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1 MATERIAL SAFETY DATA SHEET FOR LEAD- ACID BATTERIES, WET, FILLED WITH ACID – UN 2794 CHEMTREC CODE: C677 SECTION I: GENERAL INFORMATION For Chemical Emergency Manufacturers Name: Crown Battery Mfg. Company Spill Leak Fire Exposure or Accident Street Address: 1445 Majestic Drive Call CHEMTREC Day or Night City, State, Zip: Fremont, Ohio 43420 DOMESTIC NORTH AMERICA 800-424-9300 Phone Number; 419 334-7181 INTERNATIONAL, CALL 703-527-3887 Revision Date: 03/01/08 (collect calls accepted) SECTION II: MATERIAL IDENTIFICATION AND INFORMATION COMPONENTS PERCENT OSHA ACGIH OTHER LIMITS CAS NUMBER Hazardous Components PEL TLV 1% or greater Carcinogens 0.01 % or greater METALLIC METAL ALLOY 25.5% 0.05mg/m3 .05 mg/m3 NONE 7439-92-1 LEAD SULFATES 18.2% 0.05mg/m3 .05 mg/m3 NONE 7439-92-1 LEAD OXIDES 18.0% 0.05mg/m3 .05 mg/m3 NONE 7439-92-1 POLYPROPYLENE CASE MTL 6.4% SEPARATORS 3.5% SULFURIC ACID (H2SO4) 5.2% 1.0 mg/m3 1.0 mg/m3 NONE 7664-93-9 WATER 19.2% SECTION III: PHYSICAL / CHEMICAL CHARACTERISTICS Boiling Point Approximately 203F Vapor Density: Greater than 1 Vapor Pressure 14 @ 37% @ 80 F Melting Point: -35 F to +10.6 F Solubility in Water 100% Water Reactive Yes, Produces Heat Specific Gravity 1.245 - 1.295 Battery Electrolyte Appearance & Odor: Clear Liquid with Sharp Pungent Odor SECTION IV: FIRE AND EXPLOSION HAZARD DATA: Flash Point: Not Combustible NFPA WARNING: 1 Auto Ignition Temperature N/A Flammability Limits in Air % by Volume: N/A Extinguishing Media: Dry Chemical Carbon Dioxide, Water Fog, Water Special Fire Fighting Procedures: Sulfuric Acid Fumes, Sulfur Dioxide Gas or Carbon Monoxide may be released when acid decomposes. Wear NIOSH approved self contained breathing apparatus. Unusual Hazards: Water applied to sulfuric acid generates heat and causes acid to spatter. Wear full-cover acid resistant clothing. Sulfuric acid reacts violently with metals, nitrates, chlorates, carbides, fulminates, picrates and other organic materials. Reacts with most metals to yield explosive/flammable hydrogen gas. This reaction is intensified when sulfuric acid is diluted with water to form battery electrolyte. 2 MATERIAL SAFETY DATA SHEET – PAGE TWO FOR LEAD- ACID BATTERIES, WET, FILLED WITH ACID – UN 2794 SECTION V: REACTIVITY DATA Stability: STABLE NFPA WARNING: 0 CONDITIONS TO AVOID: Charging and over-charging without proper ventilation. Incompatibility: AVOID COMBUSTIBLES, ORGANIC MATERIALS, AND STRONG REDUCING AGENTS. Hazardous Decomposition Products: SULFUR TRIOXIDE, CARBON MONOXIDE, SULFURIC ACID FUMES AND SULFUR DIOXIDE. Hydrogen, Arsine, Stibene with over charging. Hazardous Polymerization: Should not occur SECTION VI – HEALTH HAZARD DATA PRIMARY ROUTES OF ENTRY: Inhalation - Yes NPFA WARNING: 3 Skin Yes Ingestion Yes HEALTH HAZARDS - Acute: Eyes, Skin, Respiratory System & Digestive System Chronic: Eyes, Skin, Respiratory System & Digestive System Exposure to Lead Compounds can occur only when product is heated, oxidized or other-wised processed or damaged to create dust vapor or fume. Lead is a systemic poison. Carcinogenicity - NTP: No Carcinogenicity - IARC: Yes (Group 2 B *94-4* Carcinogenicity -OSHA: No Signs and Symptoms of Exposure: Irritation of Exposed Area, Burns, and Respiratory Problems No possibility of over exposure of lead will occur unless battery is destroyed. MEDICAL CONDITIONS GENERALLY: Aggravated by Exposure: Exposure to acid mist may cause lung damage & aggravate pulmonary conditions. EMERGENCY FIRST AID PROCEDURES Seek medical assistance for further treatment, observation and support if necessary. Eye Contact: Wash with copious quantities of cool water for at least 15 minutes. Skin Contact: Flush area with large amounts of cool water for at least 15 minutes. Inhalation: Remove to fresh air, if breathing is difficult – give oxygen. Ingestion: Give milk to drink. DO NOT INDUCE VOMITING, CALL PHYSICIAN. 3 MATERIAL SAFETY DATA SHEET – PAGE THREE FOR LEAD- ACID BATTERIES, WET, FILLED WITH ACID – UN 2794 SECTION VII:SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES STEPS TO TAKE IF MATERIALS RELEASED: Wash area with water, neutralize with lime, caustic soda or sodium bicarbonate. If released on soils: work neutralizing materials into top three inches of soils. Neutralizing Agent: Lime, Caustic Soda, or Sodium Bicarbonate. Waste Disposal Method: Neutralize and dispose of residue in accordance with federal, state and local regulation for chemical and toxic metals disposal. Lead and Sulfuric Acid is packed into a container to form the lead-acid battery. Since all containers are subject to leakage and breakage, employees who work in operations where they handle batteries in containers are potentially exposed to hazardous chemicals, and, therefore, need access to information as well as training. SECTION VI II– SPECIAL PROTECTION INFORMATION/CONTROL MEASURES Respiratory Protection: Sulfuric Acid Mist-Mask with filter approved for acid mist. Ventilation: Local exhaust: Room air change four times per hour. Protective Gloves: Rubber Eye Protection: Goggles, Face Shield Other Protective Equipment: Rubber Apron, Acid Resistant Clothing Recommended Work Hygienic Practices: Wash thoroughly after handling SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES COMPONENTS METALLIC METAL ALLOY 25.5% LEAD SULFATES 18.2% LEAD OXIDES 18.0% POLYPROPYLENE CASE MTL 6.4% SEPARATORS 3.5% SULFURIC ACID (H2SO4) 5.2% WATER 19.2% 4 MATERIAL SAFETY DATA SHEET – PAGE FOUR FOR LEAD- ACID BATTERIES, WET, FILLED WITH ACID – UN 2794 SECTION X – STABILITY AND REACTIVITY Stability: STABLE CONDITIONS TO AVOID: Charging and over-charging without proper ventilation. Incompatibility: AVOID COMBUSTIBLES, ORGANIC MATERIALS, AND STRONG REDUCING AGENTS. SECTION XI: TOXICOLOGICAL INFORMATION HEALTH HAZARDS - Acute: Eyes, Skin, Respiratory System & Digestive System Chronic: Eyes, Skin, Respiratory System & Digestive System Signs and Symptoms of Exposure: Irritation of Exposed Area, Burns, and Respiratory Problems No possibility of over exposure of lead will occur unless battery is destroyed. MEDICAL CONDITIONS GENERALLY: Aggravated by Exposure: Exposure to mist may cause lung damage & aggravate pulmonary conditions. SECTION XII – ECOLOGICAL INFORMATION All care should be taken to protect the environment from any adverse impact by lead-acid batteries or from the batteries ingredients. SECTION XIII – DISPOSAL CONSIDERATION Lead-Acid Batteries are restricted land disposal objects. All spent lead-acid batteries should be properly Recycled to a permitted Secondary Lead Smelter. All battery parts should be properly recycled. No whole spent lead-acid battery should be land-filled or placed in house hold garbage. 5 MATERIAL SAFETY DATA SHEET – PAGE FIVE FOR LEAD- ACID BATTERIES, WET, FILLED WITH ACID – UN 2794 SECTION XIIII – TRANSPORT INFORMATION Electric storage batteries containing electrolyte acid or alkaline corrosive battery fluid must be completely protected so that short circuits will be prevented. DOT SHIPPING NAME: LEAD-ACID BATTERIES, WET, FILLED WITH ACID DOT CLASS: 8 DOT ID NUMBER: UN2794 DOT PACKING GROUP: III DOT LABEL REQUIREMENTS: CORROSIVE SECTION XV – REGULATION INFORMATION REGULATORY INFORMATION: Those ingredients in lead-acid batteries listed above are not subject to the reporting requirements of 313 of Title III of the Superfund Amendments and Re-authorization Act, if the lead acid batteries are in storage and have no potential to leak, spill or break during normal storage prior to use. DOT REGULATIONS: 49 CFR 173.159 EPA REGULATIONS: 40 CFR 266.80 OSHA REGULATIONS: 29 CFR 1910.1200
