Conforms to 93/112/EC and ISO 11014-1
Material Safety Data Sheet
RBS 50 PF
1583
0027965 0027961
CALL CHEMTREC:
800.424.9300
OUTSIDE US:
202.483.7616
11/4/2002
11/12/2002
Product name
Supplier
Manufacturer
Product No.
MSDS#
Validation Date
Print Date
In Case of Emergency
Section 1. Chemical Product and Company Identification
Responsible Name Pierce Administration
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
Eng
In USA:
In Europe:
Pierce
Perbio Science
P.O. Box 117
Industriezone III
Rockford, IL 61105 Industrielaan 27
USA
9320 Erembodegem-Aalst
815.968.0747 or
Belgium
1.800.874.3723
Tel:+32 53 83 44 04

Fax:+32 53 83 76 38
Pierce Biotechnology
P.O. Box 117
Rockford, IL 61105
USA
815.968.0747 or
1.800.874.3723
1) Sodium Hydroxide
1310-73-2
1-3
215-185-5
C
R22, R35, R40
Ingredient Name
EC Number
CAS No.
R-Phrases
Substance/Preparation
Preparation
%
Symbol
:
Section 2. Composition, Information on Ingredients
Physical/chemical hazards
Human health hazards
Environmental hazards Not applicable.
Not applicable.
Not applicable.
Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Emergency Overview
Medical Conditions Aggravated by
Overexposure:
Repeated or prolonged exposure is not known to aggravate medical condition.
Not available.
Overexposure /Signs/Symptoms
Section 3. Hazards Identification
Routes of Entry
Potential Acute Health Effects
Carcinogenic Effects Data
See Toxicological Information (section 11)
Do not get in eyes, on skin or on clothing. Do not breathe vapor or mist. Keep container closed. Use only with adequate
ventilation. Wash thoroughly after handling.
Slightly hazardous in case of skin contact (corrosive, irritant), of eye contact (irritant, corrosive), of ingestion, of inhalation
(lung irritant, lung sensitizer, lung corrosive).
CARCINOGENIC EFFECTS: Classified None. by NIOSH [Sodium Hydroxide].
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
Review the most current and approved institutional guideline, protocol, standard operating procedure(s) and MSDS(s)
for the proper handling of institutional materials/equipment associated with the use of this product.
WARNING!
CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS.
CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS,
MUCOUS MEMBRANES, RESPIRATORY TRACT, SKIN, EYES, EYE, LENS OR CORNEA.
Classification Not controlled under dsd (Europe).
United States
Europe
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RBS 50 PF
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Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Skin Contact
Ingestion
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly
clean shoes before reuse. Get medical attention immediately.
Slightly hazardous in case of inhalation (lung irritant, lung sensitizer, lung corrosive).
Slightly hazardous in case of ingestion.
Sensitization of the product: Not available.
Slightly hazardous in case of skin contact (corrosive, irritant). Skin inflammation is characterized by itching, scaling,
reddening, or, occasionally, blistering.
Skin Contact
Slightly hazardous in case of eye contact (irritant, corrosive).
Eye Contact
Inhalation
Aggravating conditions Repeated or prolonged exposure is not known to aggravate medical condition.
First-Aid Measures
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Notes to Physician Not available.
Not available.
Protection of first-aiders
Ingestion
Effects and symptoms
Inhalation
Eye Contact
Section 4. First Aid Measures
Notice to Reader Get immediate medical attention.
Hazardous thermal (de)composition
products
Some metallic oxides.
Non-flammable.
Not applicable.
Not applicable.
Not applicable.
Section 5. Fire Fighting Measures
Flammability of the Product
Flash Points
Fire Hazards in Presence of Various
Substances
Fire Fighting Media
and Instructions
Not applicable.
Protective Clothing (Fire)
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Neutralize the residue with
a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and allow to evacuate
through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV
on the MSDS and with local authorities.
Section 6. Accidental Release Measures
Small Spill and Leak Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
If necessary: Neutralize the residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the
contaminated surface and dispose of according to local and regional authority requirements.
Environmental Precautions and
Clean-up Methods
Personal precautions Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after
handling.
Section 7. Handling and Storage
Handling
Storage
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
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RBS 50 PF
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Suitable / Not suitable
Packaging materials
Use original container.
1) Sodium Hydroxide
TWA: 2 CEIL: 2 (mg/m3) from BAuA [Germany] [1999] Inhalation
Germany
1) Sodium Hydroxide
TWA: 2 CEIL: 2 (mg/m3) from Arbeidsinspectie [Netherlands] [2000] Inhalation
Netherlands
1) Sodium Hydroxide
TWA: 2 (mg/m3) from INRS [France] [1999] Inhalation
France
1) Sodium Hydroxide
TWA: 2 CEIL: 2 (mg/m3) from Arbeidstilsynet [Norway] [1996] Inhalation
Norway
1) Sodium Hydroxide
TWA: 2 CEIL: 2 (mg/m3) from Arbejdstilsynet [Denmark] [1996] Inhalation
Denmark
1) Sodium Hydroxide
STEL: 2 (mg/m3) from AFS [Sweden] [1996] Inhalation
Sweden
1) Sodium Hydroxide
Not available.
United States
Ingredient Name
Occupational Exposure Limits
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value.
Section 8. Exposure Controls/Personal Protection
Exposure Limit Values
Personal Protection
Eyes
Body
Protective Clothing
(Pictograms)
Safety glasses.
Lab coat.
Liquid. (Detergent)
Basic.
The only known value is 2.13 (Water = 1) (Sodium Hydroxide).
See solubility in water.
Partially soluble in cold water, hot water.
Not applicable.
Not available.
Not available.
Not available.
Physical State and
Appearance
Molecular Weight
pH (1% Soln/Water)
Specific Gravity
Dispersion Properties
Solubility
Odor
Taste
Color
Section 9. Physical and Chemical Properties
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RBS 50 PF
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The product is stable.
Slightly reactive to reactive with metals, acids.
Will not occur.
Not available.
Section 10. Stability and Reactivity
Stability and Reactivity
Conditions to avoid
Materials to avoid
Hazardous Polymerization
Hazardous Decomposition
Products
Some metallic oxides.
Acute oral toxicity (LD50): 16667 mg/kg (Rabbit) (Calculated value for the mixture).
Slightly hazardous in case of eye contact (irritant, corrosive), of ingestion, of inhalation (lung irritant, lung sensitizer, lung
corrosive).
CARCINOGENIC EFFECTS: Classified None. by NIOSH [Sodium Hydroxide].
Not available.
possible irritant
possible irritant
Section 11. Toxicological Information
Toxicity to Animals
Chronic Effects on Humans
Other Toxic Effects on Humans
Special Remarks on Toxicity to
Animals
Special Remarks on Chronic
Effects on Humans
Special Remarks on Other Toxic
Effects on Humans
Ecotoxicity Not available.
Mobility
Germany water class
Not available.
Not available.
Not available.
Persistence/degradability
Bioaccumulative potential
VCI WGK: No products were found.
Section 12. Ecological Information
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Not available.
Waste Information
Waste Stream
Section 13. Disposal Considerations
Consult your local or regional authorities.
Contact the supplier for all information regarding the proper transportation method for this material.
Section 14. Transport Information
Section 15. Regulatory Information
Label Requirements
1
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RBS 50 PF
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U.S. Federal Regulations
Pennsylvania RTK: Sodium Hydroxide: (environmental hazard, generic environmental hazard)
Massachusetts RTK: Sodium Hydroxide
New Jersey: Sodium Hydroxide
--
HCS Classification
California prop. 65: No products were found.
TSCA 8(b) inventory: Sodium Hydroxide
TSCA 8(d) H and S data reporting: Sodium Hydroxide
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: Sodium Hydroxide
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
State Regulations
CEPA DSL: Sodium Hydroxide
Australia (NICNAS): Sodium Hydroxide
Germany water class: Sodium Hydroxide
VCI WGK: No products were found.
Korea (TCCL): Sodium Hydroxide
Philippines (RA6969): Sodium Hydroxide
WHMIS (Canada) CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
This product is not classified according to the EU regulations.
DSCL (EEC)
International Regulations
Not available.
EINECS
International Lists
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Sodium Hydroxide
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Sodium Hydroxide: immediate health hazard
SARA 313 toxic chemical notification and release reporting: No products were found.
This product is not classified according to the EU regulations.
(Europe)
Date of Previous Issue No Previous
Validation
Not available.
Section 16. Other Information
References
Validated by Pierce Administration on 11/4/2002.
Verified by Pierce Administration.
Hazardous Material
Information System
(U.S.A.)
0
0
0
h
0
0
0
*
National Fire Protection
Association (U.S.A.)
Health
Specific Hazard
Reactivity
Fire Hazard
Health
Fire Hazard
Reactivity
Personal Protection
History of Document Changes Any information changes since last document version are marked with a triangle symbol.
Harmful if ingested.
Causes severe burns.
Possible risks of irreversible effects.
Full text of R-Phrases
referenced under headings 2 and 3:
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
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RBS 50 PF
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Version
0.01
Printed 11/12/2002.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.