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28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: RISALAH DATA KESELAMATAN BAHAN MATERIAL SAFETY DATA SHEET 1. Pengenalan Produk dan Syarikat 1. Product and Company Identification Produk: Product: Diaseton alkohol Diacetone alcohol Nombor MSDS: MSDS number: 28 Nombor bahan: Material number: 80028 Celanese Pte Ltd 501 Orchard Road Wheelock Place #11-01 Singapore 238880 Tel No: (65) 67331767 Nombor telefon kecemasan pengangkutan: + (65) 66639259 (Operations Room direct dial) + (65) 62656917 (Operations Room direct dial) + (65) 62650177(Switchboard, ask for Operations Room) or fax request to +(65) 62644190 (Facsimile to Operations Room) +(65) 62664696 (Facsimile to Operations Room) or email to opsroom@semco.psa.com.sg or Call CHEMTREC 703 527 3887 (USA), collect calls accepted "+" = International Dialing Access Code ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 1 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: 2. Komposisi/ Maklumat tentang Ramuan 2. Composition / Information on Ingredients Komponen Component No. CAS CAS Number % Berat Percent % Status kawalselia OSHA: OSHA hazard category: 2-Pentanon, 4-hidroksi-4-metil- DIACETONE ALCOHOL 123-42-2 99 Berbahaya Hazardous 3. Pengenalan Bahaya 3. Hazards Identification Perihalan produk Product Description Rupa: Appearance: Cecair jernih, tak berwarna dan mudah bergerak (boleh beransur-ansur menjadi kuning semasa disimpan). Clear, colorless, mobile liquid (can gradually turn yellow during storage). ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 2 of 20 Gambaran Menyeluruh Kecemasan: Emergency Overview: AMARAN! WARNING! • Cecair dan wap mudah menyala. • Flammable liquid and vapor. • Menyebabkan kerengsaan mata. • Causes eye irritation. • Boleh menyebabkan kerengsaan trek pernafasan. • May cause respiratory tract irritation. 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: Bau: Odor: Mild, characteristic "ketone" odor. Kesan kesihatan yang berpotensi berlaku Potential health effects Laluan pendedahan: Routes of exposure: Kulit, mata, dihidu, ditelan. Skin, eyes, inhalation, ingestion. Kesan serta merta Immediate effects: Kulit: Skin: Pada asasnya tidak merengsa. Essentially non-irritating. Sentuhan berpanjangan atau berulang kali boleh mengeringkan kulit dan menyebabkan kerengsaan. Prolonged or repeated contact may dry skin and cause irritation. Gejala pendedahan mungkin termasuk: Symptoms of exposure may include: kulit mengering, merekah atau mengalami radang. Drying, cracking or inflammation of skin. Mata: Eyes: Pendedahan kepada wap dan cecair: Exposure to vapors and liquid menyebabkan kerengsaan mata. Causes eye irritation. Gejala pendedahan mungkin termasuk: Symptoms of exposure may include: kerengsaan mata, rasa terbakar atau bisa mata, mata berair, dan/atau perubahan penglihatan Eye irritation, burning sensation, pain, watering, and/or change of vision. ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 3 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: Dihidu: Inhalation: Boleh menyebabkan menyebabkan kerengsaan trek pernafasan. May cause respiratory tract irritation. Gejala pendedahan mungkin termasuk: Symptoms of exposure may include: lelehan hidung, suara garau, batuk-batuk, sakit dada dan kesukaran bernafas. Nasal discharge, hoarseness, coughing, chest pain and breathing difficulty. mual, sakit kepala dan/atau pening. Nausea, headache and/or dizziness. Ditelan: Ingestion: Pada asasnya tidak toksik. Essentially non-toxic. Gejala pendedahan mungkin termasuk: Symptoms of exposure may include: Depresi sistem saraf pusat disertai rasa mual, sakit kepala dan kelembapan mental. Central nervous system depression with nausea, headache and mental sluggishness. Mutagenik: Mutagenic: Menunjukkan hasil bercampur-campur tentang potensi mutagenik in vitro. Shows mixed results for mutagenic potential in vitro. Kesan pada organ sasaran: Target Organ Effects: • Pendedahan terlampau (pendadahan berpanjangan atau berulang kali) boleh menyebabkan: • Overexposure (prolonged or repeated exposure) may cause: Kerengsaan setempat di bahagian yang terdedah Local irritation at the site of exposure ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 4 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: Keadaan perubatan yang umumnya diketahui bertambah buruk oleh pendedahan: Medical Conditions which may be Aggravated by Exposure: Pendedahan yang banyak kepada bahan kimia ini boleh memberikan kesan buruk terhadap orang yang menghidap penyakit akut atau kronik pada organ- organ berikut: Significant exposure to this chemical may adversely affect people with acute or chronic disease of the: Saluran pernafasan Respiratory Tract Kulit Skin Mata Eyes Sistem saraf pusat Central nervous system Bagi mendapatkan maklumat lanjut, lihat: For further information, see: Bahagian 4 - Langkah-Langkah Pertolongan Cemas Bahagian 5 - Langkah-Langkah Memadam Kebakaran Bahagian 6 - Langkah-Langkah Pembebasan Tidak Sengaja Bahagian 8 - Kawalan Pendedahan / Perlindungan Diri Bahagian 9 - Sifat-Sifat Fizikal dan Kimia Bahagian 10 - Kestabilan dan Kereaktifan Section 4 - First Aid Measures Section 5 - Fire Fighting Measures Section 6 - Accidental Release Measures Section 8 - Exposure Controls/Personal Protection Section 9 - Physical and Chemical Properties Section 10 - Stability and Reactivity 4. Langkah-Langkah Pertolongan Cemas 4. First Aid Measures ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 5 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: Kulit: Skin: Siram kulit serta merta dengan air yang banyak. Tanggalkan pakaian dan kasut yang tercemar. Dapatkan rawatan perubatan jika kerengsaan terjadi dan berterusan. Basuh pakaian sebelum menggunakannya semula. Bersihkan kasut sebersih-bersihnya sebelum menggunakannya semula. Immediately flush skin with plenty of water. Remove contaminated shoes and clothing. Get medical attention if irritation develops and persists. Wash clothing before reuse. Thoroughly clean shoes before reuse. Mata: Eyes: Serta merta siram mata dengan air yang banyak selama sekurang-kurangnya 15 minit. Jika mudah, tanggalkan kanta lekap yang dipakai. Dapatkan perhatian perubatan dengan serta merta. Immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get medical attention immediately. Dihidu: Inhalation: Pindahkan ke tempat berudara bersih. Jika tidak bernafas, berikan bantuan pernafasan. Jika sukar bernafas, berikan oksigen. Dapatkan perhatian perubatan. Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ditelan: Ingestion: Jika bahan ini ditelan dalam jumlah yang banyak, panggil doktor dengan serta merta. JANGAN dipaksa muntah kecuali diarahkan oleh kakitangan perubatan. Jangan berikan apa-apa melalui mulut kepada orang yang tidak sedar. Dapatkan perhatian perubatan. If large quantities of this material are swallowed, call a physician immediately. Do NOT induce vomiting unless directed to do so by a physician. Never give anything by mouth to an unconscious person. Get medical attention. 5. Langkah-Langkah Memadam Kebakaran 5. Fire Fighting Measures NFPA: Health: 1 Flammability: 2 Reactivity: 0 Sifat-sifat mudah menyala Flammable properties Takat kilat (kaedah ujian): Flash point (test method): 58.9 C (138 F) (SETA) Had mudah menyala, Dalam udara, % mengikut isipadu Flammable limits in air, % by volume: Atas: Upper: 6.9% ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 6 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: Bawah: Lower: 1.8% Suhu swapencucuhan: Autoignition temperature: Not determined. Hasil Pembakaran: Products of combustion: Karbon Monoksida. Carbon Monoxide. Media pemadam: Extinguishing Media: Gunakan busa pembentuk selaput akueus jenis alkohol bagi kebakaran besar. Use alcohol type aqueous film forming foam for large fires. Gunakan CO2 atau kimia kering bagi kebakaran kecil. Use CO2 or dry chemical for small fires. Petunjuk Memadam Kebakaran Fire Fighting Instructions Semburan air patut digunakan bagi menyejukkan struktur dan wadah yang terdedah kepada api. Semburan air boleh digunakan bagi mengurangkan keamatan api dan mencairkan tumpahan menjadi campuran tidak mudah menyala. Water spray should be used to cool fire-exposed structures and vessels. Water spray can be used to reduce the intensity of flames and to dilute spills to a non- flammable mixture. Kakitangan hendaklah dipindahkan dan dipastikan berada di atas arah tiupan angin ke api. Jika ada kemungkinan pendedahan kepada wap atau produk pembakaran, pakai pakaian bomba yang lengkap serta alat pernafasan swalengkap yang diluluskan NIOSH. Bahan kimia yang mengoksida mungkin mencepatkan kadar pembakaran dalam keadaan kebakaran. Keep personnel removed from and upwind of fire. If potential for exposure to vapors or products of combustion exists, wear full fire fighting turnout gear and NIOSH approved self-contained breathing apparatus. Oxidizing chemicals may accelerate the burning rate in a fire situation. Persoalan Alam Sekitar Semasa Memadam Kebakaran Fire Fighting Environmental Concerns Kelengkapan pakaian bunker dan peralatan memadam kebakaran yang lain hendaklah dibersihkan daripada pencemaran sebelum digunakan semula. Thoroughly decontaminate bunker gear and other fire-fighting equipment before re- use. ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 7 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: 6. Langkah-Langkah Pembebasan Tidak Sengaja 6. Accidental Release Measures ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 8 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: Petunjuk Tumpahan atau Kebocoran Spill or Leak Instructions Hapuskan punca-punca pencucuhan. Eliminate ignition sources. Lihat peralatan perlindungan diri di Bahagian 8. Tumpahan hendaklah ditampung dengan benteng tanah atau bahan penyerap yang tidak mudah menyala bagi mengurangkan kawasan yang tercemar. See Section 8 for appropriate personal protective equipment. Contain spill with dikes of soil or nonflammable absorbent to minimize contaminated area. Jika ada potensi kebakaran, selimutkan tumpahan dengan busa pembentuk selaput akueus jenis alkohol atau gunakan aliran kabut air untuk menyebarkan wap. If fire potential exists, blanket spill with alcohol type aqueous film-forming foam or use water fog stream to disperse vapors. Hindarkan pengaliran ke dalam pembetung dan parit yang membawa ke saluran air. Jika dikehendaki, maklumkan pihak berkuasa negeri dan tempatan. Letakkan bekas yang bocor di kawasan yang sempurna pengudaraannya. Avoid run-off into storm sewers and ditches leading to waterways. If required, notify state and local authorities. Place leaking containers in well-ventilated area. Bersihkan tumpahan kecil dengan menggunakan bahan penyerap tidak mudah menyala atau dengan menyiram sedikit-sedikit dengan air. Tampung tumpahan besar dengan benteng atau bahan penyerap tidak mudah menyala. Bersihkan dengan vakum atau menyapu. Clean up small spills by using a nonflammable absorbent or flushing sparingly with water. Contain larger spills with nonflammable diking or absorbent. Clean up by vacuuming or sweeping. Orang yang tidak perlu jangan dibiarkan dekat; pencilkan kawasan bahaya dan jangan benarkan masuk. Pastikan berada di atas arah tiupan angin; jauhi kawasan rendah. Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Pencilkan sejauh 800 meter atau 0.5 batu di semua arah jika tangki, gerabak, atau lori tangki terbabit dalam kebakaran. Isolate for 800 meters or 0.5 miles in all directions if tank, rail car, or tank truck in involved in fire. Taksir situasi tumpahan, kerana tumpahan mungkin tidak menghasilkan banyak bahan pencemar bawaan udara yang berbahaya dalam kebanyakan situasi tumpahan di luar. Mungkin wajar dalam hal-hal tertentu untuk memantau keadaan sahaja hingga produk tumpah itu dihapuskan. Assess the spill situation, as the spill may not evolve large amounts of hazardous airborne contaminants in many outdoor spill situations. It may be advisable in some ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 9 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: cases to simply monitor the situation until spilled product is removed. 7. Penanganan dan Penyimpanan 7. Handling and Storage Penanganan: Handling: Gunakan dengan pengudaraan memadai. Bekas hendaklah sentiasa ditutup apabila tidak digunakan. Bekas hendaklah dibuka perlahan-lahan bagi melepaskan lebihan tekanan. Jangan menghidu wapnya. Hindarkan daripada terkena mata, kulit atau pakaian. Basuh tubuh bersih-bersih dengan sabun dan air setelah menanganinya. Pakaian kotor hendaklah dibersihkan daripada pencemaran sebelum digunakan semula. Pakaian daripada kulit hendaklah dimusnahkan jika tercemar. Use with adequate ventilation. Keep containers closed when not in use. Always open containers slowly to allow any excess pressure to vent. Avoid breathing vapor. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling. Decontaminate soiled clothing thoroughly before re-use. Destroy contaminated leather clothing. Produ ini mungkin membangkitkan cas statik. Bumikan/ikat peralatan peralatan apabila memindahkan bahan bagi mencegah penumpukan statik. Di AS, peralatan elektrik dan litar dalam semua situasi penyimpanan dan penanganan mesti mematuhi Kod Elektrik Nasion (Perkara 500 dan 501) bagi lokasi berbahaya. This product may generate a static charge. Ground/bond equipment when transferring material to prevent static accumulation. Electrical equipment and circuits in all storage and handling must conform to requirements of National Electric Code (Article 500 and 501) for hazardous location. Penyimpanan: Storage: Semua bekas hendaklah sentiasa ditutup ketat apabila tidak digunakan. Simpan secara terlindung daripada sinaran matahari langsung dan di lantai yang tidak telus. Keep all containers tightly closed when not in use. Store out of direct sunlight and on an impermeable floor. Janga simpan bersama bahan yang tidak serasi. Lihat Bahagian 10. Kestabilan dan Kereaktifan. Do not store with incompatible materials. See Section 10. Stability and Reactivity. ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 10 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: 8. Kawalan Pendedahan / Perlindungan Diri 8. Exposure Controls / Personal Protection Kawalan kejuruteraan Engineering Controls: Pengudaraan umum atau sebaran sering kali tidak mencukupi sebagai satu- satunya cara mengawal pendedahan pekerja. Biasanya pendedahan setempat lebih diutamakan. General or dilution ventilation is frequently insufficient as the sole means of controlling employee exposure. Local ventilation is usually preferred. Peralatan pelindung diri Protective Equipment Tempat mandi keselamatan dan tempat membasuh mata harus disediakan di tempat mudah didapatkan. A safety shower and eyebath should be readily available. Perlindungan kulit: Skin Protection: Pakai pakaian dan sarung tangan tidak telus bagi menghindari sentuhan. Disarankan supaya menggunakan neoprena. Bahan pelindung yang lain boleh digunakan, mengikut keadaan, sekiranya ada data yang memadai tentang degradasi dan penelapan. Jika bahan kimia lain digunakan bersama bahan kimia ini, pemilihan bahan harus berdasarkan perlindungan terhadap semua bahan kimia yang hadir. Wear impervious clothing and gloves to prevent contact. Neoprene is recommended. Other protective material may be used, depending on the situation, if adequate degradation and permeation data is available. If other chemicals are used in conjunction with this chemical, material selection should be based on protection for all chemicals present. Perlindungan mata/muka: Eye/face protection: Pakai gogal kimia jika ada kemungkinan munasabah akan terkena mata. Wear chemical goggles when there is a reasonable chance of eye contact. ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 11 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: Perlindungan pernafasan: Respiratory Protection: Berdasarkan aras pencemaran dan had bekerja alat pernafasan, gunakan alat pernafasan yang diluluskan oleh NIOSH. Berikut adalah peralatan minimum disarankan bagi aras pendedahan pekerjaan. Bagi menganggarkan pendedahan pekerjaan lihat Bahagian 3, Bahagian 8 dan Bahagian 11. Based on workplace contaminant level and working limits of the respirator, use a respirator approved by NIOSH. The following is the minimum recommended equipment for an occupational exposure level. To estimate an occupational exposure level see Section 3, Section 8 and Section 11. Bagi kadar kepekatan > 1 dan <10 kali aras pendedahan pekerjaan: Gunakan alat pernafasan pemurni udara dengan pelindung muka penuh dan kartrij wap organik atau alat pernafasan pemurni udara berpelindung muka penuh dengan bejana wap organik atau alat pernafasan kuasa pemurni udara berpelindung muka penuh yang dilengkapi kartrij wap organik. Elemen pemurni udara harus dilengkapi penunjuk tamat hayat perkhidmatan, atau harus disahkan dengan dokumentasi jika ada perubahan tidak mengikut jadual. Jika tidak, gunakan bekalan udara. For concentrations > 1 and < 10 times the occupational exposure level: Use air- purifying respirator with full facepiece and organic vapor cartridge(s) or air-purifying full facepiece respirator with an organic vapor canister or a full facepiece powered air-purifying respirator fitted with organic vapor cartridge(s). The air purifying element must have an end of service life indicator, or a documented change out schedule must be established. Otherwise, use supplied air. Bagi kadar kepekatan lebih daripada 10 kali aras pendedahan pekerjaan dan kurang daripada 100 kali aras pendedahan pekerjaan atau IDLH, mana yang lebih rendah: Gunakan alat pernafasan bekalan udara berpelindung muka penuh Jenis C dikendalikan dalam cara permintaan tekanan atau aliran terus menerus. For concentrations more than 10 times the occupational exposure level and less than the lower of either 100 times the occupational exposure level or the IDLH: Use Type C full facepiece supplied-air respirator operated in positive-pressure or continuous- flow mode. Bagi kadar kepekatan > 100 kali aras pendedahan pekerjaan atau lebih tinggi daripada aras IDLH atau kadar kepekatan tidak diketahui (misalnya dalam kecemasan): Gunakan alat pernafasan swalengkap dengan pelindung muka penuh dalam cara tekanan positif atau alat pernafasan bekalan udara tekanan positif berpelindung muka penuh Jenis C dengan sistem lolos alat pernafasan swalengkap tekanan positif bantu. For concentrations > 100 times the occupational exposure level or greater than the IDLH level or unknown concentrations (such as in emergencies): Use self-contained breathing apparatus with full facepiece in positive-pressure mode or Type C positive-pressure full facepiece supplied-air respirator with an auxiliary positive- pressure self-contained breathing apparatus escape system. Untuk lolos: Gunakan alat pernafasan swalengkap dengan pelindung muka ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 12 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: penuh atau mana-mana alat pernafasan yang khusus diluluskan bagi meloloskan diri. For escape: Use self-contained breathing apparatus with full facepiece or any respirator specifically approved for escape. Garis panduan pendedahan Exposure guidelines Komponen Component No. CAS CAS Number % Berat Percent % ACGIH TWA ACGIH STEL ACGIH CEILING OSHA TWA OSHA STEL OSHA CEILING WEL (Had Pendedah an Tempat Kerja) Celanese Celanese WEL (Workplace Exposure Limit) Mexico TWA Mexico STEL Mexico CEILING 2-Pentanon, 4- hidroksi-4-metil- DIACETONE ALCOHOL 123-42-2 99 50 ppm - - 50 ppm - - - 50 ppm 75 ppm - Komponen Component No. CAS CAS Number % Berat Percent % 1990 NIOSH IDLH (Recognized by OSHA) 1994 NIOSH IDLH 2-Pentanon, 4-hidroksi-4-metil- DIACETONE ALCOHOL 123-42-2 99 2100 PPM 1800 ppm Comments: * Workplace Exposure Limit 9. Sifat-Sifat Fizikal dan Kimia 9. Physical and Chemical Properties Rupa: Appearance: Cecair jernih, tak berwarna dan mudah bergerak (boleh beransur-ansur menjadi kuning semasa disimpan). Clear, colorless, mobile liquid (can gradually turn yellow during storage). Bau: Odor: Mild, characteristic "ketone" odor. Tekanan Wap: Vapor Pressure: 0.97 ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 13 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: Ketumpatan wap (udara = 1 pada 20o C): Vapor Density (Air=1 @ 20 C): 4.0 Takat didih (760 mmHgA): Boiling Point (760 mmHgA): 168.0 C (334.4 F) Takat beku: Freezing Point: -48.0 C (-54.4 F) Keterlarutan dalam air pada 20o C: Solubility in Water @ 20 C: 100% Graviti tentu: Specific Gravity: 0.94 Berat molekul: Molecular Weight: 116.0 Kadar penyejatan (n-Butil asetat = 1): Evaporation Rate (n-Butyl acetate = 1): 0.15 10. Kestabilan dan Kereaktifan 10. Stability and Reactivity Kestabilan: Stability: Stabil. Stable. ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 14 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: Keadaan yang harus dihindarkan: Conditions to Avoid: Produk ini higroskopik. Satu kaedah bagi mengeluarkan lembapan mesti disediakan bagi mencegah pencemaran dan kemungkinan terbentuknya polimer. Avoid heat , flames, sparks, and other sources of ignition. Bahan yang harus dihindarkan: Incompatibility: Jauhkan dari asid sulfurik dan asid tak organik keras yang lain, aluminum atau plumbum (termasuk peralatan yang dibuat daripada logam tersebut), dan agen pengoksidaan seperti peroksida, asid nitrik, asid perklorik atau kromium trioksida. Keep away from sulfuric and other strong inorganic acids, aluminum or lead (including equipment made of these metals), and oxidizing agents such as peroxides, nitric acid, perchloric acid or chromium trioxide. Hasil Pembakaran atau Penguraian Berbahaya: Hazardous combustion or decomposition products: Hasil penguraian terma boleh termasuk oksida karbon. Thermal decomposition products may include oxides of carbon. Pempolimeran berbahaya: Hazardous Polymerization: Pempolimeran berbahaya tidak akan terjadi. Hazardous polymerization will not occur. 11. Maklumat Toksikologi 11. Toxicological Information Component Toxicological Information ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 15 of 20 Komponen Component 2-Pentanon, 4-hidroksi-4-metil- DIACETONE ALCOHOL 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: 12. Maklumat Ekologi 12. Ecological Information Component Ecological Information ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 16 of 20 Acute Exposure: Oral LD50 : 4 g/kg (rats); slightly toxic to animals. CNS depression, respiratory depression, decreased blood pressure, anemia, liver and kidney damage have been reported in animals at high dose levels near the LD50. Dermal LD50 : 13 g/kg (rabbits); slightly toxic to animals. Diacetone alcohol is not considered a contact sensitizer in guinea pigs. Inhalation : Practically non-toxic to animals (no deaths in rats after 8 hr. saturated vapor exposure). Eye: moderately irritating to rabbit eyes. Mutagenicity : In vitro, not mutagenic in bacteria and yeast; weakly mutagenic in rat liver cells at high concentrations. In vivo, no information. Other : Causes liver and kidney damage in animals via repeated inhalation or oral exposure at high concentrations. Causes potentiation of chloroform-induced liver injury in laboratory animals via oral exposure. 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: 13. Pertimbangan Pelupusan 13. Disposal Considerations Lupuskan bahan tumpah sejajar dengan peraturan negeri dan tempatan bagi bahan buangan berbahaya. Kaedah yang disarankan adalah penunuan atau pengolahan biologi di kemudahan pelupusan yang diizinkan oleh pihak berkuasa negeri atau Persekutuan. Harap ingat bahawa maklumat ini adalah bagi bahan sebagaimana dibuat; pemprosesan, penggunaan, atau pencemaran mungkin menjadikan maklumat ini tidak wajar, tidak tepat atau tidak lengkap. Dispose of spilled material in accordance with state and local regulations for hazardous waste. Recommended methods are incineration or biological treatment at a federally or state-permitted disposal facility. Note that this information applies to the material as manufactured; processing, use, or contamination may make this information inappropriate, inaccurate, or incomplete. Harap ingat bahawa maklumat penanganan dan pelupusan ini juga mungkin terpakai bagi bekas kosong, pelapik dan bahan bilasannya. Peraturan atau sekatan peringkat negeri atau tempatan adalah kompleks dan mungkin berbeza dengan peraturan persekutuan. Maklumat ini dimaksudkan sebagai bantuan bagi penanganan dan pelupusan yang wajar; tanggung jawab muktamad bagi penanganan dan pelupusan terletak di tangan pemilik bahan buangan berkenaan. Lihat Bahagian 9 Sifat-Sifat Fizikal dan Kimia. Note that this handling and disposal information may also apply to empty containers, liners and rinsate. State or local regulations or restrictions are complex and may differ from federal regulations. This information is intended as an aid to proper handling and disposal; the final responsibility for handling and disposal is with the owner of the waste. See Section 9 - Physical and Chemical Properties. Kod Bahan Buangan Berbahaya EPA: EPA Hazardous Waste Code(s): D001 14. Maklumat Pengangkutan 14. Transport Information US Department of Transportation: UN/NA Number: UN 1148 Shipping name: DIACETONE ALCOHOL Hazard class: 3 Packing Group: PG III Emergency Response Guide: 129 ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 17 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: ICAO/IATA: IATA UN Number: UN 1148 Proper Shipping Name: DIACETONE ALCOHOL Hazard Classification: 3 Packing group: III Label: (Flammable Liquid) IMDG: International Marine UN Number: UN 1148 Proper Shipping Name: DIACETONE ALCOHOL Hazard Class: 3 Packing Group: III Takat kilat (kaedah ujian): Flash point (test method): 58.9 C (138 F) (SETA) Transport Canada Proper Shipping Name: DIACETONE ALCOHOL Trade Information Schedule B Code (export): 2914.40.1000 15. Maklumat Kawalselia 15. Regulatory Information INTERNATIONAL REGULATIONS Inventori kimia International chemical inventories: Disenaraikan dalam inventori kimia negara-negara berikut atau layak dikecualikan: Listed on the chemical inventories of the following countries or qualifies for an exemption: AUSTRALIA,CHINA,CANADA,EUROPE,KOREA,PHILIPPINES, JAPAN ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 18 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: 16. Maklumat Lain 16. Other Information Disiapkan oleh: Prepared by: Jabatan Penyeliaan Produk Celanese Ltd. Product Stewardship Department Celanese Ltd. Pentarafan bahaya Hazard ratings Maklumat ini dimaksudkan untuk digunakan hanya oleh mereka yang terlatih dalam sistem NFPA dan/atau HMIS. This information is intended solely for the use of individuals trained in the NFPA and/or HMIS systems. NFPA: Health: 1 Flammability: 2 Reactivity: 0 HMIS: Health: 2 Flammability: 2 Reactivity: 0 Maklumat berikut telah disemak sejak versi terakhir MSDS ini: The following has been revised since the last issue of this MSDS: The following sections have been revised since the last issue of this MSDS. 1. Pengenalan Produk dan Syarikat Maklumat yang terkandung di sini adalah tepat sejauh pengetahuan kami. Kami tidak menyatakan atau menjamin bahawa mana-mana bahaya yang disenaraikan di sini adalah satu-satunya yang wujud. Celanese Ltd. tidak memberi jaminan dalam apa jua bentuk, secara nyata atau tersirat, tentang penggunaan bahan ini yang selamat dalam proses anda atau secara bergabung dengan zat lain. Kesan-kesannya boleh diburukkan oleh bahan lain dan/atau bahan ini pula boleh memburukkan atau menambah kesan-kesan bahan lain. Bahan ini boleh dibebaskan daripada bahan gas, cecair, atau pepejal yang dibuat secara langsung atau tidak langsung daripadanya. Pengguna memikul tanggungjawab tunggal untuk menentukan kesesuaian bahan-bahan bagi apa jua kegunaan dan cara penggunaan yang dirancangkan. Pengguna mesti memenuhi semua piawai keselamatan dan kesihatan yang berkenaan. Lembaran data keselamatan bahan disediakan di Internet oleh Celanese, Ltd. sebagai satu perkhidmatan untuk pelanggannya. Memiliki MSDS Internet tidak menandakan bahawa pemilik MSDS itu adalah pembeli atau pengguna produk yang berkenaan. ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 19 of 20 28 Diacetone alcohol Nombor bahan: Material number:80028 Nama produk: Product name: Tarikh diterbitkan: Published date: 02/02/2006 Nombor MSDS: MSDS number: Note: For industrial use only. The information contained herein is accurate to the best of our knowledge. We do not suggest or guarantee that any hazards listed herein are the only ones which exist. Celanese Ltd. makes no warranty of any kind, express or implied, concerning the safe use of this material in your process or in combination with other substances. Effects can be aggravated by other materials and/or this material may aggravate or add to the effects of other materials. This material may be released from gas, liquid, or solid materials made directly or indirectly from it. User has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated. User must meet all applicable safety and health standards. Material safety data sheets are provided on the Internet by Celanese, Ltd. as a service to its customers. Possession of an Internet MSDS does not indicate that the possessor of the MSDS was a purchaser or user of the subject product. ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------ Kecemasan pengangkutan: Transportation emergency: 703 527 3887 (USA) CHEMTREC, collect calls accepted, 24 hrs/day 20 of 20
