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MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 2001, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: COMMERCIAL CARE DIVISION TRADE NAME: 3M Brand CARPET STAIN REMOVER, HEAVY DUTY ID NUMBER/U.P.C.: 61-5000-0317-5 00-48011-08112-0 61-5000-6134-8 00-48011-14004-4 FX-0100-0470-8 - - - FZ-0100-0395-7 - - - FZ-0100-0467-4 - - - FZ-0100-0468-2 - - - XN-1014-3526-3 - - - ISSUED: September 18, 2001 SUPERSEDES: March 17, 2000 DOCUMENT: 10-2822-4 ----------------------------------------------------------------------------- 1. INGREDIENT C.A.S. NO. PERCENT ----------------------------------------------------------------------------- WATER................................... 7732-18-5 40 - 70 TETRACHLOROETHYLENE..................... 127-18-4 7 - 13 2-BUTOXYETHANOL......................... 111-76-2 7 - 13 ISOBUTANE............................... 75-28-5 5 - 10 SODIUM LAURYL SULFATE................... 151-21-3 3 - 7 STYRENE MALEIC ANHYDRIDE RESIN AMMONIUM SALT.................................. 143496-13-3 1 - 5 PROPANE................................. 74-98-6 1 - 5 IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24 HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT. This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372: TETRACHLOROETHYLENE 2-BUTOXYETHANOL ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT:................. 212 F VAPOR PRESSURE:................ N/D VAPOR DENSITY:................. N/D EVAPORATION RATE:.............. N/D ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand CARPET STAIN REMOVER, HEAVY DUTY September 18, 2001 PAGE 2 ----------------------------------------------------------------------------- 2. PHYSICAL DATA (continued) ----------------------------------------------------------------------------- SOLUBILITY IN WATER:........... complete SPECIFIC GRAVITY:.............. 0.995 Water=1 PERCENT VOLATILE:.............. ca. 90 % pH:............................ 9.9 VISCOSITY:..................... N/D MELTING POINT:................. N/D APPEARANCE AND ODOR: Aerosol, liquid, clear, mild odor ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT:................... N/A (liquid only-no FP; propellent FP < 0 F) FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water spray, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. Water may not effectively extinguish fire; however, it should be used to keep fire- exposed containers and surfaces cool and prevent explosive rupture. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section for products of combustion. Closed containers exposed to heat from fire may build pressure and explode. NFPA HAZARD CODES: HEALTH: 2 FIRE: 1 REACTIVITY: 0 AEROSOL STORAGE: 1 UNUSUAL REACTION HAZARD: none ----------------------------------------------------------------------------- 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Heat. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand CARPET STAIN REMOVER, HEAVY DUTY September 18, 2001 PAGE 3 ----------------------------------------------------------------------------- 4. REACTIVITY DATA (continued) ----------------------------------------------------------------------------- HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Sulfur, Hydrogen Chloride, Phosgene, Toxic Vapors, Gases or Particulates. ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Ventilate area. Extinguish all ignition sources. Evacuate unprotected personnel from hazard area. Place leaking containers in a well-ventilated area, preferrably in an exhaust hood, if available, or outdoors. RECOMMENDED DISPOSAL: Incinerate in a permitted hazardous waste incinerator in the presence of a combustible material. Do not puncture or burn cans in a household incinerator. Facility must be capable of handling aerosol cans. Combustion products will include HCl. ENVIRONMENTAL DATA: Not determined. REGULATORY INFORMATION: Volatile Organic Compounds: ca. 315 gms/liter South Coast Air Quality Mgmt Dist Method Rule 443.1, calculated. VOC Less H2O & Exempt Solvents: N/D. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = D001 (Ignitable) D039 (Tetrachloroethylene) EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: Yes REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water. Get immediate medical attention. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand CARPET STAIN REMOVER, HEAVY DUTY September 18, 2001 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID (continued) ----------------------------------------------------------------------------- SKIN CONTACT: Flush skin with large amounts of water. If irritation persists, get medical attention. INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: Avoid eye contact. SKIN PROTECTION: Avoid prolonged or repeated skin contact. RECOMMENDED VENTILATION: Use in a well-ventilated area. RESPIRATORY PROTECTION: Avoid prolonged breathing of spray or mists. PREVENTION OF ACCIDENTAL INGESTION: Do not ingest. RECOMMENDED STORAGE: Store at temperatures below 120 degrees F (49 degrees C). Keep out of the reach of children. FIRE AND EXPLOSION AVOIDANCE: Aerosol container contains flammable gas under pressure. Keep away from heat, sparks, open flame, and other sources of ignition. Do not pierce or burn container, even after use. HMIS HAZARD RATINGS: HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions, section 7.) ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand CARPET STAIN REMOVER, HEAVY DUTY September 18, 2001 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* ----------------------------------------------------------------------------- WATER................................ NONE NONE NONE NONE TETRACHLOROETHYLENE.................. 25 PPM TWA ACGIH TETRACHLOROETHYLENE.................. 100 PPM STEL ACGIH TETRACHLOROETHYLENE.................. 25 PPM TWA OSHAV OSHA VACATED PEL TETRACHLOROETHYLENE.................. 100 PPM TWA OSHA TETRACHLOROETHYLENE.................. 200 PPM CEIL OSHA 2-BUTOXYETHANOL...................... 25 PPM TWA ACGIH Y 2-BUTOXYETHANOL...................... 25 PPM TWA OSHAV Y OSHA VACATED PEL 2-BUTOXYETHANOL...................... 50 PPM TWA OSHA Y ISOBUTANE............................ NONE NONE NONE NONE SODIUM LAURYL SULFATE................ NONE NONE NONE NONE STYRENE MALEIC ANHYDRIDE RESIN AMMONIUM SALT...................... NONE NONE NONE NONE PROPANE.............................. 1000 PPM TWA OSHA PROPANE.............................. 2500 PPM TWA ACGIH * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - OSHA: Occupational Safety and Health Administration - OSHAV: Occupational Safety and Health Administration Vacated PEL. Vacated Permissible Exposure Limits (PEL) are enforced as the OSHA PEL in some states. Check with your local regulatory authority. - NONE: None Established ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: Moderate Eye Irritation: signs/symptoms can include redness, swelling, pain, tearing, and hazy vision. SKIN CONTACT: Mild Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swelling, and itching. May be absorbed through the skin and produce effects similiar to ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand CARPET STAIN REMOVER, HEAVY DUTY September 18, 2001 PAGE 6 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- those caused by inhalation and/or ingestion. INHALATION: Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. Prolonged or repeated overexposure, above recommended guidelines, may cause: Kidney Effects: signs/symptoms can include reduced urine volume, blood in urine and back pain. Liver Effects: signs/symptoms can include yellow skin(jaundice) and tenderness of upper abdomen. IF SWALLOWED: Ingestion is not a likely route of exposure to this product. Ingestion may cause: Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. Aspiration Pneumonitis: signs/symptoms can include coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal. CANCER: WARNING: Contains a chemical which can cause cancer. (127-18-4) (NTP anticipated human carcinogen, IARC probable human carcinogen 2A, Calif. Proposition 65) ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- HEALTH HAZARD DATA SECTION CHANGED SINCE March 17, 2000 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand CARPET STAIN REMOVER, HEAVY DUTY September 18, 2001 PAGE 7 ----------------------------------------------------------------------------- The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
