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<p> WACKER SILRES BS POWDER A PRODUCT DISTRIBUTED BY / PRODUIT DISTRIBUÉ PAR Brenntag Canada Inc. WHMIS Number: 00066208 43 Jutland Road. Index: HCI5348/07B Toronto, Ontario Effective Date: 2007 April 05 M8Z 2G6 Date of Revision: 2007 April 05 (416) 259-8231 Website: http://www.brenntag.ca _______________________________________________________________________________________________ EMERGENCY TELEPHONE NUMBERS / EN CAS D'URGENCE Toronto, ON (416) 226-6117 Montréal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827 Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036 _______________________________________________________________________________________________ This document consists of an English MSDS. Le présent document comprend une fiche signalétique en anglais. READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT. LIRE LA FICHE SIGNALÉTIQUE EN ENTIER POUR UNE ÉVALUATION COMPLÈTE DES DANGERS QUE REPRÉSENTE CE PRODUIT Material Safety Data Sheet Material: 00243888 SILRES® BS POWDER A #BLOCKED# Version: 1.5 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 1/8 1 Product and company identification 1.1 Identification of the substance or preparation: Commercial product name: SILRES® BS POWDER A #BLOCKED# Use of substance / preparation: Industrial. Modifying agent for: Building materials 1.2 Company/undertaking identification: Manufacturer/distributor: Wacker Chemie AG Hanns-Seidel-Platz 4 81737 München Germany Customer information: Wacker Chemical Corporation 3301 Sutton Road Adrian,Michigan 49221-9397 USA Customer Care Center:Tel (517) 264-8240, Fax (517) 264- 8740 Hours of operation:Monday - Friday, 8 am to 5 pm (eastern standard time) Corporate website: www.wackersilicones.com Emergency telephone no. (24h): (517) 264-8500 Transportation emergency: (800) 424-9300 (CHEMTREC, USA) (703) 527-3887 (CHEMTREC, international)(613) 996-6666 (CANUTEC, Canada) This MSDS was prepared by the Regulatory Affairs and Product Safety Department (RAPS) of Wacker Chemical Corporation. 2 Composition/information on ingredients 2.1 Chemical characterization (preparation): Chemical characteristics alkoxysilane + auxiliary product 2.2 Information on ingredients: Type CAS No. Substance Content [wt. %] Note Lower Upper INHA 35435-21-3 Octyl triethoxy silane 30.0 60.0 NEBE 64-17-5 Ethanol 0.0varies 0.495varies Type: HYD - by-product upon hydrolysis, INHA - ingredient, NEBE - by-product, MONO - residual monomer, VERU - impurity, VUL - by-product upon vulcanization. *** Note: C1 - IARC carcinogen, C2 - NTP carcinogen, C3 - OSHA carcinogen, NH - non-hazardous, R - reproductive toxin. This material does not contain any OSHA or WHMIS reportable hazardous ingredients. Substances listed in the Subsections "HAPS" and "California Proposition 65 Carcinogens / Reproductive Toxins" that are not listed in Section 2 are only present at quantities below 0.1% for California Proposition 65 listed toxins or below 1% for non-carcinogenic HAPS or they are inextricably bound in the product. 3 Hazards identification 3.1 Hazards classifications HMIS® rating (product as packaged): Health: 1 Fire: 1 Reactivity: 1 PPE: E Material Safety Data Sheet Material: 00243888 SILRES® BS POWDER A #BLOCKED# Version: 1.5 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 2/8 (HMIS codes are based on contact with the product as packaged and any hydrolysis by-products, if present.) Hazardous Materials Identification System and HMIS are registered trademarks of the National Paint and Coatings Association. Note: Respiratory protection is only recommended in the event that ventilation or engineering controls are unable to maintain exposures below recommended levels; or in the event of a spill or other emergency response situation. Canadian WHMIS Classification: None. 3.2 Emergency overview and potential hazards This material is not hazardous under OSHA criteria. This material is not hazardous under WHMIS criteria. Physical Hazards: No known physical hazards. Acute health effects Route of entry or possible contact: inhalation (in case of dust formation) , skin , eyes . Eye contact: May cause eye irritation. Skin contact: May cause skin irritation. Inhalation: May cause respiratory tract irritation. May cause mucous membrane irritation. Neurotoxic effects are possible. In case of dust formation: If inhaled lung damage is possible. Ingestion: Ingestion is not expected in industrial use. Additional information on acute health effects: The toxicological evaluation is based on known effects of the active ingredient(s). This material releases ethanol upon hydrolysis. Ethanol (CAS-No. 64-17-5) is an irritant to the eyes and mucous membranes. Overexposure has been shown to cause central nervous system depression. Direct contact with the eyes will cause burning and stinging. 3.3 Further information: Chronic health effects: No known or expected chronic health effects. Medical conditions which may be aggravated by exposure: none known . Target organs affected: Lungs Signs and Symptoms of Exposure: Refer to Acute Health Effects, listed above. Carcinogens/Reproductive toxins: This material does not contain any reportable carcinogenic ingredients. This material does not contain any reproductive toxins at or above OSHA or WHMIS reportable levels. See Section 11 for Toxicological Information, if any. Material Safety Data Sheet Material: 00243888 SILRES® BS POWDER A #BLOCKED# Version: 1.5 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 3/8 4 First-aid measures 4.1 General information: Get medical attention if irritation occurs or if breathing becomes difficult. Remove contaminated clothing and shoes. 4.2 After inhalation: If inhaled remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult give oxygen. 4.3 After contact with the skin: Wash with soap and water. 4.4 After contact with the eyes: If contact with eyes, immediately hold eyelids apart and flush with plenty of water for at least 15 min. 4.5 After swallowing: For ingestion, if conscious, give several glasses of water but do not induce vomiting. If vomiting does occur, give additional fluids. 4.6 Advice for the physician: Treat symptomatically. 5 Fire-fighting measures 5.1 Flammable properties: Method Flash point..........................: 96 °C (204 °F) (ISO 2592) Boiling point / boiling range........: not applicable Lower explosion limit (LEL)..........: not determined Upper explosion limit (UEL)..........: not determined Ignition temperature ................: 265 °C (509 °F) (DIN 51794) 5.2 Fire and explosion hazards: As a result of hydrolysis flammable vapors may accumulate in the container head space. Explosion limits for hydrolysis product: 3.5-15% v/v (ethanol) . 5.3 Recommended extinguishing media: water-spray , water-mist , carbon dioxide , dry chemical or alcohol-resistant foam . 5.4 Unsuitable extinguishing media: none known 5.5 Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases: Hazardous decomposition products: carbon dioxide , carbon monoxide , formaldehyde , silicon dioxide and incompletely burnt hydrocarbons . 5.6 Fire fighting procedures: Fire fighters should wear full protective clothing including a self-contained breathing apparatus. Use respiratory protection independent of recirculated air. 6 Accidental release measures 6.1 Precautions: Wear personal protection equipment (see section 8). Do not breathe dust. HAZWOPER PPE Level: D 6.2 Containment: Prevent material from entering surface waters, drains or sewers and soil. Cover any spilled material in accordance with regulations to prevent dispersal by wind. Spills of material which could reach surface waters must be reported to the United States Coast Guard National Response Center's toll free phone number (800) 424-8802. 6.3 Methods for cleaning up: Take up mechanically and dispose of according to local/state/federal regulations. Avoid dust formation. 6.4 Further information: Eliminate all sources of ignition. Material Safety Data Sheet Material: 00243888 SILRES® BS POWDER A #BLOCKED# Version: 1.5 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 4/8 7 Handling and storage 7.1 Handling Precautions for safe handling: Avoid dust formation. Precautions against fire and explosion: Danger of dust explosion: Do not stir up dust; remove dust after wetting. Avoid dust deposit, remove dust regularly. During transfusion electrostatic charging possible. Take precautionary measures against electrostatic charging. Keep away from sources of ignition and do not smoke. 7.2 Storage Conditions for storage rooms and vessels: Observe precautionary measures against dust explosion. Advice for storage of incompatible materials: not applicable Further information for storage: Keep container dry and tightly closed. 8 Exposure controls and personal protection 8.1 Engineering controls Ventilation: Use with adequate ventilation. Local exhaust: In case of dust formation: Local exhaust ventilation which meets the requirements of ANSI Z9.2 is recommended to control airborne contaminants at the point of use. 8.2 Associate substances with specific control parameters such as limit values Maximum airborne concentrations at the workplace: CAS No. Material Type mg/m3 ppm Dust fract. 64-17-5 Ethanol OSHA PEL 1,900.0 1,000.0 Particulates not otherwise classified OSHA PEL 15.0 Inhalable dust Particulates not otherwise classified OSHA PEL 5.0 Respirable dust 64-17-5 Ethanol ACGIH TWA 1,000.0 Particulates not otherwise classified ACGIH TWA 10.0 Inhalable dust Particulates not otherwise classified ACGIH TWA 3.0 Respirable dust Re Ethanol (CAS no. 64-17-5): carcinogenicity: A4 (ACGIH). Re Particulates not otherwise classified: The value is for particulate matter containing no asbestos and < 1% crystalline silica (ACGIH). 8.3 Personal protection equipment (PPE) Respiratory protection: In case of dust formation: A NIOSH approved air purifying respirator fitted with at least P-99 solid/aerosol particulate filters is recommended if overexposure to dust or aerosol mist could occur. Hand protection: Any liquid-tight rubber or vinyl gloves. Eye protection: Safety glasses with side shields or chemical safety goggles. Other protective clothing or equipment: Additional protective clothing or equipment is not normally required. Provide eye bath and safety shower. 8.4 General hygiene and protection measures: Do not breathe dust/vapor/mist/gas/aerosol. Avoid contact with eyes, skin and clothing. Do not eat, drink or smoke when handling. Follow standard industrial hygiene practices when using this material. Wash thoroughly after handling. Material Safety Data Sheet Material: 00243888 SILRES® BS POWDER A #BLOCKED# Version: 1.5 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 5/8 9 Physical and chemical properties 9.1 Appearance Physical state / form................: solid - powder Colour...............................: white Odour................................: slight 9.2 Safety parameters Method Melting point / melting range........: not applicable Boiling point / boiling range........: not applicable Flash point..........................: 96 °C (204 °F) (ISO 2592) Ignition temperature ................: 265 °C (509 °F) (DIN 51794) Lower explosion limit (LEL)..........: not determined Upper explosion limit (UEL)..........: not determined Vapour pressure......................: not applicable Bulk density.........................: approx. 400 kg/m³ Water solubility / miscibility.......: virtually insoluble pH-Value.............................: not applicable Viscosity (dynamic)..................: not applicable 9.3 Further information Minimum ignition energy .............: 3 - 10 mJ with induction Minimum ignition energy .............: 10 - 30 mJ without induction 10 Stability and reactivity 10.0 General information: If stored and handled in accordance with standard industrial practices no hazardous reactions are known. 10.1 Conditions to avoid: moisture . 10.2 Materials to avoid: Reacts slowly with: water and acids . Reaction causes the formation of: ethanol . 10.3 Hazardous decomposition products: If stored and handled in accordance with standard industrial practices and local regulations where applicable: none known . Measurements have shown the formation of small amounts of formaldehyde at temperatures above about 150 °C (302 °F) through oxidation. By hydrolysis: ethanol . 10.4 Further information: Hazardous polymerization cannot occur. 11 Toxicological information 11.1 General information: Toxicological testing has not been conducted with this material. 11.2 Toxicological data: Experience with man: - 12 Ecological information 12.1 Information on elimination (persistence and degradability) Biodegradation / further information: Silicone content: Biologically not degradable. The hydrolysis product (Ethanol) is readily biologically degradable. Further information: By hydrolysis: ethanol and silanol- and/or siloxanol-compounds Elimination by adsorption to activated sludge. Material Safety Data Sheet Material: 00243888 SILRES® BS POWDER A #BLOCKED# Version: 1.5 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 6/8 12.2 Behaviour in environmental compartments Mobility - Further information: - 12.3 Ecotoxicological effects: Classification based on ingredients: Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. 12.4 Additional information Other harmful effects - General information: According to our present knowledge no further data known. 13 Disposal considerations 13.1 Product disposal Recommendation: Dispose of according to regulations by incineration in a special waste incinerator. Small quantities may be disposed of by incineration in an approved facility. Observe local/state/federal regulations. 13.2 Packaging diposal Recommendation: Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used. Observe local/state/federal regulations. 14 Transport information 14.1 US DOT & CANADA TDG SURFACE Valuation....................: Not regulated for transport 14.2 Transport by sea IMDG-Code Valuation....................: Not regulated for transport Marine Pollutant.............: no 14.3 Air transport ICAO-TI/IATA-DGR Valuation....................: Not regulated for transport 15 Regulatory information 15.1 U.S. Federal regulations TSCA inventory status and TSCA information: This material or its components are listed on or are in compliance with the requirements of the TSCA Chemical Substance Inventory. TSCA 12(b) Export Notification: This material does not contain any TSCA 12(b) regulated chemicals. CERCLA Regulated Chemicals: This material does not contain any CERCLA regulated chemicals. SARA 302 EHS Chemicals: This material does not contain any SARA extremely hazardous substances. SARA 311/312 Hazard Class: This product does not present any SARA 311/312 hazards. SARA 313 Chemicals: This material does not contain any SARA 313 chemicals above de minimus levels. Material Safety Data Sheet Material: 00243888 SILRES® BS POWDER A #BLOCKED# Version: 1.5 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 7/8 HAPS (Hazardous Air Pollutants): This material does not contain any hazardous air pollutants. 15.2 U.S. State regulations California Proposition 65 Carcinogens: This material does not contain any chemicals known to the state of California to cause cancer. California Proposition 65 Reproductive Toxins: This material does not contain any chemicals known to the state of California to cause reproductive effects. Massachusetts Substance List: 112926-00-8 Amorphous precipitated Silica New Jersey Right-to-Know Hazardous Substance List: 112926-00-8 Amorphous precipitated Silica Pennsylvania Right-to-Know Hazardous Substance List: 112926-00-8 Amorphous precipitated Silica 15.3 Canadian regulations This product has been classified in accordance with the Hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS Hazard Classes: None. DSL Status: This material or its components are listed on the Canadian Domestic Substances List. Canadian Ingredient Disclosure List: 112926-00-8 Amorphous precipitated Silica 15.4 Other international regulations EU Risk Phrases: R-Phrase Description R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. EU Safety Phrases: S-Phrase Description S61 Avoid release to the environment. Refer to special instructions / safety data sheets. Details of international registration status Listed on or in accordance with the following inventories: IECSC - China TSCA - USA PICCS - Philippines ENCS - Japan ECL - Korea DSL - Canada AICS - Australia EINECS - Europe HSNO - New Zealand 16 Other information 16.1 Additional information: This Material Safety Data Sheet (MSDS) meets the requirements of the Federal OSHA Hazard Communication Standard (29 CFR 1910.1200). This product has been classified according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the Material Safety Data Sheet Material: 00243888 SILRES® BS POWDER A #BLOCKED# Version: 1.5 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 8/8 information required by the CPR. This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is to the best of our knowledge and belief accurate and reliable as of the date compiled. However, no representation, warranty or guarantee expressed or implied, is made as to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending a license under valid patents. This MSDS provides selected regulatory information on this product, including its components. This is not intended to include all regulations. It is the responsibility of the user to know and comply with all applicable rules, regulations and laws relating to the product being used. Vertical lines in the left-hand margin indicate changes compared with the previous version. 16.2 Glossary of Terms: ACGIH - American Conference of Governmental Industrial Hygienists DOT - Department of Transportation hPa - Hectopascals mPa*s - Milli Pascal-Seconds OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limit ppm - Parts per Million SARA - Superfund Amendments and Reauthorization Act STEL - Short Term Exposure Limit TSCA - Toxic Substances Control Act TWA - Time Weighted Average WHMIS - Canadian Workplace Hazardous Materials Identification System Flash point determination methods Common name ASTM D56 Tagliabue (Tag) closed cup ASTM D92, DIN 51376, ISO 2592 Cleveland open cup ASTM D93, DIN 51758, ISO 2719 Pensky-Martens closed cup ASTM D3278, DIN 55680, ISO 3679 Setaflash or Rapid closed cup DIN 51755 Abel-Pensky closed cup 16.3 Conversion table: Pressure: Viscosity: 1 hPa * 0.75 = 1 mm Hg = 1 Torr; 1 bar = 1000 hPa 1 mPa*s = 1 Centipoise (Cp) </p>
