In USA: In Europe: Thermo Fisher Scientific Perbio Science P.O. Box 117 Industriezone III Rockford, IL 61105 Industrielaan 27 USA 9320 Erembodegem-Aalst 815.968.0747 or Belgium 1.800.874.3723 Tel:+32 53 83 44 04 Fax:+32 53 83 76 38 Conforms to 93/112/EC and ISO 11014-1 Material Safety Data Sheet AminoLink Reductant 44892 1851910 1877390 Product Name Supplier Manufacturer Product no. In case of emergency Section 1. Chemical Product and Company Identification Responsible Name MSDS_Specialist Synonyms Sodium Cyanotrihydroborate; Sodium cyanotrihydridoborate; Sodium borocyanohydride; Use of the substance/preparation Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications. borate(1-), (cyano-c)trihydro-, sodium, (t-4)- Chemical name Eng CHEMTREC: 800.424.9300 OUTSIDE US: 703.527.3887 Print date 8/30/2007 8/30/2007 Validation date MSDS# 1235 Pierce 3747 N. Meridian Road P.O. Box 117 Rockford, IL 61105 USA 815.968.0747 or 1.800.874.3723 (815)968-7316 fax www.thermo.com Substance/preparation Substance : Section 2. Composition, Information on Ingredients CAS number Ingredient name % EC number Classification AminoLink Reductant 25895-60-7 98 - 100 247-317-2 F; R11, 15 T+; R26/27/28 C; R34 R32 N; R50/53 Dermal contact. Eye contact. Inhalation. Ingestion. Emergency overview Section 3. Hazards identification Routes of entry Do not ingest. Do not get in eyes, on skin or clothing. Do not breathe dust. Keep away from heat, sparks and flame. Will react with water or steam to produce heat and toxic fumes. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Review the most current and approved institutional guideline, protocol, standard operating procedure(s) and MSDS(s) for the proper handling of institutional materials/equipment associated with the use of this product. Danger! MAY BE FATAL IF INHALED, ABSORBED THROUGH SKIN OR SWALLOWED. CAUSES SEVERE RESPIRATORY TRACT, EYE AND SKIN BURNS. FLAMMABLE SOLID. SPILLAGE MAY CAUSE FIRE OR LIBERATE POISONOUS GAS. CONTACT WITH WATER MAY CAUSE FLASH FIRE. CAUSES DAMAGE TO THE FOLLOWING ORGANS: BLOOD. United States Potential acute health effects Very toxic by inhalation. Severely corrosive to the respiratory system. Severely corrosive to the eyes. Very toxic in contact with skin. Severely corrosive to the skin. Eyes Skin Inhalation Target organs Causes damage to the following organs: blood. Continued on Next Page AminoLink Reductant Page: 2/8 Physical/chemical hazards Human health hazards Environmental hazards Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Very toxic by inhalation, in contact with skin and if swallowed. Contact with acids liberates very toxic gas. Causes burns. Highly flammable. Contact with water liberates extremely flammable gases. Medical conditions aggravated by overexposure Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. Not available. Over-exposure signs/symptoms Carcinogenic effects See toxicological Information (section 11) CARCINOGENIC EFFECTS: Classified None. by OSHA, None. by NIOSH. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Classification F; R11, 15 T+; R26/27/28 C; R34 R32 N; R50/53 Europe Very toxic if swallowed. May cause burns to mouth, throat and stomach. Ingestion Potential chronic health effects Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin contact Ingestion In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Very hazardous in case of inhalation (lung irritant, lung corrosive). Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing. Over-exposure by inhalation may cause respiratory irritation. May be fatal if inhaled. Extremely hazardous in case of ingestion. May be fatal if swallowed. May cause burns to mouth, throat and stomach. Extremely hazardous in case of skin contact (corrosive). Very hazardous in case of skin contact (irritant). The amount of tissue damage depends on length of contact. Skin contact can produce inflammation and blistering. Skin contact may produce burns. Severe over-exposure can result in death. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Skin contact Extremely hazardous in case of eye contact (corrosive). Very hazardous in case of eye contact (irritant). Eye contact can result in corneal damage or blindness. Inflammation of the eye is characterized by redness, watering, and itching. Eye contact Inhalation Aggravating conditions Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. First-Aid measures If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Notes to physician Not available. Not available. Protection of first-aiders Ingestion Effects and symptoms Inhalation Eye contact Section 4. First aid measures Notice to reader Get immediate medical attention. Continued on Next Page AminoLink Reductant Page: 3/8 Hazardous thermal decomposition products These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...). Some metallic oxides. Flammable. Not available. Use dry chemical or CO2. Do not use water or foam. Not available. Container explosion may occur under fire conditions or when heated. Dangerous fire and explosion risk. FLAMMABLE. Forms flammable and explosive gas and corrosive solid on exposure to moisture. Evolves toxic and flammable gas on contact with acids. Section 5. Fire fighting measures Flammability of the product Flash Points Fire hazards in presence of various substances Fire fighting media and instructions Special Remarks on Fire Hazards Be sure to use an approved/certified respirator or equivalent. Protective clothing (fire) This material is very toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Cover with dry earth, sand or other non-combustible material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Section 6. Accidental release measures Small spill and leak Use appropriate tools to put the spilled solid in a convenient waste disposal container. Environmental precautions and clean-up methods Personal precautions Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Do not ingest. Do not get in eyes, on skin or on clothing. Keep container closed. Use only with adequate ventilation. Do not breathe dust. Keep away from heat, sparks and flame. Will react with water or steam to produce heat and toxic fumes. To avoid fire, minimize ignition sources. Avoid contact of spilled material and runoff with soil and surface waterways. Wash thoroughly after handling. Section 7. Handling and storage Handling Storage Suitable / Not suitable Packaging materials Use original container. Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications. AminoLink Reductant OSHA PEL (United States). Skin : 5 mg/m3 United States Ingredient Name Occupational Exposure Limits Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Section 8. Exposure Controls, Personal Protection Exposure Limit Values AminoLink Reductant KTV: 10 mg/m3 TGV: 5 mg/m3 Sweden Denmark Continued on Next Page AminoLink Reductant Page: 4/8 Personal Protection Eyes Body Hands Protective Clothing (Pictograms) Gloves. Lab coat. Splash goggles. Respiratory Respirator is not needed under normal and intended conditions of use, if exposures are kept below established limits. AminoLink Reductant MAK (Germany). Skin : 5 mg/m3 AminoLink Reductant GV: 5 mg/m3 AminoLink Reductant VME: 5 mg/m3 AminoLink Reductant MAC-TGG (Netherlands). Skin : 5 mg/m3 France Netherlands Germany AminoLink Reductant MAK-W (Switzerland). : 5 mg/m3 Switzerland AminoLink Reductant MAK (Austria). Skin : 5 mg/m3 Austria AminoLink Reductant LTEL (United Kingdom (UK)). Skin : 5 mg/m3 United Kingdom (UK) AminoLink Reductant TWA: 5 mg/m3 STEL: 10 mg/m3 Finland Solid. (Solid powder.) 240 to 242°C (464 to 467.6°F) 1.2 (Water = 1) See solubility in water, methanol. Easily soluble in cold water, hot water, methanol. Insoluble in diethyl ether. 62.84 g/mole Stench. Not available. White to off white. (Light.) Melting/freezing point Physical State Molecular weight Specific Gravity Dispersion properties Solubility Odor Taste Color CH3BNNa Molecular formula Section 9. Physical and chemical properties Explosive properties Flammability (solid, gas) Highly explosive in presence of heat. Highly flammable solid. The product is stable. Extremely reactive or incompatible with acids. Highly reactive with moisture. Reactive with oxidizing agents. The product reacts violently with water to emit flammable but non toxic gases. Will not occur. Keep away from heat and flame. May decompose on exposure to moist air or water. Section 10. Stability and reactivity Stability and Reactivity Conditions to avoid Materials to avoid Hazardous polymerization Continued on Next Page AminoLink Reductant Page: 5/8 Hazardous Decomposition Products Not available. borate(1-), (cyano-c)trihydro-, sodium, (t-4)- LD50: Not available. LC50: Not available. Extremely hazardous in case of eye contact (corrosive), of ingestion, . Very hazardous in case of eye contact (corrosive), of ingestion, . CARCINOGENIC EFFECTS: Classified None. by OSHA, None. by NIOSH. Causes damage to the following organs: blood. Not available. Direct contact with the eyes can cause irreversible damage including blindness. Exposure can cause lung irritation, chest pain and oedema which may be fatal. Exposure can cause nausea, headache and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract. May be fatal. May cause convulsions. Prolonged contact can cause severe irritation or even burns. Reacts violently when water is added to this product. Can cause gastrointestinal disturbances. Exposure can cause coughing, chest pains, difficulty in breathing. Exposure can cause stomach pains, vomiting and diarrhea. Lacrymator. May be fatal, if the substance enters bloodstream. May cause convulsions. Will cause serious damage to the eyes. Chemical pneumonitis. Section 11. Toxicological information Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Special Remarks on Toxicity to Animals Special Remarks on Chronic Effects on Humans Special Remarks on Other Toxic Effects on Humans Skin Ingestion Inhalation No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Over-exposure signs/symptoms Target organs Causes damage to the following organs: blood. No known significant effects or critical hazards. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Reproductive toxicity Ecotoxicity Not available. Mobility Germany water class Not available. Not available. Not available. Persistence/degradability Bioaccumulative potential VCI WGK: No products were found. Section 12. Ecological information Mobility Not available. : Species Period Ecotoxicity data Ingredient name LogPow BCF Persistence/degradability Bioaccumulative potential Other ecological information Ingredient name Ingredient name BOD5 COD Ingredient name Aquatic half-life Photolysis Continued on Next Page AminoLink Reductant Page: 6/8 Other adverse effects : Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Not available. Waste Stream Section 13. Disposal considerations Denmark – Carcinogenic waste Not available. Not available. Sweden - thermoset plastic waste Not available. European waste catalogue (EWC) The classification of the product may meet the criteria for a hazardous waste Hazardous waste Austria - Waste catalogue Not available. Denmark - Waste card number Not available. Denmark - Waste group Not available. Sweden - Waste group Not available. Norway - Waste number Not available. Switzerland - Waste code Not available. The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Methods of disposal Norway - Hazardous waste The classification of the product may meet the criteria for a hazardous waste Contact the supplier for all information regarding the proper transportation method for this material. Section 14. Transport information Section 15. Regulatory information R11- Highly flammable. R15- Contact with water liberates extremely flammable gases. R26/27/28- Very toxic by inhalation, in contact with skin and if swallowed. R34- Causes burns. R32- Contact with acids liberates very toxic gas. R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S4- Keep away from living quarters. S7/8- Keep container tightly closed and dry. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28- After contact with skin, wash immediately with plenty of [***]. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S60- This material and its container must be disposed of as hazardous waste. S61- Avoid release to the environment. Refer to special instructions/Safety data sheets. Highly flammable, Very toxic, Dangerous for the environment. Label Requirements (Europe) 1 Continued on Next Page AminoLink Reductant Page: 7/8 U.S. Federal Regulations No products were found. Flammable solid Water reactive material Highly toxic material Corrosive material Target organ effects HCS Classification TSCA 8(b) inventory: borate(1-), (cyano-c)trihydro-, sodium, (t-4)- Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. Clean air act (CAA) 112 accidental release prevention: No products were found. Clean air act (CAA) 112 regulated flammable substances: No products were found. Clean air act (CAA) 112 regulated toxic substances: No products were found. State Regulations CEPA NDSL: borate(1-), (cyano-c)trihydro-, sodium, (t-4)- Australia (NICNAS): borate(1-), (cyano-c)trihydro-, sodium, (t-4)- China: borate(1-), (cyano-c)trihydro-, sodium, (t-4)- Korea (TCCL): borate(1-), (cyano-c)trihydro-, sodium, (t-4)- Philippines (RA6969): borate(1-), (cyano-c)trihydro-, sodium, (t-4)- WHMIS (Canada) Class B-6: Reactive and very flammable material. Class D-1B: Material causing immediate and serious toxic effects (TOXIC). Class E: Corrosive solid. R11- Highly flammable. R15- Contact with water liberates extremely flammable gases. R26/27/28- Very toxic by inhalation, in contact with skin and if swallowed. R34- Causes burns. R32- Contact with acids liberates very toxic gas. R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. DSCL (EEC) International Regulations Not available. EINECS International Lists SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: No products were found. SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found. No products were found. State regulations SARA 313 Form R - Reporting requirements AminoLink Reductant 25895-60-7 98 - 100 : Product name CAS number Concentration SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. Not available. Section 16. Other information References Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.) History of Document Changes Any information changes since last document version are marked with a triangle symbol. Full text of R phrases referred to in sections 2 and 3 - Europe R11- Highly flammable. R15- Contact with water liberates extremely flammable gases. R26/27/28- Very toxic by inhalation, in contact with skin and if swallowed. R34- Causes burns. R32- Contact with acids liberates very toxic gas. R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 4 3 2 C * Health Fire hazard Reactivity Personal protection W 2 3 4 Health Special Instability Flammability Continued on Next Page AminoLink Reductant Page: 8/8 Version 0.05 Date of previous issue 10/20/2006 Validated by MSDS_Specialist on 8/30/2007. Verified by MSDS_Specialist. Printed 8/30/2007. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications. Full text of classifications referred to in sections 2 and 3 - Europe F - Highly flammable T+ - Very toxic C - Corrosive N - Dangerous for the environment.