Denatured Alcohol 2I

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<p>MATERIAL SAFETY DATA SHEET
DENATURED ALCOHOL 2I (ANHYDROUS)
3. HAZARDS IDENTIFICATION
Toxic! Harmful if swallowed. Causes severe eye irritation. Causes skin irritation. At elevated 
temperatures may cause irritation of the eyes and respiratory tract. High vapour concentrations may 
cause drowsiness. See "Other Health Effects" Section. Flammable liquid and vapour. May cause flash 
fire or explosion. Can decompose at high temperatures forming toxic gases. Contents may develop 
pressure on prolonged exposure to heat.
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS
Product is irritating to the nose, throat and respiratory tract. See "Other Health Effects" Section.
Inhalation:
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON  (416) 226-6117                     Montreal, QC (514) 861-1211                     Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754                  Calgary, AB  (403) 263-8660                       Vancouver, BC (604) 685-5036
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Brenntag Canada Inc.
43 Jutland Rd.
Toronto, ON
M8Z 2G6
(416) 259-8231
Website:  http:\\www.brenntag.ca
WHMIS#:
00066342
Index: 
2007 February 05
PRODUCT IDENTIFICATION
Denatured Alcohol 2I (Anhydrous).
Product Name:  
2007 February 05
Date of Revision:
Effective Date:
HCI5482/07A
Denatured Alcohol.
Chemical Name:
D.A.G. No. 2 I ( Anhydrous ); Denatured Ethyl Alcohol Grade No. 2 I ( Anhydrous ).
Synonyms:
Mixture of oxygenated aliphatic hydrocarbons.
Chemical Family:
Not applicable.
Molecular Formula:
Industrial solvent, cleaner, degreaser. Chemical intermediate.
Product Use:
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
B-2:  Flammable Liquid
D-2B:  Toxic (skin and eye irritant)
Ingredient
CAS#
ACGIH TLV
% Concentration
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
Ethanol 
64-17-5
1 000 ppm 
90 - 99
*A4
Isopropanol 
67-63-0
200 ppm 
5 - 10
*A4
Ethyl acetate 
141-78-6
400 ppm 
1 - 5
A4 = Not classifiable as a human carcinogen. (ACGIH-A4).
Denatured Alcohol 2I (Anhydrous)
Brenntag Canada Inc.
Date of Revision:
2007 February 05
WHMIS Number :
00066342
Page 2 of 7
4. FIRST AID MEASURES
FIRST AID PROCEDURES
Move victim to fresh air.  Give artificial respiration ONLY if breathing has stopped.  Give 
cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse.  Oxygen administration may 
be beneficial in this situation but should only be administered by personnel trained in its use.  Obtain 
medical attention IMMEDIATELY.
Inhalation:
Flush skin with running water for a minimum of 20 minutes.  Start flushing while removing contaminated 
clothing.  If irritation persists, repeat flushing.  If irritation, redness, or a burning sensation develops and 
persists, obtain medical attention.
Skin Contact:
Immediately flush eyes with running water for a minimum of 20 minutes.  Hold eyelids open during 
flushing.  If irritation persists, repeat flushing.  Obtain medical attention.
Eye Contact:
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not 
convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material.  IMMEDIATELY contact 
local Poison Control Centre.  Vomiting should only be induced under the direction of a physician or a 
poison control centre.  If spontaneous vomiting occurs, have victim lean forward with head down to 
avoid breathing in of vomitus, rinse mouth and administer more water.  IMMEDIATELY transport victim 
to an emergency facility.
Ingestion:
This product contains materials that may cause severe pneumonitis if aspirated.  If ingestion has 
occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to 
prevent aspiration.  Observe patient for respiratory difficulty from aspiration pneumonitis.  Give artificial 
resuscitation and appropriate chemotherapy if respiration is depressed.
Medical conditions that may be aggravated by exposure to this product include neurological and 
cardiovascular disorders, diseases of the skin, eyes or respiratory tract, preexisting liver and kidney 
disorders.
Note to Physicians:
Prolonged and repeated contact may lead to dermatitis. May cause defatting, drying and cracking of the 
skin. Skin contact can cause irritation, especially under the finger nails (and other confined spaces such 
as under rings or watch bands).
Skin Contact:
May be absorbed through intact skin.
Skin Absorption:
Vapours from this product are irritating to the eyes. This product causes irritation, redness and pain. 
May cause conjunctivitis.
Eye Contact:
This product causes irritation, a burning sensation of the mouth and throat and abdominal pain.
Ingestion:
Effects (irritancy) on the skin and eyes may be delayed, and damage may occur without the sensation 
or onset of pain.  Strict adherence to first aid measures following any exposure is essential.
Prolonged abuse of Ethyl Alcohol may cause permanent liver and cardiovascular damage. May cause 
central nervous system (CNS) depression, kidney damage, systemic poisoning and death. CNS 
depression is characterized by headache, dizziness, drowsiness, nausea, vomiting and incoordination.  
Severe overexposures may lead to coma and possible death due to respiratory failure. Liver damage is 
characterized by the loss of appetite, jaundice (yellowish skin colour), and occasional pain in the upper 
left-hand side of the abdomen. Signs and symptoms of kidney damage generally progress from oliguria, 
to blood in the urine, to total renal failure.
Other Health Effects:
5. FIRE-FIGHTING MEASURES
Flashpoint (°C)
AutoIgnition 
Temperature (°C)
LEL
UEL
Flammability Limits in Air (%):  
13.  (3)
399.  (3)
2.2.  (3)
19.0.  (3)
B-2:  Flammable Liquid
Flammability Class (WHMIS):
Thermal decomposition products are toxic and may include formaldehyde, oxides of carbon and 
irritating gases.
Hazardous Combustion 
Products:
Vapours from this product are heavier than air, and may "travel" to a source of ignition (eg. pilot lights, 
heaters, electric motors) some distance away, and then "flash back" to the point of product discharge 
causing an explosion and fire. Closed containers exposed to heat may explode. Spilled material may 
cause floors and contact surfaces to become slippery.
Unusual Fire or Explosion 
Hazards:
Not expected to be sensitive to mechanical impact.
Sensitivity to Mechanical Impact:
Denatured Alcohol 2I (Anhydrous)
Brenntag Canada Inc.
Date of Revision:
2007 February 05
WHMIS Number :
00066342
Page 3 of 7
Not available.
Rate of Burning:
Not available.
Explosive Power:
Expected to be sensitive to static discharge when vapours are present between the lower and upper 
explosive limits.
Sensitivity to Static Discharge:
EXTINGUISHING MEDIA
Use carbon dioxide or dry chemical media for small fires.  If only water is available, use it in the form of 
a fog. This material may produce a floating fire hazard in extreme fire conditions.
Fire Extinguishing Media:
FIRE FIGHTING 
INSTRUCTIONS
Use water spray to cool fire-exposed containers or structures.  Use water spray to disperse vapours;  re-
ignition is possible. Isolate materials that are not involved in the fire and protect personnel.  Cool 
containers with flooding quantities of water until well after the fire is out.
Instructions to the Fire Fighters:
Use self-contained breathing apparatus and protective clothing.
Fire Fighting Protective 
Equipment:
6. ACCIDENTAL RELEASE MEASURES
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons, 
property and the environment.  There may be specific reporting requirements associated with spills, leaks or releases, which change from 
region to region.
In all cases of leak or spill contact vendor at Emergency Number shown on the front page of this MSDS. 
Wear protective clothing. Do not use combustible materials such as sawdust as an absorbent. Eliminate 
all sources of ignition.  Collect product for recovery or disposal.  For release to land, or storm water 
runoff, contain discharge by constructing dykes or applying inert absorbent;  for release to water, utilize 
damming and/or water diversion to minimize the spread of contamination.  Ventilate enclosed spaces.  
Notify applicable government authority if release is reportable or could adversely affect the environment.
Containment and Clean-Up 
Procedures:
7. HANDLING AND STORAGE
HANDLING
Ground and bond equipment and containers to prevent a static charge buildup.  Use spark-resistant 
tools and avoid "splash-filling" of containers. Use normal "good" industrial hygiene and housekeeping 
practices. Containers exposed to heat may be under internal pressure.  These should be cooled and 
carefully vented before opening.  A face shield and apron should be worn. Vent container frequently, 
and more often in warm weather, to relieve pressure. Enforce NO SMOKING rules in area of use.
Handling Practices:
See Section 8, "Engineering Controls".
Ventilation Requirements:
Use only with adequate ventilation and avoid breathing vapours and aerosols. Avoid contact with eyes, 
skin or clothing.  Wash thoroughly with soap and water after handling.  Wash contaminated clothing 
thoroughly before re-use. Do not use cutting or welding torches on empty drums that contained this 
material/product. Absorption via contact with skin, eyes and mucous membranes can contribute to the 
overall exposure.  Consider measures to prevent absorption by these routes. Store wiping rags and 
similar material in metal cans with tight fitting lids.
Other Precautions:
STORAGE
See below.
Storage Temperature (°C):
Ventilation should be explosion proof.
Ventilation Requirements:
Store in a cool, well-ventilated area.  Keep away from heat, sparks and flames.  Keep containers 
closed.  Do not expose sealed containers to temperatures above 40° C. Avoid moisture contamination. 
Protect from direct sunlight. Protect against physical damage.
Storage Requirements:
Confirm suitability of any material before using.
Special Materials to be Used for 
Packaging or Containers:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this 
product.  Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific 
protective devices at your workplace.
ENGINEERING CONTROLS
Denatured Alcohol 2I (Anhydrous)
Brenntag Canada Inc.
Date of Revision:
2007 February 05
WHMIS Number :
00066342
Page 4 of 7
Local exhaust ventilation required.  Ventilation should be explosion proof. Make up air should be 
supplied to balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas 
such as sumps or pits where dense vapours may collect.
For personnel entry into confined spaces (i.e. bulk storage tanks) a proper procedure must be followed.  
It must include consideration of, among other things, ventilation, testing of tank atmosphere, provision 
and maintenance of SCBA, and emergency rescue. Use the "buddy" system.  The second person 
should be in view and trained and equipped to execute a rescue.  (4)
Engineering Controls:
PERSONAL PROTECTIVE 
EQUIPMENT (PPE)
Safety glasses with side shields are recommended to prevent eye contact. Use chemical safety goggles 
when there is potential for eye contact. Contact lenses should not be worn when working with this 
material.
Eye Protection:
Gloves and protective clothing made from butyl rubber, nitrile rubber or natural rubber should be 
impervious under conditions of use.   Do not use gloves or protective clothing made from polyvinyl 
alcohol (PVA) or PVC. Discard contaminated gloves. Prior to use, user should confirm impermeability.
Skin Protection:
No specific guidelines available. Do not use compressed oxygen in hydrocarbon atmospheres. A 
NIOSH/MSHA-approved air-purifying respirator equipped with organic vapour cartridges for 
concentrations up to 1 000 ppm organic vapours. An air-supplied respirator if concentrations are higher 
or unknown.
If while wearing a respiratory protection, you can smell, taste or otherwise detect anything unusual, or in 
the case of a full facepiece respirator you experience eye irritation, leave the area immediately.  Check 
to make sure the respirator to face seal is still good.  If it is, replace the filter, cartridge or canister.  If 
the seal is no longer good, you may need a new respirator.  (4)
Respiratory Protection:
Wear an impermeable apron and boots. Locate safety shower and eyewash station close to chemical 
handling area. Take all precautions to avoid personal contact. Clothing and footwear that is fire 
retardant and dissipates static electrical charges should be worn when handling flammable materials.  
Natural fibers (cotton, wool, leather and linen) should be selected in favour of synthetic materials (rayon, 
nylon and polyester).
Other Personal Protective 
Equipment:
EXPOSURE GUIDELINES
SUBSTANCE
ACGIH TLV
(STEL)
OSHA PEL
(TWA)                   (STEL)
NIOSH REL
(TWA)                      (STEL)    
Ethanol 
— 
1 000 ppm 
--- 
1 000 ppm 
--- 
Isopropanol 
400 ppm 
400 ppm 
--- 
400 ppm 
500 ppm 
Ethyl acetate 
— 
400 ppm 
--- 
400 ppm 
--- 
Liquid.
Clear, colourless liquid.
Mild alcohol odour.
Not available.
75 - 79.
Not available.
Not available.
Not available.
0.7915.
791.5 kg/m3.
Not available.
1.8.
Soluble in water.
100.
Not available.
Not available.
100 %.
Physical State:
Appearance:
Odour:
Odour Threshold (ppm):
Boiling Range (°C):
Melting/Freezing Point (°C):
Vapour Pressure (mm Hg at 20° C):
Vapour Density (Air = 1.0):
Relative Density (g/cc):
Bulk Density:
Viscosity:
Evaporation Rate (Butyl Acetate = 1.0):
Solubility:
% Volatile by Volume:
pH:
Coefficient of Water/Oil Distribution:
Volatile Organic Compounds (VOC):
9. PHYSICAL AND CHEMICAL PROPERTIES  (Not intended as Specifications)
10. STABILITY AND REACTIVITY
Denatured Alcohol 2I (Anhydrous)
Brenntag Canada Inc.
Date of Revision:
2007 February 05
WHMIS Number :
00066342
Page 5 of 7
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL DATA:
SUBSTANCE
LD50 (Oral, Rat)
LD50 (Dermal, Rabbit)
LC50 (Inhalation, Rat, 4h)
Ethanol 
7 060 mg/kg (3)
5 628 mg/kg (3)
20 000 ppm (3)
Isopropanol 
4 420 - 5 840 mg/kg (1,3)
6 291- 12 900 mg/kg (1,3)
12 000 ppm (3)
Ethyl acetate 
5 620 - 10 200 mg/kg (1)
> 18 000 mg/kg (4)
19 600 ppm (4)
The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP.
Carcinogenicity Data:
No adverse reproductive effects are anticipated.
Reproductive Data:
No adverse mutagenic effects are anticipated.
Mutagenicity Data:
No adverse teratogenic effects are anticipated.
Teratogenicity Data:
None known.
Respiratory / Skin Sensitization 
Data:
Alcohols may interact synergistically with chlorinated solvents (example - carbon tetrachloride, 
chloroform, bromotrichloromethane), dithiocarbamates (example - disulfiram), dimethylnitrosamine and 
thioacetamide.  (4)
Synergistic Materials:
Chronic Ethyl Alcohol overexposure has been shown to inhibit the function of the male sex accessory 
organs and to impair the testicular synthesis and secretion of testosterone. (3)  However, such effects 
have not been shown to occur from occupational exposures.
    Ethyl Alcohol has been shown to be teratogenic in humans and animals (the "Fetal Alcohol 
Syndrome").  However, this effect is seen only at doses which induce maternal toxicity.  It is our belief 
that this product does not pose a teratogenic risk to the worker under conditions of occupational 
exposure.
Isopropanol:  An indication of reduced mating performance in second generation male rats was noted at 
oral doses of 1,000 mg/Kg/day in a two-generation reproductive study.  Increased neonatal mortality 
was also seen at doses of 500 mg/Kg/day and greater in this study.  (3)
Other Studies Relevant to 
Material:
12. ECOLOGICAL INFORMATION
Not available. May be harmful to aquatic life.
Ecotoxicity:
Not available. Can be dangerous if allowed to enter drinking water intakes. Do not contaminate 
domestic or irrigation water supplies, lakes, streams, ponds, or rivers.
Environmental Fate:
13. DISPOSAL CONSIDERATIONS
None required.
Deactivating Chemicals:
CHEMICAL STABILITY
Stable.
Under Normal Conditions:
Flammable.
Under Fire Conditions:
Will not occur.
Hazardous Polymerization:
High temperatures, sparks, open flames and all other sources of ignition.
Conditions to Avoid:
Strong oxidizers. Lewis or mineral acids. Strong bases. Mixtures or reactions of alcohols with the 
following materials may cause explosions:  barium perchlorate, chlorine, hypochlorous acid, ethylene 
oxide, hexamethylene diisocyanate and other isocyanates, nitrogen tetroxide, permonosulfuric acid and 
tri-isobutyl aluminum.  (4)
Materials to Avoid:
Thermal decomposition products are toxic and may include formaldehyde, oxides of carbon and 
irritating gases.
Decomposition or Combustion 
Products:
Denatured Alcohol 2I (Anhydrous)
Brenntag Canada Inc.
Date of Revision:
2007 February 05
WHMIS Number :
00066342
Page 6 of 7
This information applies to the material as manufactured. Reevaluation of the product may be required 
by the user at the time of disposal since the product uses, transformations, mixtures and processes 
may influence waste classification. Dispose of waste material at an approved (hazardous) waste 
treatment/disposal facility in accordance with applicable local, provincial and federal regulations.  Do not 
dispose of waste with normal garbage, or to sewer systems.
Waste Disposal Methods:
See "Waste Disposal Methods".
Safe Handling of Residues:
Empty containers retain product residue and can be dangerous. Empty drums should be completely 
drained, properly bunged and promptly returned to a drum reconditioner. Do not expose such containers 
to heat, flame, sparks, static electricity, or other sources of ignition; they may explode and cause injury 
or death. Do not dispose of package until thoroughly washed out.
Disposal of Packaging:
14. TRANSPORTATION INFORMATION
CANADIAN TDG ACT SHIPPING DESCRIPTION:
ALCOHOLS, N.O.S. (Ethyl Alcohol), Class 3, UN1987, PG II.
Label(s):  Flammable Liquids.          Placard:  Flammable Liquids.
ERAP Index: -----.
Exemptions: None known.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
ALCOHOLS, N.O.S. (Ethyl Alcohol), Class 3, UN1987, PG II.
Label(s):  Flammable Liquid.          Placard:  Flammable Liquid.
CERCLA-RQ: Not available.
Exemptions: None known.
15. REGULATORY INFORMATION
CANADA
All constituents of this product are included on the DSL.
CEPA - NSNR:
Isopropanol.
CEPA - NPRI:
Controlled Products Regulations Classification (WHMIS):
B-2:  Flammable Liquid
D-2B:  Toxic (skin and eye irritant)
USA
All constituents of this product are included on the TSCA inventory.
Environmental Protection Act:
Flammable Liquid, Skin and Eye Irritant.
OSHA HCS (29CFR 1910.1200):
Text22:
NFPA:   Health,    Fire,    Reactivity   (Not available.)
Text22:
HMIS:  0 Health,   3 Fire,   0 Reactivity   (3)
INTERNATIONAL
Not available.
16.  OTHER INFORMATION
REFERENCES
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS 
database.
1.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons, 
New York, 1981.
2.
Supplier's Material Safety Data Sheet(s).
3.
CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
4.
Guide to Occupational Exposure Values, 2005, American Conference of Governmental Industrial Hygienists, Cincinnati, 2005.
5.
Regulatory Affairs Group, Brenntag Canada Inc.
6.
The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical 
Association, Ottawa, 1981.
7.
Denatured Alcohol 2I (Anhydrous)
Brenntag Canada Inc.
Date of Revision:
2007 February 05
WHMIS Number :
00066342
Page 7 of 7
____________________________________________________________________________________________________________
The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith 
by technically knowledgeable personnel.  It is not intended to be all-inclusive and the manner and conditions of use and handling may 
involve other and additional considerations.  No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for 
any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained 
herein.  This Material Safety Data Sheet is valid for three years.
____________________________________________________________________________________________________________
To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia:  20333-102B Avenue, Langley, BC, V1M 3H1
         Phone:  (604) 513-9009         Facsimile:  (604) 513-9010
Alberta:   6628 - 45 th. Street, Leduc, AB, T9E 7C9
         Phone:  (780) 986-4544         Facsimile:  (780) 986-1070
Manitoba:  681 Plinquet Street, Winnipeg, MB, R2J 2X2
         Phone:  (204) 233-3416         Facsimile:  (204) 233-7005
Ontario:  43 Jutland Road, Toronto, ON, M8Z 2G6
         Phone:  (416) 259-8231         Facsimile:  (416) 259-6175
Quebec:  2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8
         Phone:  (514) 636-9230         Facsimile:  (514) 636-0877
Atlantic:  A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7
         Phone:  (902) 468-9690         Facsimile:  (902) 468-3085
____________________________________________________________________________________________________________
Prepared By:  Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.
</p>