9170.pdf

Loading ...
Global Do...
News & Politics
Material Safety Data Sheet 
Section 1. Product and Company Identification
Product Name
Methyl Violet 2B
Product Code
B35071
Manufacturer
EMD Chemicals Inc.  
P.O. Box 70 
480 Democrat Road  
Gibbstown, NJ 08027 
Prior to January 1, 2003 EMD Chemicals Inc. was EM 
Industries, Inc. or EM Science, Division of EM Industries, 
Inc.
Effective Date
3/4/2003
For More Information Call
In Case of Emergency Call
856-423-6300 Technical Service  
Monday-Friday: 8:00 AM - 5:00 PM
800-424-9300 CHEMTREC (USA)  
613-996-6666 CANUTEC (Canada) 
24 Hours/Day: 7 Days/Week  
Synonym
BASIC VIOLET 1 C.I. #42535
Material Uses
Analytical reagent.  
Chemical Family
Triphenylmethane derivative.
Section 2. Composition and Information on Ingredients
Component
CAS #
% by 
Weight
C.I. BASIC VIOLET 1
8004-87-3
100
Section 3. Hazards Identification
Physical State and 
Appearance
Solid. (Crystalline granules solid.)
Emergency Overview
WARNING !  
HARMFUL IF INHALED OR SWALLOWED. 
CAUSES EYE AND SKIN IRRITATION.  
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: 
MUCOUS MEMBRANES.
Routes of Entry
Eye contact. Inhalation. Ingestion. 
Potential Acute Health Effects
Eyes Hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness, watering, 
and itching. 
Skin Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, 
reddening, or, occasionally, blistering. 
Inhalation Hazardous in case of inhalation. 
Ingestion Hazardous in case of ingestion. 
Potential Chronic Health Effects
Carcinogenic Effects This material is not known to cause cancer in animals or humans. 
Additional information See Toxicological Information (section 11)
Medical Conditions 
Aggravated by 
Overexposure:
Repeated exposure to a highly toxic material may produce general deterioration of health by an 
accumulation in one or many human organs. 
Section 4. First Aid Measures
Eye Contact
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water 
for at least 15 minutes. Cold water may be used. Get medical attention immediately. 
Skin Contact
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing 
contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be 
used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention 
immediately. 
Inhalation
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give 
oxygen. Get medical attention immediately. 
Ingestion
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything 
by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get 
medical attention immediately. 
Section 5. Fire Fighting Measures
Flammability of the Product Non-flammable.
Auto-ignition Temperature Not applicable.
Flash Points
Not applicable.
Page 1 of 4
Methyl Violet 2B
2/10/2006
http://www.emdchemicals.com/analytics/doc/msds/MSDSU_B35071.htm
Flammable Limits
Not applicable.
Products of Combustion
Not applicable.
Fire Hazards in Presence of 
Various Substances
Not applicable.
Explosion Hazards in 
Presence of Various 
Substances
Risks of explosion of the product in presence of static discharge: No.  
 
Risks of explosion of the product in presence of mechanical impact: No.
Fire Fighting Media  
and Instructions
Not applicable.
Protective Clothing (Fire) Not applicable.
Special Remarks on Fire 
Hazards
Not available.
Special Remarks on 
Explosion Hazards
Not available.
Section 6. Accidental Release Measures
Small Spill and Leak
Use appropriate tools to put the spilled solid in a convenient waste disposal container. 
Large Spill and Leak
Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray 
to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for 
assistance on disposal. Finish cleaning by spreading water on the contaminated surface and allow to 
evacuate through the sanitary system. 
Spill Kit Information
No specific spill kit required for this product. Contain and collect spillage with non-combustible 
absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth, and place in container for disposal 
according to local regulations (see section 13).
Section 7. Handling and Storage
Handling
Avoid contact with eyes, skin and clothing. Do not ingest. Avoid breathing dust. Keep container closed. 
Use only with adequate ventilation. Wash thoroughly after handling. 
Storage
Keep container tightly closed. Keep container in a cool, well-ventilated area. 
Section 8. Exposure Controls/Personal Protection
Engineering Controls
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels 
below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to 
keep exposure to airborne contaminants below the exposure limit. 
Personal Protection
Eyes Splash goggles. 
Body Lab coat. 
Respiratory Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator 
when ventilation is inadequate.
Hands Gloves. 
Feet Not applicable.
Protective 
Clothing 
(Pictograms)
Personal Protection in Case 
of a Large Spill
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self-contained breathing apparatus should be 
used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a 
specialist BEFORE handling this product.
Product Name
Exposure Limits
C.I. BASIC VIOLET 1
Not available.
Section 9. Physical and Chemical Properties
Odor
Odorless.
Color
Green.
Physical State and 
Appearance
Solid. (Crystalline granules solid.)
Molecular Weight
393.94 g/mole
Molecular Formula
C24H28N3CL
pH
Not available.
Boiling/Condensation Point Not available.
Melting/Freezing Point
Decomposition temperature: 137°C (278.6°F)
Specific Gravity 
Not available.
Vapor Pressure
Not available.
Vapor Density
Not available.
Page 2 of 4
Methyl Violet 2B
2/10/2006
http://www.emdchemicals.com/analytics/doc/msds/MSDSU_B35071.htm
Odor Threshold
Not available.
Evaporation Rate
Not available.
LogKow
Not available.
Solubility
Soluble in water.
Section 10. Stability and Reactivity
Stability and Reactivity
The product is stable.
Conditions of Instability
Not available.
Incompatibility with 
Various Substances
Reactive with oxidizing agents.
Rem/Incompatibility
Avoid Heat Avoid generating dust or vapors.
Hazardous Decomposition 
Products
NOx , COx , Chlorine compounds
Hazardous Polymerization Will not occur.
Section 11. Toxicological Information
RTECS Number:
Methyl Violet (2B)
GC8425000
Toxicity
Acute oral toxicity (LD50): 105 mg/kg [Mouse]. 
Chronic Effects on Humans Contains material which may cause damage to the following organs: mucous membranes.  
Acute Effects on Humans Hazardous in case of eye contact (irritant). Inflammation of the eye is characterized by redness, watering, 
and itching. Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, 
scaling, reddening, or, occasionally, blistering. Hazardous in case of inhalation. Hazardous in case of 
ingestion. 
Synergetic Products 
(Toxicologically)
Not available.
Irritancy
Draize Test: Not available.
Sensitization
Not available.
Carcinogenic Effects
This material is not known to cause cancer in animals or humans. 
Toxicity to Reproductive 
System
Not available.
Teratogenic Effects
Not available.
Mutagenic Effects
Tests on laboratory animals for mutagenic effects are cited in Registry of Toxic Effects of Chemical 
Substances (RTECS).
Section 12. Ecological Information
Ecotoxicity
Not available.
BOD5 and COD
Not available.
Toxicity of the Products of 
Biodegradation
The products of degradation are less toxic than the product itself.
Section 13. Disposal Considerations
EPA Waste Number
Not available.
Treatment
Material does not have an EPA Waste Number and is not a listed waste, however consultation with a 
permitted waste disposal site (TSD) should be accomplished. ALWAYS CONTACT A PERMITTED 
WASTE DISPOSAL (TSD) TO ASSURE COMPLIANCE WITH ALL CURRENT LOCAL, STATE 
AND FEDERAL REGULATIONS.
Section 14. Transport Information
DOT Classification
Not available.
TDG Classification
Not available.
IMO/IMDG 
Classification
Not available.
ICAO/IATA 
Classification
Not available.
Section 15. Regulatory Information
U.S. Federal Regulations
TSCA 8(b) inventory: C.I. BASIC VIOLET 1
SARA 302/304/311/312 extremely hazardous substances: No products were found.  
SARA 302/304 emergency planning and notification: No products were found. 
SARA 302/304/311/312 hazardous chemicals: No products were found.  
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found.
Page 3 of 4
Methyl Violet 2B
2/10/2006
http://www.emdchemicals.com/analytics/doc/msds/MSDSU_B35071.htm
SARA 313 toxic chemical notification and release reporting: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
WHMIS (Canada)
Class D-1B: Material causing immediate and serious toxic effects (TOXIC).  
Class D-2B: Material causing other toxic effects (TOXIC).
CEPA DSL: C.I. BASIC VIOLET 1
This product has been classiifed in accordance with the hazard criteria of the Controlled Product 
Regulations and the MSDS contains all required information.
International Regulations
EINECS
Not available.
DSCL (EEC)
R22- Harmful if swallowed.  
R38- Irritating to skin. 
R41- Risk of serious damage to eyes.
International Lists Australia (NICNAS): C.I. BASIC VIOLET 1  
 
Japan (MITI): C.I. BASIC VIOLET 1  
 
Korea (TCCL): C.I. BASIC VIOLET 1  
 
Philippines (RA6969): C.I. BASIC VIOLET 1
China: No products were found.
State Regulations
New Jersey: C.I. BASIC VIOLET 1
California prop. 65: No products were found.
Section 16. Other Information
National Fire 
Protection 
Association 
(U.S.A.)
Health
0
2 0
Fire Hazard
 
Reactivity 
 
Specific Hazard
Changed Since Last 
Revision
+
Notice to Reader
The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable, are offered for 
information purposes only and as a guide to the appropriate precautionary and emergency handling of the material by a 
properly trained person having the necessary technical skills. Users should consider these data only as a supplement to other 
information gathered by them and must make independent determinations of suitability and completeness of information from 
all sources to assure proper use, storage and disposal of these materials and the safety and health of employees and customers 
and the protection of the environment. EMD CHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF 
ANY KIND, EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, 
WITH RESPECT TO THE INFORMATION HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
Page 4 of 4
Methyl Violet 2B
2/10/2006
http://www.emdchemicals.com/analytics/doc/msds/MSDSU_B35071.htm