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MATERIAL SAFETY DATA SHEET ITWC, Inc. Phone: (641)-528-3000 P.O. Box 247 Fax: (641)-528-5403 106 South Main Street Toll Free: (888)-489-2462 Malcom, IA 50157 www.itwcinc.com 1. PRODUCT IDENTIFICATION PRODUCT NAME: CSYA70POLY CHEMICAL FAMILY: Polyester Polyol CHEMICAL NAME: Caprolactone polyols, Lactone Polyols 2. COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENT NAME CAS NUMBER % OSHA PEL ACGIH TLV 2-Oxepanone, Polymer with 1,6-hexanediol 36609-29-7 <30 Not established Not established Polyester Polyol 26570-73-0 <70 Not established Not established 3. PHYSICAL / CHEMICAL CHARACTERISTICS APPEARANCE (physical form, color, texture, etc.) Colorless Liquid ODOR: Mild MELTING/FREEZING POINT: Not available BOILING POINT: ~>200°C >392°F VAPOR PRESSURE (mm Hg): Not available SPECIFIC GRAVITY (H2O = 1): Not available 4. FIRE & EXPLOSION HAZARD DATA FLASH POINT (Method Used): 204.4°C 400°F (Pensky-Martens Closed Cup) FLAMMABLE LIMITS: LEL (Lower Explosion Limit)= Not established. UEL (Upper Explosion Limit)= Not established. EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical, water spray. For large fires use water spray, water fog, or foam. SPECIAL FIRE FIGHTING PROCEDURES: Do not direct a solid stream of water or foam into burning molten material; this may cause spattering and spread the fire. Use self-contained breathing apparatus when fighting fires in enclosed areas. UNUSUAL FIRE & EXPLOSION HAZARDS: Sudden release of hot organic chemical vapor or mists from process equipment operating at elevated temperature and pressure, or sudden ingress of air into hot equipment under a vacuum, may result in ignitions without the presence of obvious ignition sources. Published “autoignition” or “ignition” temperature values cannot be treated as safe operating temperatures in chemical processes without analysis of the actual process conditions. Any use of this product in elevated-temperature processes should be thoroughly evaluated to establish and maintain safe operating conditions. Further information is available in a technical bulletin entitled “Ignition Hazards of Organic Chemical Vapor.” 5. REACTIVITY DATA STABILITY: Stable under normal storage conditions. INCOMPATIBILITY (MATERIALS TO AVOID): Not applicable. HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Not applicable. HAZARDOUS POLYMERIZATION: Not expected to occur. CONDITIONS TO AVOID (if polymerization may occur): Not applicable. Revision Date: 4-14-09 MSDS Product: CSYA70POLY Page 1 of 4 Revision Date: 4-14-09 MSDS Product: CSYA70POLY Page 2 of 4 6. HEALTH HAZARD DATA HMIS RATINGS: Health – 1 Flammability – 1 Reactivity – 0 (0=Minimal; 1=Slight; 2=Moderate; 3=Serious; 4=Severe, *=Chronic) PRIMARY ROUTES OF ENTRY: INHALATION? No. SKIN CONTACT? Yes. EYE CONTACT? Yes. INGESTION? No. ACUTE HEALTH HAZARDS: INHALATION- Short-term harmful health effects are not expected from vapor generated at ambient temperature. SKIN- Brief contact may cause slight irritation with itching a local redness. Molten material may cause thermal burns. EYE- May cause mild discomfort.. Molten can cause thermal burns. INGESTION- Slightly toxic. May cause abdominal discomfort, nausea, and vomiting CHRONIC HEALTH HAZARDS: INHALATION- Overexposure to vapor generated at high temperatures may result irritation, dizziness and nausea. SKIN- None Known.. EYE- Overexposure to vapor generated at high temperatures may result in eye irritation. INGESTION- Overexposure to vapor generated at high temperatures may result in nausea. CARCINOGENICITY: NTP (National Toxicology Program)? No. IARC (International Agency for Research on Cancer? No. OSHA REGULATED? No. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: knowledge of the available toxicology information and of the physical and chemical properties of the material suggests that overexposure is unlikely to aggravate existing medical conditions. 7. EMERGENCY & FIRST AID PROCEDURES INHALATION- Remove to fresh air. SKIN- Remove all contaminated clothing and shoes. Wash affected area thoroughly with mild soap and water. Wash clothing before wearing again. Clean shoes before wearing again. If irritation develops or persists, consult a physician. If molten material contacts the skin, immediately flush with large amounts of water to cool the affected tissue and polymer. Do not use ice. Do not attempt to peel polymer from skin. Cover the wounded area with gauze dressing moistened with cool water; keep the dressing moist. Obtain medical attention. EYE- Flush with large amounts of water for several minutes. Remove contact lenses, if worn. For thermal burns: Immediately flush eyes with water and continue washing for several minutes. DO NOT remove contact lenses, if worn. Obtain medical attention without delay, preferably from an ophthalmologist. INGESTION- If a large quantity (several ounces) has been swallowed, and if patient is fully conscious, give two glasses of water. Induce vomiting. This should be done only by medical or experienced first-aid personnel. Obtain medical attention. NOTES TO PHYSICIAN- There are no specific antidote. Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient. 8. ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: o Stop the spill or leak. o Contain or dike the spilled product. Revision Date: 4-14-09 MSDS Product: CSYA70POLY Page 3 of 4 o Equip clean-up personnel with necessary personal protective equipment. o Avoid contact with hot product as it may cause burns. o Sweep/shovel into suitable disposal containers. o Report spill per regulatory requirements. 9. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Dispose of in accordance with applicable federal, state, and local regulations. EMPTY CONTAINER PRECAUTIONS: Empty containers retain product residue (liquid and/or vapor) and can be hazardous. Do not pressurize, cut, weld, braze, solder, drill, grind or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. All containers should be disposed of in an environmentally safe manner and in accordance with applicable federal, state, and local regulations. 10. HANDLING AND STORAGE HANDLING- For liquid state: Do not get hot liquid in eyes, on skin, on clothing. Keep container closed. Use with adequate ventilation. Wash thoroughly after handling. For solid state: Do not handle or empty in presence of flammable vapor. Keep container closed. Use with adequate ventilation. Wash thoroughly after handling. STORAGE- Store in a well-sealed container at moderate temperatures preferably under a nitrogen atmosphere. Avoid contact with atmospheric moisture, re-test after a maximum of two years. OTHER PRECAUTIONS: Melt and thoroughly mix before using. Do not heat above 121°C (250°F). 11. PERSONAL PROTECTION VENTILATION: No special ventilation is recommended under anticipated conditions of normal use beyond that needed for normal comfort control. RESPIRATORY PROTECTION: No occupational exposure limits have been established for this material or its components. A respiratory protection program that meets OSHA’s 29 CFR 1910.134 requirements must be followed whenever workplace conditions warrant respirator use. SKIN PROTECTION: Wear chemical resistant gloves such as neoprene. Wear heat protective gloves and clothing if there is a potential for product. EYE PROTECTION: Safety glasses or monogoggles. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Safety showers and eyewash stations should be readily available and in working condition. WORK/HYGIENIC PRACTICES: Wash hands, forearms, and face thoroughly after handling product and before eating, smoking, using lavatory, and at the end of the day. Educate and train employees in safe use of product. Follow all label instructions. 12. TOXICOLOGICAL INFORMATION NOT ESTABLISHED FOR PRODUCT 13. ECOLOGICAL INFORMATION NOT ESTABLSISHED FOR PRODUCT 14. TRANSPORT INFORMATION U.S. D.O.T. - NON REGULATED 15. REGULATORY INFORMATION OSHA HAZARD COMMUNICATION STATUS: This product is not considered hazardous as defined under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. Revision Date: 4-14-09 MSDS Product: CSYA70POLY Page 4 of 4 RCRA STATUS: Information not available. US INVENTORY (TSCA): The ingredients of this product are listed on the TSCA inventory or are not required to be listed on the TSCA inventory. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA), TITLE III: Sections 301-303 – Emergency Planning - Extremely Hazardous Substances: None. Section 304 – Emergency Release Notification – Reportable Substances: None. Section 311/312 – Community Right-to-Know Reporting Requirements - Emergency Hazard Categories: None. Section 313 – Toxic Chemical Notification & Release Inventory Reporting – Listed Substances: None. This information must be included in all MSDSs that are copied and distributed for this material. 16. OTHER INFORMATION PREPARED BY: ITWC Compliance Dept. (lrt) APPROVED BY: ITWC Director of Technical Service. (SF) This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of ITWC, Inc. The data on this sheet relates only to the specific material designated herein. ITWC, Inc. assumes no legal responsibility for use or reliance upon these data. Visit our website at www.ITWCINC.com or call (888)-489-2462
