SODIUM XYLENE SULPHONATE , 40 % SOLUTION

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SODIUM XYLENE SULPHONATE PRODUCT MATERIAL water Contact irritant skin SOLUTION Brenntag Canada protective
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SODIUM XYLENE SULPHONATE PRODUCT MATERIAL water Contact irritant skin SOLUTION Brenntag Canada protective
<p>MATERIAL SAFETY DATA SHEET
SODIUM XYLENE SULPHONATE , 40 % SOLUTION
3. HAZARDS IDENTIFICATION
Causes skin irritation. Mists or sprays are irritating to eyes and respiratory tract. Can decompose at high 
temperatures forming toxic gases.
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS
Prolonged or repeated overexposure to mists may cause mild respiratory irritation. If heated to the point 
where Sulphur Dioxide gas is driven off, then this gas is highly irritating to the respiratory tract. Acute 
exposure may result in dryness and irritation of the nose and throat, choking, sneezing, coughing and 
bronchospasm.  Severe overexposure may cause death through systemic acidosis, pulmonary oedema 
or from respiratory arrest.  Prolonged or repeated exposure may cause impaired lung function, 
bronchitis, hacking cough, nasal irritation and discharge, increased fatigue, alteration in the senses of 
taste and smell and longer duration of common colds.  Dental caries, loss of fillings, gum disorders and 
the rapid and painless destruction of teeth may result from overexposure.  (3)
Inhalation:
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON  (416) 226-6117                     Montreal, QC (514) 861-1211                     Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754                  Calgary, AB  (403) 263-8660                       Vancouver, BC (604) 685-5036
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Brenntag Canada Inc.
43 Jutland Rd.
Toronto, ON
M8Z 2G6
(416) 259-8231
Website:  http:\\www.brenntag.ca
WHMIS#:
00061677
Index: 
2006 October 19
PRODUCT IDENTIFICATION
Sodium Xylene Sulphonate , 40 % Solution.
Product Name:  
2006 October 19
Date of Revision:
Effective Date:
HCI0525/06D
Benzenesulfonic acid, dimethyl-, sodium salt.
Chemical Name:
SXS401; SXS-40; Naxonate; Xylenesulfonic acid, sodium salt; Sodium dimethylbenzenesulfonate.
Synonyms:
Dimethylbenzene sulfonic acid salt.
Chemical Family:
C8H10O3S . Na .
Molecular Formula:
Surfactant. Chemical intermediate. Industrial solvent, cleaner, degreaser. Hydrotopic solvent. Coupling 
agent.
Product Use:
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
D-2B:  Toxic (skin irritant)
Ingredient
CAS#
ACGIH TLV
% Concentration
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
Sodium Xylene Sulphonate
1300-72-7
--- 
30 - 60
Sodium Xylene Sulphonate , 40 % Solution
Brenntag Canada Inc.
Date of Revision:
2006 October 19
WHMIS Number :
00061677
Page 2 of 6
4. FIRST AID MEASURES
FIRST AID PROCEDURES
Move victim to fresh air.  Give artificial respiration ONLY if breathing has stopped.  Give 
cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse.  Obtain medical attention 
IMMEDIATELY.
Inhalation:
Start flushing while removing contaminated clothing. Wash affected areas thoroughly with soap and 
water. If irritation, redness, or a burning sensation develops and persists, obtain medical advice.
Skin Contact:
Immediately flush eyes with running water for a minimum of 20 minutes.  Hold eyelids open during 
flushing.  If irritation persists, repeat flushing.  Obtain medical attention IMMEDIATELY.
Eye Contact:
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not 
convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material.  IMMEDIATELY contact 
local Poison Control Centre.  Vomiting should only be induced under the direction of a physician or a 
poison control centre.  If spontaneous vomiting occurs, have victim lean forward with head down to 
avoid breathing in of vomitus, rinse mouth and administer more water.  IMMEDIATELY transport victim 
to an emergency facility.
Ingestion:
This product contains materials that may cause severe pneumonitis if aspirated.  If ingestion has 
occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to 
prevent aspiration.  Observe patient for respiratory difficulty from aspiration pneumonitis.  Give artificial 
resuscitation and appropriate chemotherapy if respiration is depressed. Medical conditions that may be 
aggravated by exposure to this product include diseases of the skin, eyes or respiratory tract.
Note to Physicians:
Contact may cause irritation, redness and swelling. Prolonged, confined (especially under the finger 
nails, under rings or watch bands) or repeated exposure may cause skin irritation. May cause more 
severe response if skin is abraded (scratched, scraped or cut). Prolonged and repeated contact may 
lead to dermatitis.
Skin Contact:
A single, prolonged skin exposure is not likely to result in the absorption of toxic amounts of the material.
Skin Absorption:
Splashes to the eye may cause irritation, redness and pain.
Eye Contact:
Ingestion is not a likely route of exposure. This product may cause mild gastrointestinal discomfort. May 
cause nausea and vomiting.
Ingestion:
Effects (irritancy) on the skin and eyes may be delayed, and damage may occur without the sensation 
or onset of pain.  Strict adherence to first aid measures following any exposure is essential.
Other Health Effects:
5. FIRE-FIGHTING MEASURES
Flashpoint (°C)
AutoIgnition 
Temperature (°C)
LEL
UEL
Flammability Limits in Air (%):  
> 93  (3)
Not available.
Not available.
Not available.
Not regulated.
Flammability Class (WHMIS):
Thermal decomposition products are toxic and may include oxides of carbon and sulphur.
Hazardous Combustion 
Products:
Spilled material may cause floors and contact surfaces to become slippery.
Unusual Fire or Explosion 
Hazards:
Not expected to be sensitive to mechanical impact.
Sensitivity to Mechanical Impact:
Not available.
Rate of Burning:
Not available.
Explosive Power:
Not expected to be sensitive to static discharge.
Sensitivity to Static Discharge:
EXTINGUISHING MEDIA
Dry Chemical. Water fog. Carbon Dioxide. Foam. Not normally a fire hazard.  Water content of product 
prevents ignition.  The product can support combustion if water evaporates.
Fire Extinguishing Media:
FIRE FIGHTING 
INSTRUCTIONS
Use water spray to cool fire-exposed containers or structures.  Use water spray to disperse vapours.
Instructions to the Fire Fighters:
Sodium Xylene Sulphonate , 40 % Solution
Brenntag Canada Inc.
Date of Revision:
2006 October 19
WHMIS Number :
00061677
Page 3 of 6
Use self-contained breathing apparatus and protective clothing.
Fire Fighting Protective 
Equipment:
6. ACCIDENTAL RELEASE MEASURES
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons, 
property and the environment.  There may be specific reporting requirements associated with spills, leaks or releases, which change from 
region to region.
In all cases of leak or spill contact vendor at Emergency Number shown on the front page of this MSDS. 
Wear protective clothing. Collect product for recovery or disposal.  For release to land, or storm water 
runoff, contain discharge by constructing dykes or applying inert absorbent;  for release to water, utilize 
damming and/or water diversion to minimize the spread of contamination.  Ventilate enclosed spaces.  
Notify applicable government authority if release is reportable or could adversely affect the environment.
Containment and Clean-Up 
Procedures:
7. HANDLING AND STORAGE
HANDLING
Use normal "good" industrial hygiene and housekeeping practices. Spilled material may cause floors 
and contact surfaces to become slippery.
Handling Practices:
See Section 8, "Engineering Controls".
Ventilation Requirements:
Use only with adequate ventilation and avoid breathing mists and vapours. Avoid contact with eyes, skin 
or clothing.  Wash thoroughly with soap and water after handling.  Wash contaminated clothing 
thoroughly before re-use.
Other Precautions:
STORAGE
See below.
Storage Temperature (°C):
See below.
Ventilation Requirements:
Store in a cool, well-ventilated area.  Keep away from heat, sparks and flames.  Keep containers 
closed.  Do not expose sealed containers to temperatures above 40° C.
Storage Requirements:
No specific guidelines available. Confirm suitability of any material before using.
Special Materials to be Used for 
Packaging or Containers:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this 
product.  Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific 
protective devices at your workplace.
ENGINEERING CONTROLS
General exhaust is acceptable. Local exhaust ventilation preferred. Make up air should be supplied to 
balance air that is removed by local or general exhaust ventilation.
Engineering Controls:
PERSONAL PROTECTIVE 
EQUIPMENT (PPE)
Safety glasses with side shields are recommended as minimal eye protection. Use chemical safety 
goggles when there is potential for eye contact. Contact lenses should not be worn when working with 
this material.
Eye Protection:
Gloves and protective clothing made from natural rubber, plastic, neoprene, PVC or viton should be 
impervious under conditions of use.   (4) Prior to use, user should confirm impermeability. Discard 
contaminated gloves.
Skin Protection:
No specific guidelines available. A NIOSH/MSHA-approved air-purifying respirator equipped with 
organic vapour cartridges for concentrations up to 1 000 ppm organic vapours. An air-supplied 
respirator if concentrations are higher or unknown.
Respiratory Protection:
Wear regular work clothing. The use of coveralls is recommended. Locate safety shower and eyewash 
station close to chemical handling area. Take all precautions to avoid personal contact.
Other Personal Protective 
Equipment:
None established for this product.
EXPOSURE GUIDELINES
Sodium Xylene Sulphonate , 40 % Solution
Brenntag Canada Inc.
Date of Revision:
2006 October 19
WHMIS Number :
00061677
Page 4 of 6
Liquid.
Clear, yellow liquid.
Mild odour.
Not available.
> 100.    (3)
5.    (3)
18.    (3)
> 1.     (3)
1.2.     (3)
Not available.
5.6 cSt @ 25 °C.
< 1.
Soluble in water.
40 - 60.
7 - 11.     (3)
> 1.
Not applicable.
Physical State:
Appearance:
Odour:
Odour Threshold (ppm):
Boiling Range (°C):
Melting/Freezing Point (°C):
Vapour Pressure (mm Hg at 20° C):
Vapour Density (Air = 1.0):
Relative Density (g/cc):
Bulk Density:
Viscosity:
Evaporation Rate (Butyl Acetate = 1.0):
Solubility:
% Volatile by Volume:
pH:
Coefficient of Water/Oil Distribution:
Volatile Organic Compounds (VOC):
9. PHYSICAL AND CHEMICAL PROPERTIES  (Not intended as Specifications)
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL DATA:
SUBSTANCE
LD50 (Oral, Rat)
LD50 (Dermal, Rabbit)
LC50 (Inhalation, Rat, 4h)
Sodium Xylene Sulphonate
> 2 000 mg/kg (3)
--- 
--- 
The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP.
Carcinogenicity Data:
No adverse reproductive effects are anticipated.
Reproductive Data:
No adverse mutagenic effects are anticipated.
Mutagenicity Data:
No adverse teratogenic effects are anticipated.
Teratogenicity Data:
None known.
Respiratory / Skin Sensitization 
Data:
None known.
Synergistic Materials:
None known.
Other Studies Relevant to 
Material:
12. ECOLOGICAL INFORMATION
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY
Stable.
Under Normal Conditions:
Not normally a fire hazard.  Water content of product prevents ignition.  The product can support 
combustion if water evaporates.
Under Fire Conditions:
Will not occur.
Hazardous Polymerization:
High temperatures, sparks, open flames and all other sources of ignition.
Conditions to Avoid:
Avoid materials that are not compatible with water. Strong oxidizers. Hydrogen Peroxide. bromine. 
Chromic Acid.
Materials to Avoid:
Thermal decomposition products are toxic and may include oxides of carbon and sulphur.
Decomposition or Combustion 
Products:
Sodium Xylene Sulphonate , 40 % Solution
Brenntag Canada Inc.
Date of Revision:
2006 October 19
WHMIS Number :
00061677
Page 5 of 6
Sodium Xylene Sulphonate :  
48-hour EC50 ( Daphnia magna ) = 1, 000 mg/L (3)
96-hour LC50 ( Fathead Minnow ) = 1, 000 mg/L (3)
Ecotoxicity:
This product is biodegradable.
Environmental Fate:
13. DISPOSAL CONSIDERATIONS
None required.
Deactivating Chemicals:
This information applies to the material as manufactured. Reevaluation of the product may be required 
by the user at the time of disposal since the product uses, transformations, mixtures and processes 
may influence waste classification. Dispose of waste material at an approved (hazardous) waste 
treatment/disposal facility in accordance with applicable local, provincial and federal regulations.  Do not 
dispose of waste with normal garbage, or to sewer systems.
Waste Disposal Methods:
See "Waste Disposal Methods".
Safe Handling of Residues:
Empty containers retain product residue and can be dangerous. Do not dispose of package until 
thoroughly washed out.
Disposal of Packaging:
14. TRANSPORTATION INFORMATION
CANADIAN TDG ACT SHIPPING DESCRIPTION:
This product is not regulated by TDG.
Label(s):  Not applicable.          Placard:  Not applicable.
ERAP Index: -----.
Exemptions: None known.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
This product is not regulated by DOT.
Label(s):  Not applicable.          Placard:  Not applicable.
CERCLA-RQ: Not available.
Exemptions: None known.
15. REGULATORY INFORMATION
CANADA
All constituents of this product are included on the DSL.
CEPA - NSNR:
Not included.
CEPA - NPRI:
Controlled Products Regulations Classification (WHMIS):
D-2B:  Toxic (skin irritant)
USA
All constituents of this product are included on the TSCA inventory.
Environmental Protection Act:
Skin Irritant.
OSHA HCS (29CFR 1910.1200):
Text22:
NFPA:  1 Health,   0 Fire,   0 Reactivity   (3)
Text22:
HMIS:  1 Health,   0 Fire,   0 Reactivity   (3)
INTERNATIONAL
EINECS (European Inventory of Existing Commercial Chemical Substances), MITI (Japan) and ACOIN (Australia). (3)
16.  OTHER INFORMATION
REFERENCES
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS 
database.
1.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons, 
New York, 1981.
2.
Sodium Xylene Sulphonate , 40 % Solution
Brenntag Canada Inc.
Date of Revision:
2006 October 19
WHMIS Number :
00061677
Page 6 of 6
Supplier's Material Safety Data Sheet(s)
3.
CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
4.
Guide to Occupational Exposure Values, 2005, American Conference of Governmental Industrial Hygienists, Cincinnati, 2005.
5.
Regulatory Affairs Group, Brenntag Canada Inc.
6.
The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical 
Association, Ottawa, 1981.
7.
____________________________________________________________________________________________________________
The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith 
by technically knowledgeable personnel.  It is not intended to be all-inclusive and the manner and conditions of use and handling may 
involve other and additional considerations.  No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for 
any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained 
herein.  This Material Safety Data Sheet is valid for three years.
____________________________________________________________________________________________________________
To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia:  20333-102B Avenue, Langley, BC, V1M 3H1
         Phone:  (604) 513-9009         Facsimile:  (604) 513-9010
Alberta:   6628 - 45 th. Street, Leduc, AB, T9E 7C9
         Phone:  (780) 986-4544         Facsimile:  (780) 986-1070
Manitoba:  681 Plinquet Street, Winnipeg, MB, R2J 2X2
         Phone:  (204) 233-3416         Facsimile:  (204) 233-7005
Ontario:  43 Jutland Road, Toronto, ON, M8Z 2G6
         Phone:  (416) 259-8231         Facsimile:  (416) 259-6175
Quebec:  2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8
         Phone:  (514) 636-9230         Facsimile:  (514) 636-0877
Atlantic:  A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7
         Phone:  (902) 468-9690         Facsimile:  (902) 468-3085
____________________________________________________________________________________________________________
Prepared By:  Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.
</p>