EN3487.pdf

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Luciferin Free Acid Product hazard D Luciferin Free Section contact
Conforms to 93/112/EC and ISO 11014-1
Material Safety Data Sheet
D-Luciferin, Free Acid
3487
0016500 0016505
CALL CHEMTREC:
800.424.9300
OUTSIDE US:
202.483.7616
11/4/2002
11/7/2002
Product name
Supplier
Manufacturer
Product No.
MSDS#
Validation Date
Print Date
In Case of Emergency
Section 1. Chemical Product and Company Identification
Responsible Name Pierce Administration
Synonyms (S)-4,5-DIHYDRO-2-(6-HYDROXYBENZOTHIAZOL-2-YL)THIAZOLE-4-CARBOXYLIC ACID
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
(4,5-dihydro-2-[6-hydroxy-2-benzothiazolyl]-4-thiazolecarboxylic acid)
Chemical name
Eng
In USA: 
 In Europe:
Pierce 
 Perbio Science
P.O. Box 117 
 Industriezone III
Rockford, IL 61105  Industrielaan 27
USA 
 9320 Erembodegem-Aalst
815.968.0747 or
 Belgium
1.800.874.3723
 Tel:+32 53 83 44 04
 
 Fax:+32 53 83 76 38
Pierce Biotechnology
P.O. Box 117
Rockford, IL 61105
USA
815.968.0747 or
1.800.874.3723
1) D-Luciferin, Free Acid
2591-17-5
98-100
219-981-3
--
Not controlled under
dsd (Europe).
Ingredient Name
EC Number
CAS No.
R-Phrases
Substance/Preparation
Substance
%
Symbol
:
Section 2. Composition, Information on Ingredients
Physical/chemical hazards
Human health hazards
Environmental hazards Not applicable.
Not applicable.
Not applicable.
Absorbed through skin.  Eye contact.  Inhalation.  Ingestion.
Emergency Overview
Medical Conditions Aggravated
by Overexposure:
Repeated or prolonged exposure is not known to aggravate medical condition.
Not available.
Overexposure /Signs/Symptoms
Section 3. Hazards Identification
Routes of Entry
Potential Acute Health Effects
Carcinogenic Effects Data
Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation (lung irritant).
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
Review the most current and approved institutional guideline, protocol, standard operating procedure(s) and MSDS(s)
for the proper handling of institutional materials/equipment associated with the use of this product.
No specific hazard.
Classification Not controlled under dsd (Europe).
United States
Europe
Continued on Next Page
D-Luciferin, Free Acid
Page: 2/5
See Toxicological Information (section 11)
Do NOT induce vomiting unless directed to do so by medical personnel.  Never give anything by mouth to an unconscious
person.  If large quantities of this material are swallowed, call a physician immediately.  Loosen tight clothing such as a
collar, tie, belt or waistband.
Skin Contact
Ingestion
Check for and remove any contact lenses.  In case of contact, immediately flush eyes with plenty of water for at least 15
minutes.  Cold water may be used.  WARM water MUST be used.  Get medical attention if irritation occurs.
Wash with soap and water.  Cover the irritated skin with an emollient.  Get medical attention if irritation develops.
Slightly hazardous in case of inhalation (lung irritant).
Not available.
Slightly hazardous in case of skin contact (irritant).  Skin inflammation is characterized by itching, scaling, reddening, or,
occasionally, blistering.
Skin Contact
Slightly hazardous in case of eye contact (irritant).
Eye Contact
Inhalation
Aggravating conditions Repeated or prolonged exposure is not known to aggravate medical condition.
First-Aid Measures
If inhaled, remove to fresh air.  If not breathing, give artificial respiration.  If breathing is difficult, give oxygen.  Get medical
attention if symptoms appear.
Notes to Physician Not available.
Not available.
Protection of first-aiders
Ingestion
Effects and symptoms
Inhalation
Eye Contact
Section 4. First Aid Measures
Notice to Reader Get immediate medical attention.
Hazardous thermal (de)composition
products
Not applicable.
Non-flammable.
Not applicable.
Not applicable.
Not applicable.
Section 5. Fire Fighting Measures
Flammability of the Product
Flash Points
Fire Hazards in Presence of Various
Substances
Fire Fighting Media
and Instructions
Not applicable.
Protective Clothing (Fire)
Use a shovel to put the material into a convenient waste disposal container.  Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Section 6. Accidental Release Measures
Small Spill and Leak Use appropriate tools to put the spilled solid in a convenient waste disposal container.  Finish cleaning by spreading
water on the contaminated surface and dispose of according to local and regional authority requirements.
Environmental Precautions and
Clean-up Methods
Personal precautions Safety glasses.  Lab coat.  Dust respirator.  Be sure to use an approved/certified respirator or equivalent.  Gloves.
Keep container tightly closed.  Keep container in a cool, well-ventilated area.
Avoid breathing dust.
Section 7. Handling and Storage
Handling
Storage
Suitable /  Not suitable
Packaging materials
Use original container.
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
Continued on Next Page
D-Luciferin, Free Acid
Page: 3/5
1) D-Luciferin, Free Acid
Not available.
Germany
1) D-Luciferin, Free Acid
Not available.
Netherlands
1) D-Luciferin, Free Acid
Not available.
France
1) D-Luciferin, Free Acid
Not available.
Norway
1) D-Luciferin, Free Acid
Not available.
Denmark
1) D-Luciferin, Free Acid
Not available.
Sweden
United States
Ingredient Name
Occupational Exposure Limits
Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits.  If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Section 8. Exposure Controls/Personal Protection
Exposure Limit Values
Personal Protection
Eyes
Body
Protective Clothing
(Pictograms)
Safety glasses.
Lab coat.
>300°C (572°F)
Solid. (Powder or flakes solid.)
7 [Neutral.]
200°C (392°F)
>1  (Air = 1)
See solubility in water, acetone.
Soluble in acetone.
Very slightly soluble in cold water, hot water.
280.3 g/mole
Not available.
Not available.
White to yellowish.
Boiling/Condensation Point
Melting/Freezing Point
Physical State  and
Appearance
Molecular Weight
pH (1% Soln/Water)
Vapor Density
Dispersion Properties
Solubility
Odor
Taste
Color
C11H8N2O3S2
Molecular Formula
Section 9. Physical and Chemical Properties
Continued on Next Page
D-Luciferin, Free Acid
Page: 4/5
The product is stable.
Reactive with oxidizing agents, alkalis.
Will not occur.
Not available.
Section 10. Stability and Reactivity
Stability and Reactivity
Conditions to avoid
Materials to avoid
Hazardous Polymerization
Hazardous Decomposition
Products
Not applicable.
LD50: Not available.
LC50: Not available.
Slightly hazardous in case of eye contact (irritant), of inhalation (lung irritant).
Not available.
Not available.
Not available.
Not available.
Section 11. Toxicological Information
Toxicity to Animals
Chronic Effects on Humans
Other Toxic Effects on Humans
Special Remarks on Toxicity to
Animals
Special Remarks on Chronic
Effects on Humans
Special Remarks on Other Toxic
Effects on Humans
Ecotoxicity Not available.
Mobility
Germany water class
Not available.
Not available.
Not available.
Persistence/degradability
Bioaccumulative potential
VCI WGK: No products were found.
Section 12. Ecological Information
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Not available.
Waste Information
Waste Stream
Section 13. Disposal Considerations
Consult your local or regional authorities.
Contact the supplier for all information regarding the proper transportation method for this material.
Section 14. Transport Information
Section 15. Regulatory Information
Label Requirements
1
Continued on Next Page
D-Luciferin, Free Acid
Page: 5/5
U.S. Federal Regulations
No products were found.
--
HCS Classification
California prop. 65:  No products were found.
TSCA: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
State Regulations
No products were found.
Australia (NICNAS): D-Luciferin, Free Acid
WHMIS (Canada) Not controlled under WHMIS (Canada).
This product is not classified according to the EU regulations.
DSCL (EEC)
International Regulations
Not available.
EINECS
International Lists
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found.
SARA 313 toxic chemical notification and release reporting: No products were found.
This product is not classified according to the EU regulations.
(Europe)
Version
0.01
Date of Previous Issue No Previous
Validation
Not available.
Section 16. Other Information
References
Validated by Pierce Administration on 11/4/2002.
Verified by Pierce Administration.
Printed 11/7/2002.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate.  However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Hazardous Material
Information System
(U.S.A.)
0
0
0
E
0
0
0
National Fire Protection
Association (U.S.A.)
Health
Specific Hazard
Reactivity
Fire Hazard
Health
Fire Hazard
Reactivity
Personal Protection
History of Document Changes Any information changes since last document version are marked with a triangle symbol.
Not applicable.
Full text of R-Phrases
referenced under headings 2 and 3:
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.