Page MATERIAL SAFETY DATA SHEET MSDS Name: ZINC DUST COMPONENT MSDS Number: 2452 Version Number MSDS Date: MAR-10-2005 Page Number: 1 -------------------------------------------------------------------------------- ================================================================================ SECTION 1. PRODUCT AND COMPANY INFORMATION -------------------------------------------------------------------------------- Product Name: ZINC DUST COMPONENT CAS Number N/A Hazard Rating: Health: 0 Fire: 1 Reactivity: 1 PPI: Company Identification: DAMPNEY CO INC. 85 PARIS ST EVERETT MA 02149-4411 Contact: Peter Barrett Telephone/Fax: (617) 389-2805 (617) 389-0484 Emergency Phone (24 Hour): EVENING ADMINISTRATOR (800) 424-9300 Chemtrec (24 Hour): (800) 424-9300 Product Class ZINC DUST FOR 210 & 245 PRIMER Trade Name ZINC DUST COMPONENT Product Code 2452 =============================================================================== SECTION 2. INGREDIENT AND HAZARD INFORMATION -------------------------------------------------------------------------------- Ingredient Name CAS Number Percent TSCA *ZINC DUST 7440-66-6 100.00 Y *** ALL Ingredients in this product are listed in the T.S.C.A. Inventory ================================================================================ SECTION 3. PHYSICAL DATA -------------------------------------------------------------------------------- Form: GRAY POWDER Odor: NONE pH Value: Not Applicable Boiling Range: N/A 0.°F Melting Point: Not Applicable Evaporation Rate: Non Volatile Vapor Density: Heavier than air Partition Coefficient Not Available % Volatile Weight 0.% % Volatile NONE 0.% Specific Gravity: 7.101 Weight/Gallon: 59.17 lbs VOC NONE Heavy Elements (ppm) 0. MATERIAL SAFETY DATA SHEET MSDS Name: ZINC DUST COMPONENT MSDS Number: 2452 Version Number MSDS Date: MAR-10-2005 Page Number: 2 -------------------------------------------------------------------------------- ================================================================================ SECTION 4. FIRE AND EXPLOSION HAZARD DATA -------------------------------------------------------------------------------- Flammability Class Flash Range: NONE Explosive Range: 0.5 oz/ft3 0.% 0.% EXTINGUISHING MEDIA: CLASS D Extinguisher. Dry powder type. Avoid water. ***AVOID WATER*** SPECIAL FIREFIGHTING PROCEDURES: Dry zinc dust will not ignite spontaneously; but once ignited may burn readily in air. Do not spread material. Smother and allow fire to go out. Wear self-contained breathing apparatus. UNUSUAL FIRE & EXPLOSION HAZARDS: Bulk dust in contact with water or damp air evolves hydrogen. The heat produced during this reaction could ignite the hydrogen. An explosive condition may exist if this happens in a confined space. Dry dust forms explosive mixtures with air. ================================================================================ SECTION 5. HEALTH HAZARD DATA -------------------------------------------------------------------------------- Route Species Exposure and Dose *ZINC DUST Inhalation Unknown LD50 124. PPM PERMISSIBLE EXPOSURE LEVEL: 15 mg/m3 EFFECTS OF OVEREXPOSURE: None. However zinc oxide fume may result from combustion of zinc dust. Excessive inhalation of this fume may produce symptoms known as fume fever or "zinc shakes". EMERGENCY AND FIRST AID PROCEDURES: Symptoms usually disappear within 24 hours. Symptomatic treatment such as bed rest, possibly aspirin, to afford relief from fever and chills. Obtain medical attention. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: None known. MATERIAL SAFETY DATA SHEET MSDS Name: ZINC DUST COMPONENT MSDS Number: 2452 Version Number MSDS Date: MAR-10-2005 Page Number: 3 -------------------------------------------------------------------------------- ================================================================================ SECTION 6. STABILITY AND REACTIVITY MEASURES -------------------------------------------------------------------------------- Stability: This product is stable Hazardous Polymerization: Hazardous polymerization will not occur INCOMPATIBILITY: Avoid contact with water, acids, and alkalis. CONDITIONS TO AVOID: Moisture, heat, flame, other sources of ignition. HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen gas when in contact with water. ================================================================================ SECTION 7. SPILL OR LEAK PROCEDURES -------------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Prohibit smoking, avoid all ignition sources, and avoid dusting. Small spills: take up with absorbent material and place in non-leaking containers for proper disposal. WASTE DISPOSAL METHOD: Assure confromity with applicable Federal, State and Local Regulations. ================================================================================ SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION -------------------------------------------------------------------------------- Occupational Exposure Limits ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL -------------------------------------------------------------------------------- *ZINC DUST 10.00 mg/M3 N/est N/est N/est 10.00 mg/M3 RESPIRATORY PROTECTION: Use NIOSH approved respirator as required to prevent overexposure. VENTILATION: Provide sufficient ventilation to keep air contaminant concentration below current applicable OSHA permissible exposure limit or ACGIS's TLV limit. PROTECTIVE GLOVES: Recommended. EYE PROTECTION: Use splash goggles or face shield to prevent eye contact. OTHER PROTECTIVE EQUIPMENT: Fire resistant coveralls are recommended. MATERIAL SAFETY DATA SHEET MSDS Name: ZINC DUST COMPONENT MSDS Number: 2452 Version Number MSDS Date: MAR-10-2005 Page Number: 4 -------------------------------------------------------------------------------- ================================================================================ SECTION 9. SPECIAL PRECAUTIONS -------------------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN HANDLING,TRANSPORTATION,AND STORING: Protect against physical damage. Store in cool, dry, ventilated space, separate from acids and alkalis. OTHER PRECAUTIONS: Keep areas where zinc dust is stored and/or used free from all ignition sources. ================================================================================ SECTION 10. REGULATORY INFORMATION -------------------------------------------------------------------------------- SARA TITLE III SECTION 313: This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right to Know Act of 1986 and of 40 CFR 372: Ingredient Name CAS Number Percent *ZINC DUST 7440-66-6 100.00 ================================================================= The information and recommendations contained herein are based on data believed to be correct. However, Dampney makes no warranty expressed or implied regarding the accuracy of these data or results to be obtained from the use thereof. Dampney assumes no responsibility for personal injury or property damage caused by use of the material described herein. It is the responsibility of the purchaser or user to ensure that this material is properly and safely used. -------------------------------------------------------------------------------- Last Page
