Nickel Carbonate Paste

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Product NICKEL carbon PASTE skin applicable MATERIAL water carbon PASTE Brenntag PASTE Brenntag Canada protective eye irritant CHEMICAL
<p>MATERIAL SAFETY DATA SHEET
NICKEL CARBONATE PASTE
3. HAZARDS IDENTIFICATION
Causes skin and eye irritation. May cause skin sensitization or other allergic responses. Cancer hazard. 
See "Other Health Effects" Section. Can decompose at high temperatures forming toxic gases.
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS
Product is irritating to the nose, throat and respiratory tract. Prolonged exposure to processing fumes 
may cause eye and respiratory tract irritation.  Overexposure may cause headaches and nausea. See 
"Other Health Effects" Section.
Inhalation:
This product may cause irritation due to abrasive action. May cause defatting, drying and cracking of 
the skin. Prolonged and repeated contact may lead to dermatitis. May cause skin sensitization or other 
allergic responses ( dermatitis, nickel itch ).
Skin Contact:
A single, prolonged skin exposure is not likely to result in the absorption of toxic amounts of the material.
Skin Absorption:
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON  (416) 226-6117                     Montreal, QC (514) 861-1211                     Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754                  Calgary, AB  (403) 263-8660                       Vancouver, BC (604) 685-5036
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Brenntag Canada Inc.
43 Jutland Rd.
Toronto, ON
M8Z 2G6
(416) 259-8231
Website:  http:\\www.brenntag.ca
WHMIS#:
00064575
Index: 
2007 March 27
PRODUCT IDENTIFICATION
Nickel Carbonate Paste.
Product Name:  
2007 March 27
Date of Revision:
Effective Date:
HCI3387/07A
Nickel Carbonate.
Chemical Name:
Carbonic Acid, Nickel Salt, C.I. 77779, Nickel Carbonate (1:1), Nickel (2+) Carbonate, Nickel 
Monocarbonate, Nickelous Carbonate.
Synonyms:
Inorganic metal salt.
Chemical Family:
NiCO3.
Molecular Formula:
Glass colouring. Chemical intermediate. Sewage and waste water treatment.
Product Use:
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
D-2A:  Very Toxic (carcinogen)
D-2B:  Toxic (skin sensitizer, skin & eye irritant)
Ingredient
CAS#
ACGIH TLV
% Concentration
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
Nickel Carbonate
3333-67-3
0.2 mg/m3 (I)  as 
Ni
95 - 100
Nickel Carbonate Paste
Brenntag Canada Inc.
Date of Revision:
2007 March 27
WHMIS Number :
00064575
Page 2 of 6
4. FIRST AID MEASURES
FIRST AID PROCEDURES
Move victim to fresh air.  Give artificial respiration ONLY if breathing has stopped.  Give 
cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse.  Obtain medical attention 
IMMEDIATELY.
Inhalation:
Start flushing while removing contaminated clothing. Wash affected areas thoroughly with soap and 
water. If irritation, redness, or a burning sensation develops and persists, obtain medical advice.
Skin Contact:
Immediately flush eyes with running water for a minimum of 20 minutes.  Hold eyelids open during 
flushing.  If irritation persists, repeat flushing.  Obtain medical attention IMMEDIATELY.
Eye Contact:
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not 
convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material.  IMMEDIATELY contact 
local Poison Control Centre.  Vomiting should only be induced under the direction of a physician or a 
poison control centre.  If spontaneous vomiting occurs, have victim lean forward with head down to 
avoid breathing in of vomitus, rinse mouth and administer more water.  IMMEDIATELY transport victim 
to an emergency facility.
Ingestion:
Treat symptomatically.
Note to Physicians:
This product may cause irritation, redness and possible damage due to abrasiveness.
Eye Contact:
This product may cause mild gastrointestinal discomfort. Ingestion of large amounts may cause 
intestinal obstruction.
Ingestion:
Effects (irritancy) on the skin and eyes may be delayed, and damage may occur without the sensation 
or onset of pain.  Strict adherence to first aid measures following any exposure is essential.
Nickel catalyst can react under certain conditions (low temperatures and high pressures) with carbon 
monoxide to form nickel carbonyl.  This is highly toxic and lethal to humans at 30 ppm for 20 minutes 
exposure.  Symptoms are headaches and vomiting.  Delayed symptoms (12 - 36 hours after exposure) 
include blue colouration of the skin, decreased white blood cell count and difficulty breathing.  (3)
Other Health Effects:
5. FIRE-FIGHTING MEASURES
Flashpoint (°C)
AutoIgnition 
Temperature (°C)
LEL
UEL
Flammability Limits in Air (%):  
Does not flash.
Not applicable.
Not applicable.
Not applicable.
Not regulated.
Flammability Class (WHMIS):
Thermal decomposition products are toxic and may include Metal oxides and irritating gases.
Hazardous Combustion 
Products:
Not normally a fire or dust explosion hazard.
Unusual Fire or Explosion 
Hazards:
Not expected to be sensitive to mechanical impact.
Sensitivity to Mechanical Impact:
Not available.
Rate of Burning:
Not available.
Explosive Power:
Not expected to be sensitive to static discharge.
Sensitivity to Static Discharge:
EXTINGUISHING MEDIA
Dry chemical, carbon dioxide or water spray.
Fire Extinguishing Media:
FIRE FIGHTING 
INSTRUCTIONS
Use water spray to cool fire-exposed containers or structures.  Use water spray to disperse vapours.  
Use self-contained breathing apparatus and special protective clothing.
Instructions to the Fire Fighters:
Use self-contained breathing apparatus and protective clothing.
Fire Fighting Protective 
Equipment:
6. ACCIDENTAL RELEASE MEASURES
Nickel Carbonate Paste
Brenntag Canada Inc.
Date of Revision:
2007 March 27
WHMIS Number :
00064575
Page 3 of 6
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons, 
property and the environment.  There may be specific reporting requirements associated with spills, leaks or releases, which change from 
region to region.
Collect product for recovery or disposal.  For release to land, or storm water runoff, contain discharge 
by constructing dykes or applying inert absorbent;  for release to water, utilize damming and/or water 
diversion to minimize the spread of contamination.  Ventilate enclosed spaces.  Notify applicable 
government authority if release is reportable or could adversely affect the environment.
Containment and Clean-Up 
Procedures:
7. HANDLING AND STORAGE
HANDLING
Use normal "good" industrial hygiene and housekeeping practices. Minimize air borne spreading of dust.
Handling Practices:
Do not use in poorly ventilated or confined areas without proper respiratory protection. Local exhaust 
ventilation required.
Ventilation Requirements:
Use only with adequate ventilation and avoid breathing dusts. Avoid contact with eyes, skin or clothing.  
Wash thoroughly with soap and water after handling.  Wash contaminated clothing thoroughly before re-
use.
Other Precautions:
STORAGE
See below.
Storage Temperature (°C):
Local exhaust ventilation required.
Ventilation Requirements:
Store in a cool, well-ventilated area.  Keep away from heat, sparks and flames.  Keep containers 
closed.  Do not expose sealed containers to temperatures above 40° C.
Storage Requirements:
Confirm suitability of any material before using.
Special Materials to be Used for 
Packaging or Containers:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this 
product.  Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific 
protective devices at your workplace.
ENGINEERING CONTROLS
Local exhaust ventilation required. Make up air should be supplied to balance air that is removed by 
local or general exhaust ventilation.
Engineering Controls:
PERSONAL PROTECTIVE 
EQUIPMENT (PPE)
Safety glasses with side shields are recommended to prevent eye contact. Use chemical safety goggles 
when there is potential for eye contact. Contact lenses should not be worn when working with this 
material.
Eye Protection:
Gloves and protective clothing made from rubber or neoprene should be impervious under conditions of 
use.   Prior to use, user should confirm impermeability. Discard contaminated gloves.
Skin Protection:
No specific guidelines available. A NIOSH/MSHA-approved air-purifying respirator equipped with dust, 
mist, fume cartridges for concentrations up to 10. 0 mg/m³ ( Ni ). An air-supplied respirator if 
concentrations are higher or unknown.
If while wearing a respiratory protection, you can smell, taste or otherwise detect anything unusual, or in 
the case of a full facepiece respirator you experience eye irritation, leave the area immediately.  Check 
to make sure the respirator to face seal is still good.  If it is, replace the filter, cartridge or canister.  If 
the seal is no longer good, you may need a new respirator.  (4)
Respiratory Protection:
Wear an impermeable apron and boots. Locate safety shower and eyewash station close to chemical 
handling area. Take all precautions to avoid personal contact.
Other Personal Protective 
Equipment:
EXPOSURE GUIDELINES
SUBSTANCE
ACGIH TLV
(STEL)
OSHA PEL
(TWA)                   (STEL)
NIOSH REL
(TWA)                      (STEL)    
Nickel Carbonate
— 
1.0 mg/m3 as Ni 
--- 
0.015 mg/m³ as Ni 
--- 
9. PHYSICAL AND CHEMICAL PROPERTIES  (Not intended as Specifications)
Nickel Carbonate Paste
Brenntag Canada Inc.
Date of Revision:
2007 March 27
WHMIS Number :
00064575
Page 4 of 6
Solid.
Light green crystals.
Odourless.
Not applicable.
Not available.
Not available.
Not applicable.
Not applicable.
2.6.
Not available.
Not applicable.
Not applicable.
Slightly soluble in water.
Not applicable.
Not available.
Not available.
Not applicable.
Physical State:
Appearance:
Odour:
Odour Threshold (ppm):
Boiling Range (°C):
Melting/Freezing Point (°C):
Vapour Pressure (mm Hg at 20° C):
Vapour Density (Air = 1.0):
Relative Density (g/cc):
Bulk Density:
Viscosity:
Evaporation Rate (Butyl Acetate = 1.0):
Solubility:
% Volatile by Volume:
pH:
Coefficient of Water/Oil Distribution:
Volatile Organic Compounds (VOC):
11. TOXICOLOGICAL INFORMATION
Meaningful toxicological test data could not be found for this product.
TOXICOLOGICAL DATA:
Nickel Carbonate is classified as carcinogenic by ACGIH and IARC.
Carcinogenicity Data:
No adverse reproductive effects are anticipated.
Reproductive Data:
No adverse mutagenic effects are anticipated.
Mutagenicity Data:
No adverse teratogenic effects are anticipated.
Teratogenicity Data:
None known.
Respiratory / Skin Sensitization 
Data:
None known.
Synergistic Materials:
None known.
Other Studies Relevant to 
Material:
12. ECOLOGICAL INFORMATION
Not available. May be harmful to aquatic life at low concentrations.
Ecotoxicity:
Not available. Can be dangerous if allowed to enter drinking water intakes. Do not contaminate 
domestic or irrigation water supplies, lakes, streams, ponds, or rivers.
Environmental Fate:
13. DISPOSAL CONSIDERATIONS
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY
Stable.
Under Normal Conditions:
Not flammable.
Under Fire Conditions:
Will not occur.
Hazardous Polymerization:
Minimize air borne spreading of dust.
Conditions to Avoid:
Strong acids.
Materials to Avoid:
Thermal decomposition products are toxic and may include Metal oxides and irritating gases.
Decomposition or Combustion 
Products:
Nickel Carbonate Paste
Brenntag Canada Inc.
Date of Revision:
2007 March 27
WHMIS Number :
00064575
Page 5 of 6
Not available.
Deactivating Chemicals:
This information applies to the material as manufactured. Dispose of waste material at an approved 
(hazardous) waste treatment/disposal facility in accordance with applicable local, provincial and federal 
regulations.  Do not dispose of waste with normal garbage, or to sewer systems. Reevaluation of the 
product may be required by the user at the time of disposal since the product uses, transformations, 
mixtures and processes may influence waste classification.
Waste Disposal Methods:
See "Waste Disposal Methods".
Safe Handling of Residues:
Empty containers retain product residue and can be dangerous. Dispose of waste material at an 
approved (hazardous) waste treatment/disposal facility in accordance with applicable local, provincial 
and federal regulations.
Disposal of Packaging:
14. TRANSPORTATION INFORMATION
CANADIAN TDG ACT SHIPPING DESCRIPTION:
This product is not regulated by TDG.
Label(s):  Not applicable.          Placard:  Not applicable.
ERAP Index: -----.
Exemptions: None known.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
This product is not regulated by DOT.
Label(s):  Not applicable.          Placard:  Not applicable.
CERCLA-RQ: Not available.
Exemptions: None known.
15. REGULATORY INFORMATION
CANADA
All constituents of this product are included on the DSL.
CEPA - NSNR:
Nickel (and its compounds).
CEPA - NPRI:
Controlled Products Regulations Classification (WHMIS):
D-2A:  Very Toxic (carcinogen)
D-2B:  Toxic (skin sensitizer, skin & eye irritant)
USA
All constituents of this product are included on the TSCA inventory.
Environmental Protection Act:
Carcinogenic, Skin Sensitizer, Skin and Eye Irritant.
OSHA HCS (29CFR 1910.1200):
Text22:
NFPA:  1 Health,   0 Fire,   0 Reactivity   (3)
Text22:
HMIS:  1 Health,   0 Fire,   0 Reactivity   (3)
INTERNATIONAL
The following component or components of this product appear on the European Inventory of Existing Commercial Chemical 
Substances:   Nickel Carbonate.
16.  OTHER INFORMATION
REFERENCES
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS 
database.
1.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons, 
New York, 1981.
2.
Supplier's Material Safety Data Sheet(s).
3.
CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
4.
Guide to Occupational Exposure Values, 2005, American Conference of Governmental Industrial Hygienists, Cincinnati, 2005.
5.
Regulatory Affairs Group, Brenntag Canada Inc.
6.
The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical 
7.
Nickel Carbonate Paste
Brenntag Canada Inc.
Date of Revision:
2007 March 27
WHMIS Number :
00064575
Page 6 of 6
Association, Ottawa, 1981.
____________________________________________________________________________________________________________
The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith 
by technically knowledgeable personnel.  It is not intended to be all-inclusive and the manner and conditions of use and handling may 
involve other and additional considerations.  No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for 
any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained 
herein.  This Material Safety Data Sheet is valid for three years.
____________________________________________________________________________________________________________
To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia:  20333-102B Avenue, Langley, BC, V1M 3H1
         Phone:  (604) 513-9009         Facsimile:  (604) 513-9010
Alberta:   6628 - 45 th. Street, Leduc, AB, T9E 7C9
         Phone:  (780) 986-4544         Facsimile:  (780) 986-1070
Manitoba:  681 Plinquet Street, Winnipeg, MB, R2J 2X2
         Phone:  (204) 233-3416         Facsimile:  (204) 233-7005
Ontario:  43 Jutland Road, Toronto, ON, M8Z 2G6
         Phone:  (416) 259-8231         Facsimile:  (416) 259-6175
Quebec:  2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8
         Phone:  (514) 636-9230         Facsimile:  (514) 636-0877
Atlantic:  A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7
         Phone:  (902) 468-9690         Facsimile:  (902) 468-3085
____________________________________________________________________________________________________________
Prepared By:  Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.
</p>