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3M MATERIAL SAFETY DATA SHEET COMPUBLEND(TM) II BASE V 04/08/2003 Page 1 of 7 Material Safety Data Sheet Copyright, 2003, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: COMPUBLEND(TM) II BASE V MANUFACTURER: 3M DIVISION: Commercial Care Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 04/08/2003 Supercedes Date: 10/24/2002 Document Group: 17-8616-9 Product Use: Specific Use: Disinfectant/Sanitizer Concentrate SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt WATER 7732-18-5 40 - 70 ALKYL (C-14 50%, C-12 40%, C-16 10%) DIMETHYL BENZYL AMMONIUM CHLORIDE 68424-85-1 8.68 OCTYL DECYL DIMETHYL AMMONIUM CHLORIDE 32426-11-2 6.51 ETHOXYLATED C12-C15 ALCOHOLS 68131-39-5 5 - 10 ETHYL ALCOHOL 64-17-5 1 - 5 DIDECYL DIMETHYL AMMONIUM CHLORIDE 7173-51-5 3.91 EDTA TETRASODIUM SALT 64-02-8 1 - 5 DIOCTYL DIMETHYL AMMONIUM CHLORIDE 5538-94-3 2.6 SODIUM METASILICATE 6834-92-0 1 - 5 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Clear, colorless to light amber color, musty odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: Combustible liquid and vapor. May cause chemical eye burns. May cause chemical skin burns. May be fatal if ingested. 3.2 POTENTIAL HEALTH EFFECTS 3M MATERIAL SAFETY DATA SHEET COMPUBLEND(TM) II BASE V 04/08/2003 Page 2 of 7 Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Skin Contact: Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Inhalation: Single exposure, above recommended guidelines, may cause: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Lung Effects: Signs/symptoms may include difficulty breathing, cough, wheezing, weakness, increased heart rate, bluish colored skin (cyanosis), sputum production and changes in lung function tests. Ingestion: Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain, nausea, vomiting, and diarrhea; blood in the feces and/or vomitus may also be seen. May be fatal if swallowed. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Central Nervous System Depression can occur by inhalation with a single exposure above the recommended guidelines or through ingestion. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. WARNING: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. Ingredient C.A.S. No. Class Description Regulation ETHYL ALCOHOL 64-17-5 Group 1 International Agency for Research on Cancer 3.3 POTENTIAL ENVIRONMENTAL EFFECTS This product is a disinfectant; it is toxic to microorganisms. Care must be taken to avoid improper disposal or release to the environment. When properly handled, use of this product is expected to have minimal environmental impact. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. 3M MATERIAL SAFETY DATA SHEET COMPUBLEND(TM) II BASE V 04/08/2003 Page 3 of 7 Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15 minutes. Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. 4.2 NOTE TO PHYSICIANS Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression, and convulsion may be needed. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point 133 ºF [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available OSHA Flammability Classification: Class II Combustible Liquid 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. Unusual Fire and Explosion Hazards: Combustible liquid and vapor. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non- sparking tools. Ventilate the area with fresh air. Contain spill. Avoid contact with incompatible materials listed in the Reactivity Data Section. Dilute in a large excess of water. Carefully, and with stirring, add appropriate dilute acid such as sulfamic acid or vinegar. Confirm neutrality. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Place in a metal container approved for use in transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene. Cover, but do not seal for 48 hours. Dispose of collected material as soon as possible. 3M MATERIAL SAFETY DATA SHEET COMPUBLEND(TM) II BASE V 04/08/2003 Page 4 of 7 In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Avoid eye contact with vapors, mists, or spray. Avoid breathing of vapors, mists or spray. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Avoid contact with oxidizing agents. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment. Keep out of the reach of children. Avoid creasing or impacting side walls. 7.2 STORAGE Store away from areas where product may come into contact with food or pharmaceuticals. Store away from acids. Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. Keep container in well-ventilated area. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Full Face Shield, Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber, Neoprene, Nitrile Rubber. 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid contamination of food. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information ETHYL ALCOHOL ACGIH TWA 1000 ppm Table A4 ETHYL ALCOHOL OSHA TWA 1000 ppm Table Z-1 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) 3M MATERIAL SAFETY DATA SHEET COMPUBLEND(TM) II BASE V 04/08/2003 Page 5 of 7 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Liquid Odor, Color, Grade: Clear, colorless to light amber color, musty odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point 133 ºF [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available Boiling point Approximately 212 ºF Density 1.0 [Details: [Ref Std: Water=1]] Specific Gravity Approximately 1 [Ref Std: WATER=1] pH Approximately 12.6 Melting point Not Applicable Solubility in Water Complete Evaporation rate No Data Available Volatile Organic Compounds 1 - 5 % [Test Method: calculated per CARB title 2] Percent volatile 65 - 70 % VOC Less H2O & Exempt Solvents 110 - 130 g/l [Test Method: calculated per CARB title 2] Viscosity <=100 centipoise SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Strong acids Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Chloride During Combustion Oxides of Nitrogen During Combustion SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION CHEMICAL FATE INFORMATION SECTION 13: DISPOSAL CONSIDERATIONS 3M MATERIAL SAFETY DATA SHEET COMPUBLEND(TM) II BASE V 04/08/2003 Page 6 of 7 Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. Combustion products will include HCl. Facility must be capable of handling halogenated materials. EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D002 (Corrosive) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number UPC ID Number UPC 70-0711-2569-7 00-48011-34710-3 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes FIFRA Status Registration Number Registered 6836-139-10350 CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 3 Flammability: 2 Reactivity: 0 Special Hazards: None Corrosive: Yes National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 3 Flammability: 2 Reactivity: 0 Protection: X - See PPE section. Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and Coatings Association (NPCA). DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF 3M MATERIAL SAFETY DATA SHEET COMPUBLEND(TM) II BASE V 04/08/2003 Page 7 of 7 TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com
