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Ricoh Developer Type 9100 Page 1 RTN Number: 00001781 March 4, 2003 MATERIAL SAFETY DATA SHEET ________________________________________ 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Identification ______________________ Product Name: Ricoh Developer Type 9100 Product Number: 889736 Chemical Name: mixture CAS Number: 0-00-0 Company Identification ______________________ Ricoh Corporation 5 Dedrick Place West Caldwell, NJ USA 07006 1-973-882-2000 or 1-973-882-5218 (For product information) 1-800-336-6737 (For emergencies) GENERAL USE: FT9101, FT9105. 2. COMPOSITION/INFORMATION ON INGREDIENTS COMPONENT LISTING: Chemical Name Amount CAS Number _____________ ________ __________ IRON OXIDE > 95.0 % 1317-61-9 STYRENE ACRYLIC RESIN < 3.0 % POLYESTER RESIN < 3.0 % CARBON BLACK < 1.0 % 1333-86-4 MISCELLANEOUS: According to the United States Toxic Substances Control Act all chemical ingredients/substances contained within this product are listed on the TSCA Master Inventory. EXPOSURE GUIDELINES: Carbon Black OSHA TWA: 3.5 mg/m^3 ACGIH TWA: 3.5 mg/m^3 3. HAZARDS IDENTIFICATION PRIMARY ENTRY ROUTES: Inhalation, ingestion. CARCINOGENICITY: Carbon Black was reclassified as a Group 2B by IARC in 1996 based on the result of only the inhalation study in rats. However there was not Ricoh Developer Type 9100 Page 2 RTN Number: 00001781 March 4, 2003 ____________________________________________________________________________________________________ observed the incidence of tumors on the test results on dermal or oral studies. Also 2-years inhalation study using a typical toner containing carbon black showed no association between toner exposure and animal tumors. MEDICAL CONDITION AGGRAVATED BY LONG-TERM EXPOSURE: Not applicable. CHRONIC EFFECTS: Prolonged inhalation of excessive dust may cause lung damage. It is attributed to 'lung overloading', a generic response to excessive amounts of any dust retained in the lung for a prolonged interval. Use of this product, as intended, does not result in inhalation of excessive dust. 4. FIRST AID MEASURES EYE CONTACT FIRST AID: Try to remove with eye drops or flush with water. If unsuccessful, get medical attention. SKIN CONTACT FIRST AID: Wash thoroughly with soap and water. INHALATION FIRST AID: Gargle with water, move to place in fresh air. If unsuccessful, get medical attention. INGESTION FIRST AID: Dilute stomach contents with several glasses of water. If unsuccessful, get medical attention. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES COC Flash Point: N/A Autoignition Temperature: N/A FLAMMABLE LIMITS IN AIR LEL: N/A UEL: N/A BURNING RATE: Not available. EXTINGUISHING MEDIA: Carbon dioxide, dry chemicals, foam or water. FIRE FIGHTING INSTRUCTIONS: Generally by sprinkling or extinguisher. 6. ACCIDENTAL RELEASE MEASURES SPILL / LEAK PROCEDURES: If spilled, sweep up or pick up by vacuum cleaner (rated for developer extraction). Remove residue with soap and water. MISCELLANEOUS: Personal precautions: Minimize inhalation of dust. Environment precautions: Keep product out of sewers and watercourses. 7. HANDLING AND STORAGE HANDLING PRECAUTIONS: Do not handle in areas where wind blows. Flying powder may enter eyes. Minimize breathing dust. STORAGE REQUIREMENTS: Avoid direct sunlight. Do not keep this over 35C. Keep out of reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION VENTILATION: None needed under normal use condition. RESPIRATORY PROTECTION: None required under normal conditions of use. PROTECTIVE CLOTHING / EQUIPMENT: None required under normal conditions of use. Eye protection: None required under normal conditions of use. Protective gloves: None required under normal conditions of use. 9. PHYSICAL AND CHEMICAL PROPERTIES FORM .....................: Powder COLOR ....................: Black ODOR .....................: slight plastic odor BOILING POINT ............: Not applicable C VAPOR PRESSURE ...........: Not applicable psia VAPOR DENSITY ............: Not applicable (Air = 1) SOLUBILITY IN WATER ......: Insoluble MELTING/FREEZING POINT ...: Not available C PH .......................: Not applicable % VOLATILES ..............: - % EVAPORATION RATE .........: Not applicable 10. STABILITY AND REACTIVITY POLYMERIZATION: None. CONDITIONS TO AVOID: Not applicable in normal use. HAZARDOUS DECOMPOSITION PRODUCTS: Ricoh Developer Type 9100 Page 3 RTN Number: 00001781 March 4, 2003 ____________________________________________________________________________________________________ Will not occur. 11. TOXICOLOGICAL INFORMATION ACUTE ORAL EFFECTS: 5000mg/kg. CARCINOGENICITY: In 1996 IARC reevaluated Carbon Black as a Group 2B carcinogen (possible human carcinogen). This evaluation is given to carbon black for which there is inadequate human evidence, but sufficient animal evidence. The latter is based upon the development of lung tumors in rats receiving chronic inhalation exposures to free carbon black at levels that induce particle overload of the lung. Studies performed in animal models other than rats have not demonstrated an association between carbon black and lung tumors. Moreover, 2-years cancer bioassay using a typical toner preparation containing carbon black did not demonstrate an association between toner exposure and tumor development in rats. MUTAGENICITY: Negative (Ames test). TERATOGENICITY: Not available. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL DEGRADATION: Not known. MISCELLANEOUS: Not known in bioaccumulation. 13. DISPOSAL CONSIDERATIONS DISPOSAL: Used developer should be disposed of in an environmentally appropriate manner and in accordance with governmental regulations. Do not incinerate. 14. TRANSPORT INFORMATION PRODUCT LABEL ...: Ricoh Developer Type 9100 MISCELLANEOUS: Specific precautionary transport measures: Avoid direct sunlight. Do not keep this over 35C. 15. REGULATORY INFORMATION No information available. 16. OTHER INFORMATION HMIS Rating - Health: 1 Flammability: 1 Reactivity: 0 PREPARED BY .......: Ricoh Corporation APPROVED BY .......: David Huelbig TITLE .............: Safety Engineer APPROVAL DATE .....: September 27, 2001 SUPERCEDES DATE ...: New RTN NUMBER ........: 00001781 (Official Copy) ********************************************************************** This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Ricoh Corporation. The data on this sheet are related only to the specific material designated herein. Ricoh Corporation assumes no legal responsibility for use or reliance upon these data. ********************************************************************** END OF MSDS **********************************************************************