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M A T E R I A L S A F E T Y D A T A S H E E T SECTION 1. Product and Company Identification Bio Spot Spot On Flea & Tick Control for Cats & Kittens Product Code: 2724-504-270 Product Name: Bio Spot Spot On Flea & Tick Control for Cats & Kittens Manufacturer Name and Address: Telephone Numbers: Dates: WELLMARK INTERNATIONAL Emergency: (602)285-1660 Date Created: 09/20/2006 12200 Denton Dr. Revision: 09/20/2006 Dallas, TX, . Information: (602)285-1660 Printed: 01/19/2007 USA Responsible Person: S.Faith, Regulatory , Phone #: Additional Identity Information Bio Spot Spot On Flea & Tick Control for Cats & Kittens Under 5 Lbs. Bio Spot Spot On Flea & Tick Control for Cats 5 Lbs. and Over SECTION 2. Composition/Information on Ingredients Bio Spot Spot On Flea & Tick Control for Cats & Kittens Hazardous Components (Chemical Name) CAS # Percentage 1. 2,4-Dodecadienoic acid, 11-methoxy-3,7,11-trimethyl-, 1- methylethyl ester, [S-(E,E)]- 65733-16- 6 3.6 % 2. Etofenprox {1-((2-(4-Ethoxyphenyl)-2- methylpropoxy)methyl)- 3-phenoxybenzene} 80844-07- 1 40.0 % OSHA PEL ACGIH TLV 1. No data. No data. 2. No data. No data. SECTION 3. Hazards Identification Bio Spot Spot On Flea & Tick Control for Cats & Kittens Emergency Overview PRECAUTIONARY STATEMENT Keep out of the reach of children. Repeated exposure to etofenprox can cause skin irritation Route(s) of Entry: Inhalation? N.A. , Skin? Yes , Eyes? Yes , Ingestion? Yes Potential Health Effects (Acute and Chronic) ACUTE TOXICITY Oral: LD50 > 5000 mg/kg (rat) Dermal: LD50 > 5,000 mg/kg (rat) Inhalation: (R/S)-Methoprene LC50 (rat)>210 mg/L airEtofenprox: LC50 >5.9 mg/L Carcinogenicity: NTP? N.A. , IARC Monographs? N.A. , OSHA Regulated? N.A. Carcinogenicity/Other Information Recommended Exposure Limits: Not established. LD 50/LC 50: No data available. Signs and Symptoms Of Exposure May cause mild skin irritation. May cause minimal eye irritation. Not a sensitizer. Medical Conditions Generally Aggravated By Exposure SECTION 4. First Aid Measures Bio Spot Spot On Flea & Tick Control for Cats & Kittens Emergency and First Aid Procedures Eye: Hold eyes open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes Skin: Take off contaminated clothing. Rinse skin immediately with planty of water for 15-20 minutes. Call poison control center or doctor for treatment advice. Ingestion: Call a physician or poison control center immediately for guidance. Have a person sip a glass of water if able to swallow. Do not induce vomiting unless told to by a poison control center or doctor. Never give anything by mouth to an unconscious person. Inhalation: Remove affected person to fresh air. Call a poison control center or doctor for further treatment advice. Note to Physician Treat symptomatically. SECTION 5. Fire Fighting Measures Bio Spot Spot On Flea & Tick Control for Cats & Kittens Flash Pt: 112.00 F Method Used: No data. Explosive Limits: LEL: No data. UEL: No data. Extinguishing Media Water, CO2 dry chemicals, foam Fire Fighting Instructions Firefighters should wear full protective clothing including self-contained breathing apparatus. Normal procedures. Do not allow fire fighting water to escape into waterways or sewers. Flammable Properties and Hazards None Known. Hazardous Combustion Products Carbon dioxide and carbon monoxide. SECTION 6. Accidental Release Measures Bio Spot Spot On Flea & Tick Control for Cats & Kittens Steps To Be Taken In Case Material Is Released Or Spilled Steps to be taken: Do not allow spill to enter waterways inhabited by aquatic organisms. Soak up with absorbent material and place in a suitable container for disposal. Absorbents: Clay granules, sawdust, dirt or equivalent. Incompatibles: Strong oxidizing agents SECTION 7. Handling and Storage Bio Spot Spot On Flea & Tick Control for Cats & Kittens Precautions To Be Taken in Handling Avoid contact with eyes, skin or clothing. Wash hands after handling. Precautions To Be Taken in Storing Keep out of the reach of children. Do not store near food or food stuff. Other Precautions SECTION 8. Exposure Controls/Personal Protection Bio Spot Spot On Flea & Tick Control for Cats & Kittens Respiratory Equipment (Specify Type) See below. Eye Protection See below. Protective Gloves See below. Other Protective Clothing Not needed if product is used according to label. If prolonged exposure is anticipated, it is recommended to wear impervious gloves and safety glasses. Engineering Controls (Ventilation etc.) General ventilation is sufficient under normal use conditions. Work/Hygienic/Maintenance Practices Wash hands thoroughly with soap and water after handling and before eating, drinking smoking or using restroom. SECTION 9. Physical and Chemical Properties Bio Spot Spot On Flea & Tick Control for Cats & Kittens Physical States: [ ] Gas , [ ] Liquid , [ ] Solid Boiling Point: No data. Melting Point: No data. Specific Gravity (Water = 1): 0.000000 Density: NE Vapor Pressure (vs. Air or mm Hg): NE Vapor Density (vs. Air = 1): NE Evaporation Rate (vs Butyl Acetate=1): NE Solubility in Water: Insoluble Percent Volatile: No data. Saturated Vapor Concentration: NE Viscosity: NE pH: NE Appearance and Odor Pale yellow liquid with pleasant, weak fruit-like odor SECTION 10. Stability and Reactivity Bio Spot Spot On Flea & Tick Control for Cats & Kittens Stability: Unstable [ ] Stable [ X ] Conditions To Avoid - Instability Incompatibility - Materials To Avoid Incompatibility w/ Other Materials: Strong oxidizing agents Hazardous Decomposition Or Byproducts Carbon monoxide and Carbon dioxide Hazardous Polymerization: Will occur [ ] Will not occur [ X ] Conditions To Avoid - Hazardous Polymerization SECTION 11. Toxicological Information Bio Spot Spot On Flea & Tick Control for Cats & Kittens CHRONIC TOXICITY Methoprene [Based on (RS) Methoprene Tech]is not a carcinogen. The NOEL for non- carcinogenic effects in an 18 month mouse study was 250 ppm. Etofenprox is not a human carcinogen (EPA Category C). It is not listed as a carcinogen by NTP or IARC and is not regulated by OSHA. In rats the target organs are the liver and thyroid. The NOAEL for chronic toxicity is 3.7 mg/kg/day for male rats. The target organ in mice is the kidney. The NOAEL is 3.1 mg/kg/day for mice. SUBCHRONIC TOXICITY Etofenprox is a mild skin irritant after 4-weeks of treatment. No systemic toxicity from dermal exposure was observed at doses up to 1000 mg/kg/day. DEVELOPMENTAL/REPRODUCTIVE TOXICITY Methoprene [Based on (RS) Methoprene Tech] is not a teratogen. The NOEL for maternal and embryo toxicity in rabbits was 200 mg/kg/day. The NOEL for reproductive effects in rats was 2,500 ppm. Etofenprox is not a teratogen. It is does not have adverse effects on reproduction. MUTAGENICITY Methoprene [Based on (S) Methopene Tech] is not a mutagen. Etofenprox is not a mutagen. SECTION 12. Ecological Information Bio Spot Spot On Flea & Tick Control for Cats & Kittens ENVIRONMENTAL FATE (RS) Methoprene Etofenprox Hydrolysis: T1/2 > 4 week N/A Photolysis: T1/2 < 6 hours N/A Soil half life: ~ 10 days N/A Water solubility: 0.52 ppm N/A ECOTOXICITY Acute Toxicity: (S) Methoprene Technical: LC50 (trout): 760ppb, LC50 (Bluegill): >370ppb; aquatic invertebrates: LC50 (Daphnia): 360 ppbEtofenprox Technical: extremely toxic to fish and aquatic invertebrates. LC50 (trout) 3.3 ppb and LC50 (bluegill) 8.5 ppb, SECTION 13. Disposal Considerations Bio Spot Spot On Flea & Tick Control for Cats & Kittens Waste Disposal Method Do not reuse empty tube. If household waste, wrap empty tube and discard in trash. For larger amounts, consult state and local regulations for proper disposal. SECTION 14. Transport Information Bio Spot Spot On Flea & Tick Control for Cats & Kittens DOT Proper Shipping Name Additional Transport Information SECTION 15. Regulatory Information Bio Spot Spot On Flea & Tick Control for Cats & Kittens SECTION 16. Other Information Bio Spot Spot On Flea & Tick Control for Cats & Kittens NFPA Hazard Ratings: Health: 1 Flammability: 1 Instability: NA Special Hazard: Minimal: 0 Slight: 1 Moderate:2 Serious: 3 Extreme: 4 The information and data herein are believed to be accurate and have been compiled from sources believed to be reliable. It is offered for your consideration, investigation and verification.
