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00003895 MATERIAL SAFETY DATA SHEET Page 1 CANADA COLORS & CHEMICALS LTD 152 KENNEDY ROAD SOUTH BRAMPTON, ONTARIO, CANADA L6W 3G4 (905) 459-1232; CODE: 567220 PRODUCT: BRICKOX 6807 Section 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER/SUPPLIER...................... PRINCE MINERALS, INC. ONE PRINCE PLAZA QUINCY, IL USA USA 62305 PREPARED BY............................................. Regulatory Affairs PREPARATION DATE.................................. Dec23/08 PRODUCT NAME.......................................... BRICKOX 6807 PRODUCT CODE.......................................... 567220 CHEMICAL FORMULA.................................. N.AP. MOLECULAR WEIGHT................................. N.AP. CHEMICAL FAMILY...................................... INORGANIC. MATERIAL USE............................................ N.AV. EMERGENCY PHONE NO........................... (416)-444-2112. Section 02: COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients % Exposure Limit C.A.S.# LD/50, Route,Species LC/50 Route,Species MANGANESE COMPOUND (AS 51-55 SEE SECTION 11 7439-96-5 SEE SECTION 11 SEE SECTION 11 MN) IRON OXIDE 1-5 SEE SECTION 11 1309-37-1 SEE SECTION 11 SEE SECTION 11 QUARTZ 1-5 SEE SECTION11 14808-60-7 SEE SECTION 11 SEE SECTION 11 ALUMINUM OXIDE 3-7 SEE SECTION 11 1344-28-1 SEE SECTION 11 SEE SECTION 11 BARIUM OXIDE 0.2-2 SEE SECTION 11 1304-28-5 SEE SECTION 11 SEE SECTION 11 Section 03: HAZARDS IDENTIFICATION ROUTE OF ENTRY: SKIN CONTACT............................................ MAY CAUSE IRRITATION. SKIN ABSORPTION...................................... N.AV. EYE CONTACT............................................. MAY CAUSE IRRITATION. INHALATION................................................. MAY IRRITATE THE RESPIRATORY TRACT. MAY INCREASE THE INCIDENCE OF UPPER RESPIRATORY INFECTIONS (PNEUMONIA). PROLONGED EXPOSURE TO SILICA DUST MAY RESULT IN SILICOSIS, A FIBROTIC LUNG DISEASE. INGESTION................................................... MAY CAUSE ABDOMINAL PAIN AND NAUSEA. MANGANESE DIOXIDE DUST IS POORLY ABSORBED THROUGH THE GUT. EFFECTS OF ACUTE EXPOSURE.............. REFER TO ROUTE OF ENTRY. EFFECTS OF CHRONIC EXPOSURE.......... REFER TO ROUTE OF ENTRY. INHALATION, CHRONIC.............................. SEE ABOVE. SIGNS AND SYMPTOMS OF ...................... (DUST) TEARING OF EYES, BURNING SENSATION IN THE THROAT, COUGH, CHEST OVEREXPOSURE DISCOMFORT. MEDICAL CONDITIONS AGGRAVATED BY THE EXCESSIVE INHALATION OF MINERAL DUST MAY AGGRAVATE PRE-EXISTING OVEREXPOSURE CHRONIC LUNG CONDITIONS SUCH AS, BUT NOT LIMITED TO, BRONCHITIS, EMPHYSEMA, AND ASTHMA. Section 04: FIRST AID MEASURES INSTRUCTIONS:........................................... IF INHALED, REMOVE TO FRESH AIR AND SEEK MEDICAL ATTENTION FOR ANY BREATHING DIFFICULTY. IN CASE OF SKIN CONTACT, WASH WITH SOAP AND WATER. SEEK MEDICAL ATTENTION IF RED AND IRRITATED. IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH RUNNING WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS. INGESTION: IF INGESTED, SEEK IMMEDIATE MEDICAL ATTENTION. Section 05: FIRE FIGHTING MEASURES T.D.G. FLAM. CLASS.................................... N.AV. FLAMMABILITY............................................. NOT FLAMMABLE. IF YES, UNDER WHICH CONDITIONS?...... ALTHOUGH NOT COMBUSTIBLE, THIS MATERIAL IS A STRONG OXIDIZING AGENT, WHICH LIBERATES OXYGEN DURING THERMAL DECOMPOSITION. IT MAY INCREASE THE BURNING RATE OF COMBUSTIBLE WITH A FLARE-BURNING EFFECT. IT MAY CAUSE REIGNITION AFTER A FIRE IS EXTINGUISHED . EXTINGUISHING MEDIA.............................. DRY CHEMICAL. CARBON DIOXIDE. 00003895 MATERIAL SAFETY DATA SHEET Page 2 CODE: 567220 PRODUCT: BRICKOX 6807 Section 05: FIRE FIGHTING MEASURES SPECIAL PROCEDURES............................. MATERIAL SHOULD BE KEPT OUT OF EYES AND OFF SKIN. DO NOT RELEASE RUNOFF FROM FIRE CONTROL METHODS TO SEWERS OR WATERWAYS. FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS. FLASH POINT (C), METHOD........................ >230 F CLOSED CUP-PENSKY-MARTENS. AUTO IGNITION TEMPERATURE................ N.AV. UPPER FLAMMABLE LIMIT (% BY VOL.).... N.AP. LOWER FLAMMABLE LIMIT (% BY VOL.)... N.AP. EXPLOSION DATA EXPLOSIVE POWER.................................... N.AV. RATE OF BURNING...................................... N.AV. SENSITIVITY TO STATIC DISCHARGE....... N.AV. SENSITIVITY TO IMPACT............................ N.AV. UNUSUAL FIRE AND EXPLOSION ............. ALTHOUGH NOT COMBUSTIBLE, THIS MATERIAL IS A STRONG OXIDIZING AGENT, HAZARDS WHICH LIBERATES OXYGEN DURING THERMAL DECOMPOSITION. HAZARDOUS COMBUSTION PRODUCTS.. SEE HAZARDOUS DECOMPOSITION PRODUCTS. Section 06: ACCIDENTAL RELEASE MEASURES LEAK/SPILL................................................... ISOLATE HAZARD AREA AND RESTRICT ACCESS. PRODUCT IS DRY SOLID (GRANULAR OR POWDER) AND NOT READILY SOLUBLE IN WATER. PREVENT SPILLED PRODUCT FROM ENETERING STREAMS, WATER BODIES AND WASTEWATER SYSTEMS. AVOID DIRECT CONTACT WITH MATERIAL. WEAR PROTECTIVE EQUIPMENT. DO NOT BREATHE DUST. AVOID GENERATING EXCESSIVE DUST. USE A VACUUM TO COLLECT THE PRODUCT. COLLECT AND CONTAIN IN SUITABLE DISPOSAL CONTAINERS. Section 07: HANDLING AND STORAGE HANDLING PROCEDURES AND ................ MINIMIZE DUST GENERATION AND EXPOSURE. AVOID ALL SKIN CONTACT. AVOID EQUIPMENT GETTING IN EYES. USE ADEQUATE VENTILATION. KEEP CONTAINERS CLOSED OR SEALED. MAINTAIN A GOOD PERSONAL HYGIENE. STORAGE NEEDS........................................ STORE IN A COOL, DRY AREA. PRODUCT OR COMPONENT IS A POWERFUL OXIDER, HENCE IT SHOULD NOT BE STORED NEAR ORGANIC MATTER OR OTHER EASILY OXIDIZABLE SUBSTANCES, EG. SULFUR, SULFIDES, PHOSPHIDES, HYPOPHOSPHIDES, ETC, OR INCOMPATIBLE MATERIALS SUCH AS HYDROGEN PEROXIDE AND SODIUM PEROXIDE. KEEP THE CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. Section 08: EXPOSURE CONTROLS/PERSONAL PROTECTION GLOVES/ TYPE............................................. LEATHER WORK GLOVES. RESPIRATORY/TYPE................................... USE NIOSH/MSHA APPROVED RESPIRATORY PROTECTION (AIR PURIFYING OR AIR SUPPLYING) WHEN CONCENTRATIONS ARE ABOVE EXPOSURE LIMIT VALUE. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 29 CFR PART 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT THE USE OF A RESPIRATOR. EYE/TYPE..................................................... SAFETY GOGGLES. FOOTWEAR/TYPE........................................ SAFETY SHOES. CLOTHING/TYPE.......................................... WEAR IMPERVIOUS PROTECTIVE CLOTHING. OTHER/TYPE................................................ EYE BATH AND SAFETY SHOWER. ENGINEERING CONTROLS......................... CONTROL AIRBORNE CONCENTRATIONS BELOW THE EXPOSURE GUIDELINE. LOCAL EXHAUST AND GENERAL ROOM VENTILATION ARE REQUIRED TO MEET EXPOSURE STANDARDS. LOCAL EXHAUST VENTILATION SHOULD BE USED TO MINIMIZE DUST. Section 09: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE........................................ BLACK TO BROWNISH BLACK AND AVAILABLE IN VARIOUS SIZE RANGES FROM GRANULAR TO FINE POWDERS. ODOUR......................................................... ODOURLESS. ODOUR THRESHOLD.................................. N.AV. VAPOUR PRESSURE (MMHG).................... N.AP. VAPOUR DENSITY (AIR=1).......................... N.AP. BY VOLUME BY WEIGHT EVAPORATION RATE.................................. N.AP. BOILING POINT............................................ N.AP. PH.................................................................. (10% AQUEOUS SLURRY). 9-10. BULK DENSITY............................................. N.AV. MELTING POINT (C)..................................... 535. SPECIFIC GRAVITY (WATER=1)................. 5.0. SOLUBILITY IN WATER (% W/W)................ SLIGHT. COEFFICIENT OF WATER/OIL DIST........... N.AV. 00003895 MATERIAL SAFETY DATA SHEET Page 3 CODE: 567220 PRODUCT: BRICKOX 6807 Section 10: STABILITY AND REACTIVITY CHEMICAL STABILITY: YES................................................................ YES. NO, WHICH CONDITIONS? COMPATABILITY WITH OTHER SUBSTANCES: YES NO, WHICH ONES?...................................... PYROLUSITE (MNO2) IS A POWERFUL OXIDIZER, HENCE IT SHOULD NOT BE HEATED OR RUBBED WITH ORGANIC MATTER OR TOTHER EASILY OXIDIZABLE SUBSTANCES, EG. SULFUR, SULFIDES, PHOSPHIDES, HYPOPHOSPHIDES, ETC. MATERIAL IS FLAMMABLE BY CHEMICAL REACTION. INCOMPATIBLE WITH HYDROGEN PEROXIDE AND SODIUM PEROXIDE. KEEP AWAY FROM HEAT AND FLAMMABLE MATERIALS. REACTIVITY CONDITIONS?........................ CONTACT WITH INCOMPATIBLES. HAZARDOUS PRODUCTS OF .................... NONE. DECOMPOSITION HAZARDOUS POLYMERIZATION............... WILL NOT OCCUR. Section 11: TOXICOLOGICAL INFORMATION EXPOSURE LIMIT OF MATERIAL................ MANGANESE COMPOUND (AS MN) 0.2 MG/M3. IRON OXIDE 10 MG/M3. QUARTZ (CRYSTALLINE SILICA) 10 MG/M3. ALUMINUM OXIDE 15 MG/M3. BARIUM OXIDE - NOT AVAILABLE. SIGNS AND SYMPTOMS OF EXPOSURE:. EARLY SYMPTOMS OF MANGANESE TOXICITY INCLUDE SLUGGISHNESS, SLEEPINESS, AND WEAKNESS IN LEGS. SYMPTOMS OF SILICOSIS INCLUDE IMPAIRED PULMONARY FUNCTION AND WHEEZING. CARCINOGENICITY OF MATERIAL............ CRYSTALLINE SILICA (QUARTZ) IS LISTED AS A CARCINOGEN BY NTP, IARC AND OSHA. CHRONIC TOXICITY:................................... CHRONIC EXPOSURE AND INHALATION OF EXCESSIVE MANGANESE DUST MAY CAUSE DISORDERS OF THE CENTRAL NERVOUS SYSTEM. REPRODUCTIVE EFFECTS......................... N.AV. IRRITANCY OF MATERIAL.......................... SEE SECTION 03. SENSITIZING CAPABILITY OF MATERIAL. N.AV. SYNERGISTIC MATERIALS......................... NONE. AGGRAVATION OF PRE-EXISTING ........... PERSONS WITH IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE CONDITIONS: TO THE EFFECT OF THIS SUBSTANCE. Section 12: ECOLOGICAL CONSIDERATIONS ENVIRONMENTAL STATEMENT................. NO DATA AVAILABLE. Section 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL....................................... IN ACCORDANCE WITH MUNICIPAL, PROVINCIAL AND FEDERAL REGULATIONS. Section 14: TRANSPORT INFORMATION TDG CLASSIFICATION................................. NOT REGULATED. SPECIAL SHIPPING INSTRUCTIONS......... N.AP. Section 15: REGULATORY INFORMATION WHMIS CLASSIFICATION............................ C. D2A. D2B. CPR COMPLIANCE...................................... THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. Section 16: OTHER INFORMATION N.AV.=NOT AVAILABLE N.AP.=NOT APPLICABLE
