3M MATERIAL SAFETY DATA SHEET 3M(TM) Lauricare(TM) Moisturizing Teat Dip Concentrate- No. 1433, 1433P4, 1433D and 1431 3M(TM) Swine Wash 09/09/2004 _________________________________________________________________________________________________ Page 1 of 7 Material Safety Data Sheet Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) Lauricare(TM) Moisturizing Teat Dip Concentrate- No. 1433, 1433P4, 1433D and 1431 3M(TM) Swine Wash MANUFACTURER: 3M DIVISION: Medical Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 09/09/2004 Supercedes Date: 09/09/2004 Document Group: 11-6923-4 Product Use: Specific Use: Care and management of mastitis in dairy cattle. SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt Water 7732-18-5 50 - 60 Propylene glycol 57-55-6 15 - 30 Food grade surfactant 9003-11-6 0 - 15 Food grade surfactant 106392-12-5 0 - 15 Lactic acid 50-21-5 2 - 10 Caprylic acid 124-07-2 1 - 5 Capric acid 334-48-5 1 - 5 Glycerol monolaurate 27215-38-9 < 3 Yellow dye 2783-94-0 < 0.5 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: Yellow color with fatty acid odor. General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause allergic skin reaction. May cause target organ 3M MATERIAL SAFETY DATA SHEET 3M(TM) Lauricare(TM) Moisturizing Teat Dip Concentrate- No. 1433, 1433P4, 1433D and 1431 3M(TM) Swine Wash 09/09/2004 _________________________________________________________________________________________________ Page 2 of 7 effects. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: No health effects are expected. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. No need for first aid is anticipated. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Not Applicable Flash Point Not Applicable 3M MATERIAL SAFETY DATA SHEET 3M(TM) Lauricare(TM) Moisturizing Teat Dip Concentrate- No. 1433, 1433P4, 1433D and 1431 3M(TM) Swine Wash 09/09/2004 _________________________________________________________________________________________________ Page 3 of 7 Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable 5.2 EXTINGUISHING MEDIA Non-combustible. Choose material suitable for surrounding fire. 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Not applicable. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Ventilate the area with fresh air. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Cover with soda ash (sodium carbonate) or sodium bicarbonate. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. Collect the resulting residue containing solution. Place in a metal container approved for use in transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene. Cover, but do not seal for 48 hours. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Avoid eye contact with vapors, mists, or spray. Avoid prolonged or repeated skin contact. Avoid breathing of vapors, mists or spray. Do not ingest. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep out of the reach of children. 7.2 STORAGE Store away from areas where product may come into contact with food or pharmaceuticals. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use in a well-ventilated area. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. 3M MATERIAL SAFETY DATA SHEET 3M(TM) Lauricare(TM) Moisturizing Teat Dip Concentrate- No. 1433, 1433P4, 1433D and 1431 3M(TM) Swine Wash 09/09/2004 _________________________________________________________________________________________________ Page 4 of 7 The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. 8.2.3 Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information Propylene glycol AIHA TWA, as aerosol 10 mg/m3 Propylene glycol AIHA TWA, as total 50 ppm SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: Yellow color with fatty acid odor. General Physical Form: Liquid Autoignition temperature Not Applicable Flash Point Not Applicable Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable Boiling point No Data Available Density 1.03 g/ml Vapor Density Not Applicable Vapor Pressure No Data Available Specific Gravity Approximately 1.03 [Ref Std: WATER=1] pH Approximately 2.8 Melting point Not Applicable Solubility in Water Complete Evaporation rate Not Applicable Volatile Organic Compounds Not Applicable Percent volatile Not Applicable VOC Less H2O & Exempt Solvents No Data Available Viscosity Approximately 150 centipoise [Details: Conditions: Brookfield viscosity] 3M MATERIAL SAFETY DATA SHEET 3M(TM) Lauricare(TM) Moisturizing Teat Dip Concentrate- No. 1433, 1433P4, 1433D and 1431 3M(TM) Swine Wash 09/09/2004 _________________________________________________________________________________________________ Page 5 of 7 SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Strong acids; Strong bases Additional Information: Lactic acid mixed with nitric acid and hydrofluoric acid may react vigorously. Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Aldehydes Not Specified Carbon monoxide Not Specified Carbon dioxide Not Specified SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 70-2005-6518-5, 70-2006-4365-1, 70-2006-8105-7 3M MATERIAL SAFETY DATA SHEET 3M(TM) Lauricare(TM) Moisturizing Teat Dip Concentrate- No. 1433, 1433P4, 1433D and 1431 3M(TM) Swine Wash 09/09/2004 _________________________________________________________________________________________________ Page 6 of 7 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES This material contains one or more substances not listed on the TSCA Inventory. Commercial use of this material is regulated by the FDA. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 1 Flammability: 0 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. 3M MATERIAL SAFETY DATA SHEET 3M(TM) Lauricare(TM) Moisturizing Teat Dip Concentrate- No. 1433, 1433P4, 1433D and 1431 3M(TM) Swine Wash 09/09/2004 _________________________________________________________________________________________________ Page 7 of 7 Revision Changes: Section 2: Ingredient table was modified. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com