MATERIAL SAFETY DATA SHEET
POLYCARBONATE (ALL GRADES)
3. HAZARDS IDENTIFICATION
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON (416) 226-6117 Montreal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Brenntag Canada Inc.
43 Jutland Rd.
Toronto, ON
M8Z 2G6
(416) 259-8231
Website: http:\\www.brenntag.ca
WHMIS#:
00062087
Index:
2006 November 17
PRODUCT IDENTIFICATION
Polycarbonate (All Grades).
Product Name:
2006 November 17
Date of Revision:
Effective Date:
HCI0945/06D
Polycarbonate.
Chemical Name:
Durolon HFR1900, HFV1900, HFV1910, I2200, I2700, IR200, IR2000, IR2200, V2000, V2200, V2210,
VR2000, VR2200, V2600, V2602; Ashlene PC 1500 WO BK, PC 1500-10G WO BK; Polycarbonate;
Poly(bisPhenol-A Carbonate); Polymeric condensate of Phosgene and bisPhenol-A.
Synonyms:
Polymer.
Chemical Family:
Not available.
Molecular Formula:
Melt processible plastic resin for extrusion, blow, injection or rotational moulding.
Product Use:
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
D-2B: Toxic (skin and eye irritant)
Ingredient
CAS#
ACGIH TLV
% Concentration
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
Polycarbonate
25971-63-5
---
95 - 99
Poly (butadiene acrylate / methyl
methacrylate)
25852-37-3
---
2
Additives
Not available.
---
<1
Glass
65997-17-3
---
Triphenyl phosphate
115-86-6
3 mg/m3
*A4
A4 = Not classifiable as a human carcinogen. (ACGIH-A4).
Polycarbonate (All Grades)
Brenntag Canada Inc.
Date of Revision: 2006 November 17
WHMIS Number :
00062087
Page 2 of 8
4. FIRST AID MEASURES
FIRST AID PROCEDURES
Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Give
cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse. Obtain medical attention
IMMEDIATELY.
Inhalation:
At normal temperatures : Start flushing while removing contaminated clothing. Wash affected areas
thoroughly with soap and water. If irritation, redness, or a burning sensation develops and persists,
obtain medical advice.
At processing temperatures : Contact with hot molten plastics cause severe burns to skin contact
areas and eyes. Generally, it is recommended not to remove plastic that has hardened in contact with
skin, but to cool it by gently flooding that area with copious quantities of cool water. In all such cases,
immediately seek medical attention. See "Note to Physicians" below.
Skin Contact:
Immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during
flushing. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY. At processing
temperatures : See "Note to Physicians" below.
Eye Contact:
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not
convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material. DO NOT induce
vomiting. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing
in of vomitus, rinse mouth and administer more water. Obtain medical attention IMMEDIATELY.
Ingestion:
At normal temperatures : Low hazard for usual industrial or commercial handling. Dust may cause
mechanical irritation to skin, eyes and respiratory tract. At processing temperatures : Contact with
molten material may cause severe thermal burns. Vapours are irritating to eyes and respiratory tract.
High vapour concentrations may cause drowsiness. See "Other Health Effects" Section. Can
decompose at high temperatures forming toxic gases.
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS
At normal temperatures : Inhalation is not a likely route of exposure at normally encountered
temperatures. At processing temperatures : Vapour from warmed or heated material may cause
nausea and dizziness. See "Other Health Effects" Section.
Inhalation:
At normal temperatures : Product has a tendency to cling to skin due to static charge. Care must be
exercised to remove all product from skin. (3) This product may cause irritation due to abrasive action.
Skin contact can cause irritation, especially under the finger nails (and other confined spaces such as
under rings or watch bands). At processing temperatures : Burns (thermal) can occur if not promptly
removed.
Skin Contact:
Not likely to be absorbed through the skin.
Skin Absorption:
At normal temperatures : This product may cause irritation, redness and possible damage due to
abrasiveness. At processing temperatures : Burns (thermal) can occur if not promptly removed. This
product causes immediate pain, severe burns and permanent corneal damage which may result in
blindness.
Eye Contact:
At normal temperatures : Ingestion of large amounts may cause intestinal obstruction. At processing
temperatures : Ingestion is not a likely route of exposure.
Ingestion:
Effects (irritancy) on the skin and eyes may be delayed, and damage may occur without the sensation
or onset of pain. Strict adherence to first aid measures following any exposure is essential. Not for
injection into humans.
At ambient temperatures, material is a coarsely divided solid and is inert and essentially harmless. It
can present a slippage hazard. Under normal processing conditions, the material is a hot polymer.
Contact with hot molten materials cause severe burns to skin contact areas and eyes. Generally, it is
recommended not to remove material that has hardened in contact with skin, but to cool it by gently
flooding the area with copious quantities of cool water. In all such cases, immediately seek medical
attention. Prolonged exposure to processing fumes may cause eye and respiratory tract irritation.
Overexposure may cause headaches and nausea.
At processing temperatures : May cause central nervous system (CNS) depression. CNS depression
is characterized by headache, dizziness, drowsiness, nausea, vomiting and incoordination. Severe
overexposures may lead to coma and possible death due to respiratory failure.
Other Health Effects:
Polycarbonate (All Grades)
Brenntag Canada Inc.
Date of Revision: 2006 November 17
WHMIS Number :
00062087
Page 3 of 8
At normal temperatures : Treat symptomatically.
Treatment for thermal, surface burns:
1. Immerse the burned part immediately in ice water to relieve pain and to prevent swelling and
blistering. Place cold packs, ice or wet cloths on the burned area if immersion is not possible.
2. Remove anything that is constrictive, such as rings, bracelets or footwear, beforeswelling begins.
3. Cover the burn with a clean, preferably sterile, lint-free dressing.
4. For severe burns, immediately seek medical attention and monitor breathing andtreat for shock.
Medical conditions that may be aggravated by exposure to this product include diseases of the skin,
eyes or respiratory tract.
Note to Physicians:
5. FIRE-FIGHTING MEASURES
Flashpoint (°C)
AutoIgnition
Temperature (°C)
LEL
UEL
Flammability Limits in Air (%):
> 450. (3)
450. (3)
Not available.
Not available.
Not regulated.
Flammability Class (WHMIS):
Thermal decomposition products are toxic and may include Bisphenol A, diphenyl carbonate,
monochlorobenzene, phenol, substituted phenols, oxides of carbon and irritating gases. Heating in air
may produce irritating aldehydes, acids and ketones.
Hazardous Combustion
Products:
Avoid accumulation and dispersion of dust to reduce explosion potential. Spilled material may cause
floors and contact surfaces to become slippery.
Unusual Fire or Explosion
Hazards:
Not expected to be sensitive to mechanical impact.
Sensitivity to Mechanical Impact:
Not available.
Rate of Burning:
Not available.
Explosive Power:
Not expected to be sensitive to static discharge.
Sensitivity to Static Discharge:
EXTINGUISHING MEDIA
Use carbon dioxide or dry chemical media for small fires. If only water is available, use it in the form of
a fog. Most resins melt when they burn. Fire spread is accelerated by burning and dripping of flaming
melt. Once fire becomes established it will develop rapidly and application of large quantities of water
at early stage is necessary to effect extinguishment. (4)
Fire Extinguishing Media:
FIRE FIGHTING
INSTRUCTIONS
Use water spray to cool fire-exposed containers or structures. Use water spray to disperse vapours; re-
ignition is possible. Use self-contained breathing apparatus and protective clothing. Isolate materials
that are not involved in the fire and protect personnel. Clean up immediately to eliminate slipping
hazard. Do not allow to enter sewers or watercourses.
Instructions to the Fire Fighters:
Use self-contained breathing apparatus and protective clothing.
Fire Fighting Protective
Equipment:
6. ACCIDENTAL RELEASE MEASURES
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons,
property and the environment. There may be specific reporting requirements associated with spills, leaks or releases, which change from
region to region.
Polycarbonate (All Grades)
Brenntag Canada Inc.
Date of Revision: 2006 November 17
WHMIS Number :
00062087
Page 4 of 8
In all cases of leak or spill contact vendor at Emergency Number shown on the front page of this MSDS.
Spilled material may cause floors and contact surfaces to become slippery. Eliminate all sources of
ignition. Wear respirator, protective clothing and gloves. Avoid dry sweeping. Do not use compressed
air to clean surfaces. Vacuuming or wet sweeping is preferred. Return all material possible to
container for proper disposal.
Where a package (drum or bag) is damaged and / or leaking, repair it, or place it into an over-pack
drum immediately so as to avoid or minimize material loss and contamination of surrounding
environment.
In order to prevent marine species and birds from ingesting pellets, emphasis should be placed on total
containment of plastic pellets through their lifespan. Avoid contaminating soil or releasing this material
into sewage and drainage systems and bodies of water. (3)
Containment and Clean-Up
Procedures:
7. HANDLING AND STORAGE
HANDLING
Use normal "good" industrial hygiene and housekeeping practices. Clean up immediately to eliminate
slipping hazard.
At ambient temperatures, material is a coarsely divided solid and is inert and essentially harmless. It
can present a slippage hazard. Under normal processing conditions, the material is a hot, molten
plastic. Contact with hot molten plastics cause severe thermal burns to skin contact areas and eyes.
The interior of molten masses may remain hot for some time because of low thermal conductivity of the
polymer. Generally, it is recommended not to remove plastic that has hardened in contact with skin, but
to cool it by gently flooding the area with copious quantities of cool water. In all such cases,
immediately seek medical attention.
Pneumatic conveying of this product can generate fines and dust particles that can, under certain
conditions, pose an explosion hazard. We recommend that the conveying system used be: (1)
equipped with filters of adequate size; (2) operated and maintained in such a manner to ensure that no
leaks develop; and (3) adequately grounded.
In order to avoid autoignition / hazardous decomposition of hot thick masses of plastic, purging should
be collected in small, flat shapes or thin strands to allow for rapid cooling, followed immediately by a
quench in water. (3)
The product (as is) or during its use, does not produce dust. The different components and fillers are
incorporated in the bulk of the polymer. (3)
Handling Practices:
Provide adequate mechanical ventilation at the points of extrusion where the polymer is at elevated
temperatures coming from extruder into dies, molds etc. (3) Volatile constituents of this product may
gradually degrade canvas, cloth or plastic components such as seals and flexible tube coverings of
adjustable point source ventilation equipment. Preventative programs should consider this. See Section
8, "Engineering Controls".
Ventilation Requirements:
Use only with adequate ventilation and avoid breathing dusts or vapours. Avoid contact with eyes, skin
or clothing. Wash thoroughly with soap and water after handling. Wash contaminated clothing
thoroughly before re-use.
Other Precautions:
STORAGE
93.
Storage Temperature (°C):
Local exhaust ventilation required.
Ventilation Requirements:
Store in a cool, well-ventilated area. Keep away from heat, sparks and flames. Keep containers closed.
Avoid moisture contamination. Protect against physical damage.
Storage Requirements:
Materials of construction for storing the product include: Multi-layer polyethylene, bags or sacks.
Confirm suitability of any material before using.
Special Materials to be Used for
Packaging or Containers:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this
product. Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific
protective devices at your workplace.
ENGINEERING CONTROLS
Polycarbonate (All Grades)
Brenntag Canada Inc.
Date of Revision: 2006 November 17
WHMIS Number :
00062087
Page 5 of 8
Local exhaust ventilation required. Make up air should be supplied to balance air that is removed by
local or general exhaust ventilation. Ventilate low lying areas such as sumps or pits where dense dust
may collect. Volatile constituents of this product may gradually degrade canvas, cloth or plastic
components such as seals and flexible tube coverings of adjustable point source ventilation equipment.
Preventative programs should consider this.
Engineering Controls:
PERSONAL PROTECTIVE
EQUIPMENT (PPE)
At normal temperatures : Safety glasses with side shields are recommended to prevent eye contact.
Contact lenses should not be worn when working with this material.
At processing temperatures : Use full face-shield and chemical safety goggles when there is potential
for contact.
Eye Protection:
At normal temperatures : Gloves and protective clothing made from cotton, canvas, rubber or plastic
should be impervious under conditions of use. Prior to use, user should confirm impermeability.
Discard contaminated gloves.
At processing temperatures : Skin protection should be insulated against hot or high temperatures.
Skin Protection:
At normal temperatures : No specific guidelines available. A NIOSH/MSHA-approved air-purifying
respirator equipped with dust, mist, fume cartridges for concentrations up to 100 mg/m³ particulate. An
air-supplied respirator if concentrations are higher or unknown.
At processing temperatures : A NIOSH/MSHA-approved air-purifying respirator equipped with dust,
mist, fume cartridges for concentrations up to 100 ppm Monochlorobenzene or 1 000 ppm organic
vapours. An air-supplied respirator if concentrations are higher or unknown.
If while wearing a respiratory protection, you can smell, taste or otherwise detect anything unusual, or in
the case of a full facepiece respirator you experience eye irritation, leave the area immediately. Check
to make sure the respirator to face seal is still good. If it is, replace the filter, cartridge or canister. If
the seal is no longer good, you may need a new respirator. (4)
Respiratory Protection:
Wear regular work clothing. The use of coveralls is recommended. Locate safety shower and eyewash
station close to chemical handling area. Take all precautions to avoid personal contact.
Other Personal Protective
Equipment:
Particulate Not Otherwise Classified:
ACGIH OSHA
10 mg/m³ - Inhalable particulate 50 mppcf* or 15 mg/m³ - Total Dust
3 mg/m³ - Respirable particulate 15 mppcf* or 5 mg/m³ - Respirable Fraction
* mppcf = million particles per cubic foot
EXPOSURE GUIDELINES
SUBSTANCE
ACGIH TLV
(STEL)
OSHA PEL
(TWA) (STEL)
NIOSH REL
(TWA) (STEL)
Triphenyl phosphate
—
3 mg/m3
---
3 mg/m3
---
Solid.
Opaque pellets.
Slight plastic odour.
Not applicable.
380 (decompose). (4)
220 - 230. (3)
Negligible.
Not available.
1.2. (3)
38 - 42 lb/ft3. (4)
Not applicable.
Not applicable.
Not soluble in water.
Negligible.
Not available.
Not available.
Physical State:
Appearance:
Odour:
Odour Threshold (ppm):
Boiling Range (°C):
Melting/Freezing Point (°C):
Vapour Pressure (mm Hg at 20° C):
Vapour Density (Air = 1.0):
Relative Density (g/cc):
Bulk Density:
Viscosity:
Evaporation Rate (Butyl Acetate = 1.0):
Solubility:
% Volatile by Volume:
pH:
Coefficient of Water/Oil Distribution:
9. PHYSICAL AND CHEMICAL PROPERTIES (Not intended as Specifications)
Polycarbonate (All Grades)
Brenntag Canada Inc.
Date of Revision: 2006 November 17
WHMIS Number :
00062087
Page 6 of 8
Negligible.
Volatile Organic Compounds (VOC):
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL DATA:
SUBSTANCE
LD50 (Oral, Rat)
LD50 (Dermal, Rabbit)
LC50 (Inhalation, Rat, 4h)
Polycarbonate
> 5 000 mg/kg (3)
---
---
Triphenyl phosphate
3 500 mg/kg (1)
> 7 900 mg/kg (1)
---
The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP.
Carcinogenicity Data:
No adverse reproductive effects are anticipated.
Reproductive Data:
No adverse mutagenic effects are anticipated.
Mutagenicity Data:
No adverse teratogenic effects are anticipated.
Teratogenicity Data:
None known.
Respiratory / Skin Sensitization
Data:
None known.
Synergistic Materials:
Glass : Test animals breathing very high concentrations of respirable fibers on a long-term basis
developed fibrosis, lung cancer and mesothelioma. (3)
Other Studies Relevant to
Material:
12. ECOLOGICAL INFORMATION
Not available. No adverse effect reported, toxicity to fish, aquatic species reported as negligible. (3)
The effects of resin pellets on the wildlife that may ingest them is not well understood. In the case of
seabirds, some marine biologists believe that the fowl may not be able to pass plastic pellets through
their digestive tracts. Thus, large quantities of ingested pellets may cause intestinal blockage, false
feelings of satiation or reduction in absorption of nutrients, causing malnutrition and starvation. (3)
Ecotoxicity:
Not available. This material is not considered to be biodegradable. (3) Do not contaminate domestic or
irrigation water supplies, lakes, streams, ponds, or rivers.
Environmental Fate:
13. DISPOSAL CONSIDERATIONS
None required.
Deactivating Chemicals:
This information applies to the material as manufactured. Reevaluation of the product may be required
by the user at the time of disposal since the product uses, transformations, mixtures and processes
may influence waste classification. Dispose of waste material at an approved (hazardous) waste
treatment/disposal facility in accordance with applicable local, provincial and federal regulations. Do not
dispose of waste with normal garbage, or to sewer systems.
Waste Disposal Methods:
Empty containers retain product residue. No special treatment required.
Safe Handling of Residues:
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY
Stable.
Under Normal Conditions:
Not readily flammable, but will support combustion.
Under Fire Conditions:
Will not occur.
Hazardous Polymerization:
High temperatures, sparks, open flames and all other sources of ignition. Avoid moisture contamination.
Avoid accumulation and dispersion of dust to reduce explosion potential.
Conditions to Avoid:
Strong oxidizers. Lewis or mineral acids. Strong bases.
Materials to Avoid:
Thermal decomposition products are toxic and may include Bisphenol A, diphenyl carbonate,
monochlorobenzene, phenol, substituted phenols, oxides of carbon and irritating gases. Heating in air
may produce irritating aldehydes, acids and ketones.
Decomposition or Combustion
Products:
Polycarbonate (All Grades)
Brenntag Canada Inc.
Date of Revision: 2006 November 17
WHMIS Number :
00062087
Page 7 of 8
Recycling is encouraged. Treat package in the same manner as the product. Empty package may be
disposed of with normal garbage. Dispose of waste material at an approved landfill site in accordance
with applicable local, provincial and federal regulations.
Disposal of Packaging:
14. TRANSPORTATION INFORMATION
CANADIAN TDG ACT SHIPPING DESCRIPTION:
This product is not regulated by TDG.
Label(s): Not applicable. Placard: Not applicable.
ERAP Index: -----.
Exemptions: None known.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
This product is not regulated by DOT.
Label(s): Not applicable. Placard: Not applicable.
CERCLA-RQ: Not available.
Exemptions: None known.
15. REGULATORY INFORMATION
CANADA
All constituents of this product are included on the DSL.
CEPA - NSNR:
Not included.
CEPA - NPRI:
Controlled Products Regulations Classification (WHMIS):
D-2B: Toxic (skin and eye irritant)
USA
All constituents of this product are included on the TSCA inventory.
Environmental Protection Act:
Skin and Eye Irritant.
OSHA HCS (29CFR 1910.1200):
Text22:
NFPA: Health, Fire, Reactivity (Not available.)
Text22:
HMIS: 1 Health, 1 Fire, 0 Reactivity (6)
INTERNATIONAL
Not available.
16. OTHER INFORMATION
REFERENCES
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS
database.
1.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons,
New York, 1981.
2.
Supplier's Material Safety Data Sheet(s)
3.
CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
4.
Guide to Occupational Exposure Values, 2005, American Conference of Governmental Industrial Hygienists, Cincinnati, 2005.
5.
Regulatory Affairs Group, Brenntag Canada Inc.
6.
The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical
Association, Ottawa, 1981.
7.
____________________________________________________________________________________________________________
The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith
by technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions of use and handling may
involve other and additional considerations. No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for
any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained
herein. This Material Safety Data Sheet is valid for three years.
____________________________________________________________________________________________________________
Polycarbonate (All Grades)
Brenntag Canada Inc.
Date of Revision: 2006 November 17
WHMIS Number :
00062087
Page 8 of 8
To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia: 20333-102B Avenue, Langley, BC, V1M 3H1
Phone: (604) 513-9009 Facsimile: (604) 513-9010
Alberta: 6628 - 45 th. Street, Leduc, AB, T9E 7C9
Phone: (780) 986-4544 Facsimile: (780) 986-1070
Manitoba: 681 Plinquet Street, Winnipeg, MB, R2J 2X2
Phone: (204) 233-3416 Facsimile: (204) 233-7005
Ontario: 43 Jutland Road, Toronto, ON, M8Z 2G6
Phone: (416) 259-8231 Facsimile: (416) 259-6175
Quebec: 2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8
Phone: (514) 636-9230 Facsimile: (514) 636-0877
Atlantic: A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7
Phone: (902) 468-9690 Facsimile: (902) 468-3085
____________________________________________________________________________________________________________
Prepared By: Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.