csy_d75_poly_msds.pdf

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MATERIAL SAFETY DATA SHEET 
 
 
 
 
 
 
 
 
 
 
Phone: (641)-528-3000 
P.O. Box 247 
 
 
 
 
 
 
 
                  Fax: (641)-528-5403 
106 South Main Street  
 
 
 
 
 
         Toll Free: (888)-489-2462 
Malcom, IA 50157 
 
 
 
 
 
 
                     www.itwcinc.com 
 
 
1. PRODUCT IDENTIFICATION 
 
PRODUCT NAME: 
 
CSYD75POLY 
 
 
2. HZARDS IDENTIFICATION  
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:  None known. 
 
ROUTES OF ENTRY:  Skin and eye contact.  Ingestion.  Inhalation.  
 
 
 
 
 
ACUTE HEALTH HAZARDS: 
 
INGESTION-   May cause gastric disturbances. 
 
CARCINOGENICITY: 
 
NTP (National Toxicology Program)? 
 
 
 No. 
 
IARC (International Agency for Research on Cancer?   
 No.  
 
OSHA REGULATED?  
 
 
 
 
 No. 
 
 
3. COMPOSITION / INFORMATION ON INGREDIENTS 
 
 
INGREDIENT NAME 
CAS 
NUMBER 
% OSHA PEL 
ACGIH TLV
 
 
Tetrahydroxypropylethylendiamine 
102-60-3 
<50 Not 
established 
Not established 
Propanoic Acid, 2-methyl-,2,2-dimethyl-1-(Methylethyl)-1,3-
propanediyl ester 
 
6846-50-0 
<60 Not 
established 
Not established 
 
4. FIRST AID MEASURES 
INHALATION- Remove to fresh air immediately. If not breathing, give artificial respiration. See medical 
attention immediately. 
 
 
SKIN- Remove all contaminated clothing and shoes. Wash skin thoroughly with soap and water for at least 
15 minutes. Wash clothing before wearing again. Clean shoes before wearing again. If irritation develops or persists, 
consult a physician.  
 
EYE- Flush with large amounts of water for at least 15 minutes, using fingers to hold eyelids open to insure 
that the eyes are being irrigated. Seek medical attention.  
 
INGESTION- Drink plenty of water for dilution. Never give anything by mouth to an unconscious person. 
Induce vomiting. Get medical attention immediately.  
 
 
5. FIRE FIGHTING MEASURES 
FLASH POINT (Method Used):    
 
128°c  / 262°F 
 
 
FLAMMABLE LIMITS: 
 
LEL (Lower Explosion Limit)= 
Not established. 
 
UEL (Upper Explosion Limit)= 
Not established. 
 
EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical, water spray or water fog.   
 
SPECIAL FIRE FIGHTING PROCEDURES: Evacuate area. Fight fire from a safe distance. Fire-fighters should wear 
full emergency equipment with self-contained breathing apparatus and full protective clothing.  
Revision Date: 4-15-09 
 
MSDS  
Product:  CSYD75POLY 
      itwc , inc  urethane solutions 
Page 1 of 4 
Revision Date: 4-15-09 
 
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Product:  CSYD75POLY 
      itwc , inc  urethane solutions 
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6. ACCDCIDENTAL RELEASE MEASURES 
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:  
o 
Stop the spill or leak.  
o Contain or dike the spilled product.  
o 
Evacuate spill area and keep nonessential or unprotected personnel away.  
o 
Equip clean-up personnel with necessary personal protective equipment (see Section VIII-Control 
Measures).  
o 
Prevent spilled material from entering soil, sewers, surface water, ground water, streams, or any other 
bodies of water.    
o Retain any contaminated water for removal and treatment.  
o 
Absorb small spills with inert material (e.g. dry sand, earth, chemical absorbent, etc.). 
o 
Scoop up absorbed material and absorbent and place in an approved chemical waste container.  
o 
Large spills may be taken up with pump or vacuum & then finished off with dry absorbent.  
o Report spill per regulatory requirements. 
 
7. HANDLING AND STORAGE 
PRECAUTIONS TO BE TAKEN IN HANDLING & STORING:  Store in cool dry area.  Keep container closed to 
maintain product quality.  Avoid extreme heat. Store protected against freezing. 
 
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION 
VENTILATION:  Good general ventilation.  Ventilation should be matched to conditions.  Use local exhaust to control 
vapors/mists.   
 
RESPIRATORY PROTECTION:  Approved organic vapor mist respirator as necessary.  Observe OSHA regulations 
for respiratory use (29CFR 1910.134). 
 
SKIN PROTECTION:  Gloves, coveralls, apron, boot as necessary to prevent skin contact.  
 
EYE PROTECTION:  Chemical goggles; also wear a face shield if a splashing hazard exists. 
 
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Safety showers and eyewash stations should be readily 
available and in working condition. 
 
WORK/HYGIENIC PRACTICES: Wash hands, forearms, and face thoroughly after handling product and before 
eating, smoking, using lavatory, and at the end of the day. Educate and train employees in safe use of product.  
Follow all label instructions. 
9. PHYSICAL AND CHEMICAL PROPERTIES 
APPEARANCE (physical form, color, texture, etc.) 
Clear Liquid 
ODOR: 
Mild 
VAPOR PRESSURE (mm Hg): 
Not establihsed 
SPECIFIC GRAVITY (H2O = 1): 
Not Established. 
EVAPORATION RATE (Butyl Acetate = 1): 
Not Established. 
 
10. STABILITY AND REACTIVITY 
STABILITY:  Stable.  
 
CONDITIONS TO AVOID (if unstable):  Moisture 
 
INCOMPATIBILITY (MATERIALS TO AVOID):   
 
HAZARDOUS DECOMPOSITION OR BYPRODUCTS:  CO and CO2.  
  
HAZARDOUS POLYMERIZATION:   Will not occur. 
CONDITIONS TO AVOID (if polymerization may occur): Not Applicable. 
 
11. TOXICOLOGICAL INFORMATION 
Information on individual components listed in section 3:  
Tetrahydroxypopylethylediamine 
Oral: 
 
LD50/rat/male/female:  3280 mg/kg 
Skin Irritation 
Revision Date: 4-15-09 
 
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Product:  CSYD75POLY 
      itwc , inc  urethane solutions 
Page 3 of 4 
 
Rabbit: non irritant 
Eye Irritation 
 
Rabbit: non irritant 
Sensitization 
 
Guinea pig maximization test/ guinea pig: non-sensitizing 
Genetic toxicity 
 
The substance was not mutagenic in bacteria. 
 
Propanoic Acid, 2-methyl-,2,2-dimethyl-1-(Methylethyl)-1,3-propanediyl ester 
Oral LD-50: (rat)  
 
>3.2 g/kg(highest dose tested) 
 
Oral LD-50 (mouse) 
 
>6.4 g/kg(highest dose tested) 
 
Inhalation LC-50 (rat) 
 
6h: >5.3 mg/l (highest dose tested) 
 
Dermal LD-50 (guinea pig)  
>18.9 g/kg (highest dose tested) 
 
Skin Irritation (guinea pig)  
slight 
 
Eye irritation (rabbit) 
 
slight 
 
Skin sensitization (guinea pig) 
none 
 
12. ECOLOGICAL INFORMATION 
 
Information on individual components listed in section 3: 
Tetrahydroxypopylethylediamine 
Mobility: Test Method:  
 
OECD 301 A (new version) (aerobic), activated sludge 
 
Method of analysis: 
 DOC reduction 
 
Degree of elimination: 
40-50% (42 d) 
Toxicity to microorganisms:  
 
OECD Guideline 209 aerobic Active sludge, domestic/EC20(30min): 
1,000 mg/l 
 
Propanoic Acid, 2-methyl-,2,2-dimethyl-1-(Methylethyl)-1,3-propanediyl ester 
Oxygen Demand Data: 
 
 
BOD-5 and BOD-20 were not determined because the aqueous solubility of the test article was  
 
 
below that which is required for these tests.   
 
 
ThBOD: 2.40 g/g 
 
Acute Aquatic Effects Data: 
 
 
 96 h LC-50 (fathead minnow): >1.55 mg/l NOEC:  1.55 mg/l (highest concentration tested), (limit of 
 solubility in fresh water)  
 
 96 h LC-50 (sideswimmer):  >1.55 mg/l NOEC:  1.55 mg/l (highest concentration tested), (limit of 
 solubility in fresh water) 
 
 96 h LC-50 (ramshorn snail): >1.55 mg/l NOEC:  1.55 mg/l (highest concentration tested), (limit of 
 solubility in fresh water) 
 
 96 h LC-50 (aquatic earthworm):  >1.55 mg/l NOEC:  1.55 mg/l (highest concentration tested), (limit 
 of solubility in fresh water) 
 
 96 h LC-50 (pill bug):  >1.55 mg/l NOEC:  1.55 mg/l (highest concentration tested), (limit of 
 solubility in fresh water) 
 
 96 h LC-50 (flatworm):  >1.55 mg/l NOEC:  1.55 mg/l (highest concentration tested), (limit of 
 solubility in fresh water) 
 
48 h EC-50 (daphnid):  >1.46 mg/l NOEC:  1.46 mg/l (highest concentration tested), (limit of 
solubility in fresh water) 
 
 
 
 
13. DISPOSAL CONSIDERATIONS 
WASTE DISPOSAL METHOD: Dispose of in accordance with applicable federal, state, and local regulations.  
 
EMPTY CONTAINER Disposal: All containers should be disposed of in an environmentally safe manner and in 
accordance with applicable federal, state, and local regulations.  
 
14. TRANSPORTATION INFORMATION 
Land transport (DOT) 
Proper shipping name: 
 
Non- regulated 
 
 
 
 
 
Hazard Class or Division 
 
 
 
UN/NA Number 
 
 
 
Package Group 
 
 
 
Hazard Label(s) 
 
 
 
 
 
Sea transport (IMDG) 
Proper shipping name: 
 
Non- regulated 
 
 
 
 
Hazard Class or Division 
 
 
 
UN/NA Number 
 
 
Revision Date: 4-15-09 
 
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Product:  CSYD75POLY 
      itwc , inc  urethane solutions 
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Package Group 
 
 
 
Hazard Label(s) 
 
 
Air transport (ICAO/ IATA) 
Proper shipping name: 
 
Non- regulated 
 
 
 
 
Hazard Class or Division 
 
 
 
UN/NA Number 
 
 
 
Package Group 
 
 
 
Hazard Label(s) 
 
15. REGULATORY INFORMATION 
OSHA HAZARD COMMUNICATION STATUS:   This product is not considered hazardous as defined under the 
criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200. 
 
RCRA STATUS:   
To the best of our knowledge, if discarded in its purchased form, this product would not be considered a hazardous 
waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the user of products to 
determine, at the time of disposal, whether a product meets any of the criteria for a hazardous waste. This is because 
product uses, transformations, mixtures, processes, etc., may render the resulting material hazardous, under the 
criteria of ignitability, corrosivity, reactivity, and toxicity (40 CFR 261.20-24).  
 
 
US INVENTORY (TSCA): The ingredients of this product are listed on the TSCA inventory or are not required to be 
listed on the TSCA inventory.  
  
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA), TITLE III: 
Sections 301-303 – Emergency Planning - Extremely Hazardous Substances: 
None.  
Section 304 – Emergency Release Notification – Reportable Substances: 
 
 
None. 
 
 
Section 311/312 – Community Right-to-Know Reporting Requirements - Emergency Hazard Categories: 
None. 
Section 313 – Toxic Chemical Notification & Release Inventory Reporting – Listed Substances: 
 
None. 
This information must be included in all MSDSs that are copied and distributed for this material. 
 
16. OTHER INFORMATION 
HMIS RATINGS: 
 
HEALTH 
1 
FLAMMABLILITY 
1 
REACTIVITY 
1 
 (0=Minimal; 1=Slight; 2=Moderate; 3=Serious; 4=Severe; *=Chronic) 
 
 
PREPARED BY: 
ITWC Compliance Dept. (LT) 
APPROVED BY:   
ITWC Director of Technical Service. (SF) 
 
This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of ITWC, Inc.  
The data on this sheet relates only to the specific material designated herein.  ITWC, Inc. assumes no legal responsibility for use or 
reliance upon these data. 
Visit our website at www.ITWCINC.com or call (888)-489-2462