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MATERIAL SAFETY DATA SHEET Product Name: HAVOC® XT BLOK KILLS RATS & MICE 1 Hacco, Inc. In Case of Emergency, Call 110 Hopkins Drive 1-800-888-8372 Randolph, WI 53956 (Syngenta Emergency Hotline) (920) 326-2477 (Registration Office) (920) 326-2461 (Manufacturing Location) 1. PRODUCT IDENTIFICATION Product Name: HAVOC® XT BLOK KILLS RATS & MICE EPA Signal Word: CAUTION Active Ingredient(%): Brodifacoum Technical (0.005%) CAS No.: 56073-10-0 Chemical Name: 3-[3-(4’-bromo[1,1’-biphenyl]-4-yl)-1,2,3,4-tetrahydro-1-naphthalenyl]-4-hydroxy-2H-1- benzopyran-2-one Chemical Class: A coumarin-type anticoagulant rodenticide. EPA Registration Number: 100-1055-61282 Section(s) Revised: 2 2 . COMPOSITION/INFORMATION ON INGREDIENTS Material OSHA PEL ACGIH TLV Other NTP/IARC/OSHA Carcinogen Paraffin Wax Not Established Not Established Not Established No Cereal Ingredients Not Established Not Established Not Established No Blue Pigment Not Established Not Established Not Established No Brodifacoum Technical (0.005%) Not Established Not Established 0.002 mg/m3 TWA*** No *** Syngenta Occupational Exposure Limit (OEL) Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications. Syngenta Hazard Category: A 3 . HAZARDS IDENTIFICATION Symptoms of Acute Exposure Slightly irritating to the eyes. The active ingredient is designed to cause bleeding after repeated ingestion. Hazardous Decomposition Products Can decompose at high temperatures forming toxic gases. Physical Properties Appearance: Blue solid Odor: Slight cereal and wax odor Unusual Fire, Explosion, and Reactivity Hazards During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. MATERIAL SAFETY DATA SHEET Product Name: HAVOC® XT BLOK KILLS RATS & MICE 2 4. FIRST AID MEASURES Have the product container, label, or Material Safety Data Sheet with you when calling Syngenta (800-888-8372), a poison control center or doctor, or going for treatment. Ingestion: If swallowed: Call Syngenta (800-888-8372), a poison control center or doctor immediately for treatment advice. Have the person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so after calling 800-888-8372 or by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Eye Contact: If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta (800-888-8372), a poison control center or doctor for treatment advice. Skin Contact: If on skin or clothing: Take off contaminated clothing. Wash skin with soap and water. Inhalation: Not applicable. Notes to Physician This product contains anticoagulants with an effect similar to warfarin in that they act by interfering with the synthesis of prothrombin. The specific measure is the prothrombin time. Note this may not become prolonged until 12-18 hours after ingestion. The specific antidote is Vitamin K1 (Phytomenandione BP). Antidote must be administered under medical supervision. Initially, antidote should be given by injection (10-20 mg, or 0.25 mg/kg for children, by slow intravenous infusion at a rate of 1 mg/minute. In severe cases the use of fresh frozen plasma may be required). Maintenance treatment is given orally (40 mg/day in divided doses for adults; up to 20 mg/day in divided doses for children). The prothrombin time and the hemoglobin should be monitored. Patients should be kept under medical supervision until the prothrombin time has been normal for 3 consecutive days. Oral treatment may need to be continued for several months. (20 mg/day in divided doses for adults, and up to 20 mg/day in divided doses for children). (For animal cases the dose is 2-5 mg/kg). Each 20g bar contains 1mg of brodifacoum. Medical Condition Likely to be Aggravated by Exposure As stated above this product contains anticoagulants with an effect similar to that of Warfarin. The anticoagulant interferes with the synthesis of prothrombin. Significant exposure (e.g. ingestion) can cause anticoagulation effects and could aggravate existing blood clotting disorders. 5 . FIRE FIGHTING MEASURES Fire and Explosion Flash Point (Test Method): > 375°F (paraffin wax) Method: PMCC Flammable Limits (% in Air): Lower: % Not Applicable Upper: % Not Applicable Autoignition Temperature: Not Available Flammability: Not Flammable Unusual Fire, Explosion, and Reactivity Hazards During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. In Case of Fire Use dry chemical, foam or CO2 extinguishing media. Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes, or products of combustion. Prevent use of contaminated buildings, area, and equipment until decontaminated. 6. ACCIDENTAL RELEASE MEASURES In Case of Spill or Leak Control the spill at its source. Clean up spills immediately, observing precautions outlined in Section 8. Sweep up material and place in a compatible disposal container. Once all material is collected, seal container and arrange for disposition. MATERIAL SAFETY DATA SHEET Product Name: HAVOC® XT BLOK KILLS RATS & MICE 3 7 . HANDLING AND STORAGE Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. 8 . EXPOSURE CONTROLS/PERSONAL PROTECTION THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION, PACKAGING, AND USE OF THIS PRODUCT. OR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL. F Ingestion: Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Eye Contact: Eye protection is not required for normal handling. Where eye contact is likely, wear tight-fitting chemical goggles. Skin Contact: Gloves are not required for normal handling. Where heavy contact is likely, wear chemical resistant (such as nitrile or butyl) gloves. Inhalation: Respiratory protection is not required for normal handling. In the event of an usual dust exposure, use engineering controls or a NIOSH-approved particulate respirator (N, P, R, or HE filter) to keep exposure below the Occupational Exposure Limit. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Blue solid Odor: Slight cereal and wax odor Melting Point: 130°F (paraffin wax) Boiling Point: Not Available Specific Gravity/Density: 1.15 g/ml pH: Not Available Solubility in H20 Brodifacoum Technical: Insoluble Vapor Pressure Brodifacoum Technical: 6 x 10(-6) mmHg @ 68°F (20°C) 10. STABILTY AND REACTIVITY Stability: Stable under normal use and storage conditions. Hazardous Polymerization: Will not occur. Conditions to Avoid: None known. Materials to Avoid: None known. Hazardous Decomposition Products: Can decompose at high temperatures forming toxic gases. MATERIAL SAFETY DATA SHEET Product Name: HAVOC® XT BLOK KILLS RATS & MICE 4 11. TOXICOLOGICAL INFORMATION Acute Toxicity/Irritation Studies (Finished Product) Ingestion: Practically Non-Toxic Oral (LD50 Rat) : > 5,000 mg/kg body weight Dermal: Not Available Dermal (LD50 Rat) : See “Other Toxicity Information,” Section 11 Inhalation: Not Available Inhalation (LC50 Rat) : See “Other Toxicity Information,” Section 11 Eye Contact: See “Other Toxicity Information,” Section 11 Skin Contact: See “Other Toxicity Information,” Section 11 Skin Sensitization: Not Available Reproductive/Developmental Effects Brodifacoum Technical: Not teratogenic, embryotoxic or fetotoxic in rats or rabbits at doses up to 0.02 mg/kg/day – the dose causing excessive maternal toxicity. Non-genotoxic in a range of assays. Chronic/Subchronic Toxicity Studies Brodifacoum Technical: The biological half-life for brodifacoum in body tissue in rats is > 100 days. Adverse clinical effect can develop from body accumulation. Prolonged prothrombin time, depression, pallor, subcutaneous hemorrhage, bleeding of nose or gums, gastrointestinal hemorrhage, cerebral hemorrhage, shock and death can develop following exposures. No neurotox studies have been conducted. Carcinogenicity Brodifacoum Technical: Unlikely to be carcinogenic. Other Toxicity Information Effects of overexposure are those of anticoagulant overdose, i.e., reduced blood clotting ability with spontaneous bleeding in various organs. Body accumulation can result from repeated exposures since the half-life of brodifacoum is > 100 days. Individuals with blood clotting disorders may be more susceptible to overexposure effects. Systemically toxic concentrations of this product will probably not be absorbed through human skin. Because this product is a wax block, inhalation is not expected to be a normal route of exposure. No irritation is likely to develop following contact with human eyes. Irritation will probably not develop following contact with human skin. Toxicity of Other Components Blue Pigment: Not Applicable Cereal Ingredients: Not Applicable Paraffin Wax: Not Applicable Target Organs Active Ingredients Brodifacoum Technical: Blood Inactive Ingredients Blue Pigment: Not Applicable Cereal Ingredients: Not Applicable Paraffin Wax: Not Applicable 12. ECOLOGICAL INFORMATION Summary of Effects Brodifacoum Technical: The risk of this formulation to most non-target organisms is low. However, if this product is misused or stored improperly, birds and other non-target animals may be at higher risk. MATERIAL SAFETY DATA SHEET Product Name: HAVOC® XT BLOK KILLS RATS & MICE 5 Eco-Acute Toxicity Brodifacoum Technical: Fish (Trout) 96-hr LC50 0.04 ppm Invertebrates (Daphnia) 48-hr EC50 0.06 ppm Birds (8-day dietary – Bobwhite Quail) 40-day LC50 0.8 ppm Birds (8-day dietary – Mallard Duck) 40-day LC 50 2.7 ppm Formulation (Predicted): Fish (Trout) 96-hr LC50 800 ppm Invertebrates (Daphnia) 48-hr EC50 1,200 ppm Birds (8-day dietary – Bobwhite Quail) LC50 16,000 ppm Birds (8-day dietary – Mallard Duck) LC50 54,000 ppm Eco-Chronic Toxicity Brodifacoum Technical: Not applicable studies available. Environmental Fate Brodifacoum Technical: The information presented here is for the active ingredient brodifacoum. Not persistent in soil. Stable in water. Immobile in soil. Sinks in water (after 24 hours). 1 3. DISPOSAL CONSIDERATIONS Disposal Do not reuse empty container except for holding additional product. Characteristic Waste: Not Applicable Listed Waste: Not Applicable 14. TRANSPORT INFORMATION DOT Classification Not regulated B/L Freight Classification Exterminator, Vermin, O/T Poison Comments International Transportation Environmentally Hazardous Substance, Solid, N.O.S. (brodifacoum), Class 9, UN3077, PGIII 5 kg and smaller package sizes – Limited Quantity 1 5. REGULATORY INFORMATION EPA SARA Title III Classification Section 311/312 Hazard Classes: Acute Health Hazard Section 313 Toxic Chemicals: Not Applicable California Proposition 65 Not Applicable CERLA/SARA 302 Reportable Quantity (RQ) None RCRA Hazardous Waste Classification (40 CFR 261) Not Applicable TSCA Status Exempt from TSCA, subject to FIFRA MATERIAL SAFETY DATA SHEET Product Name: HAVOC® XT BLOK KILLS RATS & MICE 6 16. OTHER INFORMATION NFPA Hazard Ratings HMIS Hazard Ratings 0 - Minimal Health: 1 Health: 1 1 - Slight Flammability: 1 Flammability: 1 2 - Moderate Instability: 0 Reactivity: 0 3 - Serious 4 - Extreme For Non-Emergency Questions About This Product Call: 1-800-621-8829 Neogen Corporation Lexington, KY Original Issue Date: July 2004 Revision Date: April 27th, 2006 Replaces: October 21st, 2005 Revision Date of Syngenta MSDS: April 10th, 2006 HAVOC® is a registered trademark of a Syngenta Group Company. ALTHOUGH THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN (HEREINAFTER "INFORMATION") ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE CORRECT, HACCO, INC., THE MANUFACTURER OR THE SELLER MAKES NO REPRESENTATIONS AS TO THE COMPLETENESS OR ACCURACY THEREOF. INFORMATION IS SUPPLIED UPON THE CONDITION THAT THE PERSONS RECEIVING IT WILL MAKE THEIR OWN DETERMINATION AS TO ITS SUITABILITY FOR THEIR PURPOSES PRIOR TO USE. THE PRODUCT COVERED BY THIS INFORMATION SHEET IS FURNISHED "AS IS" BY HACCO, INC., THE MANUFACTURER OR THE SELLER, AND IS SUBJECT ONLY TO THE WARRANTIES, IF ANY, THAT APPEAR ON THE PRODUCT'S LABEL OR ARE OTHERWISE EXPRESSLY PROVIDED HEREIN. EXCEPT AS EXPRESSLY PROVIDED ON THE PRODUCT'S LABEL OR OTHERWISE PROVIDED HEREIN, NO WARRANTIES, GUARANTEES, OR REPRESENTATIONS OF ANY KIND, EITHER EXPRESS OR IMPLIED, OR BY USAGE OF TRADE, STATUTORY OR OTHERWISE, ARE MADE BY Hacco, Inc., THE MANUFACTURER OR THE SELLER WITH REGARD TO THE PRODUCT OR USE OF THE PRODUCT, INCLUDING, BUT NOT LIMITED TO, MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, USE OR ELIGIBILITY OF THE PRODUCT FOR ANY PARTICULAR TRADE USAGE. EXCEPT AS EXPRESSLY STATED HEREIN, HACCO, INC., THE MANUFACTURER OR THE SELLER MAKES NO WARRANTY OF RESULTS TO BE OBTAINED BY USE OF THE PRODUCT COVERED BY THIS INFORMATION. BUYER'S OR USER'S EXCLUSIVE REMEDY, AND THE TOTAL LIABILITY OF HACCO, INC., THE MANUFACTURER OR THE SELLER, SHALL BE LIMITED TO DAMAGES NOT EXCEEDING THE COST OF THE PRODUCT. NO AGENT OR EMPLOYEE OF Hacco, Inc., THE MANUFACTURER OR THE SELLER IS AUTHORIZED TO AMEND THE TERMS OF THIS WARRANTY DISCLAIMER OR THE PRODUCT'S LABEL OR TO MAKE A REPRESENTATION OR RECOMMENDATION DIFFERENT FROM OR INCONSISTENT WITH THE LABEL OF THIS PRODUCT. IN NO EVENT SHALL HACCO, INC., THE MANUFACTURER OR THE SELLER BE LIABLE FOR CONSEQUENTIAL, SPECIAL OR INDIRECT DAMAGES RESULTING FROM THE USE, HANDLING, APPLICATION, STORAGE OR DISPOSAL OF THIS PRODUCT OR FOR DAMAGES IN THE NATURE OF PENALTIES AND THE BUYER AND USER WAIVE ANY RIGHT THEY MAY HAVE TO SUCH DAMAGES.
