MATERIAL SAFETY DATA SHEET
POLYETHYLENE (ALL GRADES), SOLID
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON (416) 226-6117 Montreal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Brenntag Canada Inc.
43 Jutland Rd.
Toronto, ON
M8Z 2G6
(416) 259-8231
Website: http:\\www.brenntag.ca
WHMIS#:
00062057
Index:
2009 March 23
PRODUCT IDENTIFICATION
Polyethylene (All Grades), Solid.
Product Name:
2009 March 23
Date of Revision:
Effective Date:
HCI0915/09A
1-Butene, polymer with ethene; 1-Hexene, Polymer with Ethylene; 1-Octene, polymer with ethene.
Chemical Name:
Polyethylene, Homopolymer; Ethylene/Hexene Copolymer;
Polyethylene High Density (HD); High Density Polyethylene (HDPE); Polyethylene HD Pellets;
Polyethylene High Density (HD) H5112, H5234, H5257, H5618, L4905, L5005, L5440, M5370, M6580;
Polyethylene HD (Phillips Chemical); Polyethylene HD (Union Carbide); Polyethylene HD (Barefoot)
Polyethylene HD DMDA 6200, 6220, 8907, 8920 NT7;
HDPE Brennlene 035-55BM;
Polyethylene HD LS 3420-000, 5060-00, 5140-00, 6060-00, 6080-00, 6601-00;
Polyethylene HD LR 7340-000;
Polyethylene HD HHM 5502BN, HMN 5580;
COL H.D.P.E. Pellets, Powder, (FDA Pellets, FDA Powder, LS 5140-00, H2104;
Polyethylene Low Density (LD); Linear Low-Density Polyethylene (LLDPE); Polyethylene LD NA 207-
000, 345-009, 496-196, 820-000, 860-008, 960-000, 043000;
LLDPE GA 574-000;
LDPE Pellets, (2MFI Foam), (2MFI), (20 MFI Injection), (70 MFI Injection), 2.0 / 0.92 Density;
LLDPE Dowlex 2517;
COL L.D.P.E. Powder, 20 Melt (Powder), 18DOA; COL Polyethylene LD NA 043000; COL Customer
LLDPE (EPI);
Petrothene LD NA 345-009, NA952000, NA951000;
AT190, 220;
Linear Medium Density Polyethylene (LMDPE);
Polyethylene HW AC 1702; Polyethylene Alathon 54-40; Alathon PE Resins (All Grades); AC 617A;
COL Licowax PE 520; COL Starplex Concentrate (5793);
COL Customer Resin 21198DC (Rescraft), 37398DC (Rescraft), Green 170991 (STARP);
Marlex Polyethylene (All Grades), Marlex HHM, HMN;
Polyethylene (Equistar).
Synonyms:
Thermoplastic Polyolefin. Polymers.
Chemical Family:
(-CH2-CH2-)x.
Molecular Formula:
Containers for gasoline, oil, solvents, acids, and other chemicals; films; utility and construction
sheeting; fibres; piping and tubing. Used in the manufacturing of extruded pipes. Melt processible
plastic resin for extrusion, blow, injection or rotational moulding. Mold release agents.
Product Use:
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
Not regulated.
Ingredient
CAS#
ACGIH TLV
% Concentration
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
Polyethylene (All Grades), Solid
Brenntag Canada Inc.
Date of Revision:
2009 March 23
WHMIS Number :
00062057
Page 2 of 9
4. FIRST AID MEASURES
3. HAZARDS IDENTIFICATION
At ambient temperatures: Mechanical hazard. Dust may cause mechanical irritation to skin, eyes and
respiratory tract. Powdered material may form explosive dust-air mixtures.
At elevated temperatures: Contact with molten material may cause severe thermal burns. High vapour
concentrations may cause drowsiness. See "Other Health Effects" Section. Can decompose at high
temperatures forming toxic gases.
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS
At ambient temperatures: Excessive contact with powder may cause drying of mucous membranes of
nose and throat due to absorption of moisture and oils.
At elevated temperatures: Prolonged exposure to processing fumes may cause eye and respiratory tract
irritation. Overexposure may cause headaches and nausea. Prolonged and repeated exposure may
cause pulmonary fibrosis. See "Other Health Effects" Section.
Inhalation:
At ambient temperatures: This product may cause irritation due to abrasive action. Product has a
tendency to cling to skin due to static charge. Care must be exercised to remove all product from skin.
(3)
At elevated temperatures: Burns (thermal) can occur if not promptly removed.
Skin Contact:
Not applicable.
Skin Absorption:
At ambient temperatures: This product may cause irritation, redness and possible damage due to
abrasiveness.
At elevated temperatures: Burns (thermal) can occur if not promptly removed. Vapours may cause
severe eye irritation.
Eye Contact:
Ingestion is not a likely route of exposure.
At ambient temperatures: Ingestion of large amounts may cause intestinal obstruction. Ingestion of large
amounts may cause nausea, gastrointestinal upset and abdominal pain.
At elevated temperatures: Burns (thermal) can occur if not promptly removed.
Ingestion:
Effects (irritancy) on the skin and eyes may be delayed, and damage may occur without the sensation or
onset of pain. Strict adherence to first aid measures following any exposure is essential.
At ambient temperatures, material is a coarsely divided solid and is inert and essentially harmless. It can
present a slippage hazard. Under normal processing conditions, the material is a hot, molten plastic.
Contact with hot molten plastics cause severe thermal burns to skin contact areas and eyes. The interior
of molten masses may remain hot for some time because of low thermal conductivity of the polymer.
Generally, it is recommended not to remove plastic that has hardened in contact with skin, but to cool it
by gently flooding the area with copious quantities of cool water. In all such cases, immediately seek
medical attention.
In general, long-term exposure to high concentrations of dust may cause increased mucous flow in the
nose and respiratory system airways. This condition usually disappears after exposure stops.
Controversy exists as to the role exposure to dust has in the development of chronic bronchitis
(inflammation of the air passages into the lungs). Other factors such as smoking and general air
pollution are more important, but dust exposure may contribute. (4)
May cause pneumoconiosis. Pneumoconiosis is the deposition of dust in the lungs and the tissue's
reaction to its presence. When exposure to the dust is severe or prolonged, the lungs' defenses are
overwhelmed. At elevated temperatures: High vapour concentration may cause central nervous system
(CNS) depression. CNS depression is characterized by headache, dizziness, drowsiness, nausea,
vomiting and incoordination. Severe overexposures may lead to coma and possible death due to
respiratory failure.
Other Health Effects:
Ethene, Homopolymer
9002-88-4

96 - 100
or

Polyethylene
26221-73-8

96 - 100
or

Polyethylene
25213-02-9

96 - 100
or

Polyethylene
25087-34-7

96 - 100

Additives

1 - 4
Polyethylene (All Grades), Solid
Brenntag Canada Inc.
Date of Revision:
2009 March 23
WHMIS Number :
00062057
Page 3 of 9
FIRST AID PROCEDURES
At ambient temperatures, material is a coarsely divided solid and is inert and essentially harmless. It can
present a slippage hazard. Under normal processing conditions, the material is a hot polymer. Contact
with hot molten materials cause severe burns to skin contact areas and eyes. Generally, it is
recommended not to remove material that has hardened in contact with skin, but to cool it by gently
flooding the area with copious quantities of cool water. In all such cases, immediately seek medical
attention.
General Guidelines:
Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Give cardiopulmonary
resuscitation (CPR) if there is no breathing AND no pulse. Obtain medical attention IMMEDIATELY.
Inhalation:
At ambient temperatures: Start flushing while removing contaminated clothing. Wash affected areas
thoroughly with soap and water. If irritation, redness, or a burning sensation develops and persists,
obtain medical advice.
At elevated temperatures: For thermal skin burns, remove clothing, any jewelry, and gross debris from
the burned area. Immediately flush the affected area with large amounts of water. Do not attempt to
peel polymer from skin. Leave the blisters intact. Cover the wounded area with gauze dressing
moistened with cool water; keep the dressing moist. Seek medical attention immediately. See "Note to
Physicians" below.
Skin Contact:
At normal temperatures: Immediately flush eyes with running water for a minimum of 20 minutes. Hold
eyelids open during flushing. If irritation persists, repeat flushing. Obtain medical attention
IMMEDIATELY.
At elevated temperatures: For thermal eye burns, remove any jewelry, and gross debris from the burned
area. Immediately flush the affected area with large amounts of water. Do not attempt to peel. Leave
the blisters intact. Cover the wounded area with gauze dressing moistened with cool water; keep the
dressing moist. Seek medical attention immediately. See "Note to Physicians" below.
Eye Contact:
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not convulsing,
rinse mouth out and give 1/2 to 1 glass of water to dilute material. DO NOT induce vomiting. If
spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing in of vomitus,
rinse mouth and administer more water. Obtain medical attention IMMEDIATELY.
Ingestion:
At ambient temperatures: Treat symptomatically.
At elevated temperatures: Treatment for thermal, surface burns:
1. Immerse the burned part immediately in ice water to relieve pain and to prevent swelling and
blistering. Place cold packs, ice or wet cloths on the burned area if immersion is not possible.
2. Remove anything that is constrictive, such as rings, bracelets or footwear, before swelling begins.
3. Cover the burn with a clean, preferably sterile, lint-free dressing.
4. For severe burns, immediately seek medical attention and monitor breathing and treat for shock.
Medical conditions that may be aggravated by exposure to this product include diseases of the skin,
eyes or respiratory tract.
Note to Physicians:
5. FIRE-FIGHTING MEASURES
Flashpoint (°C)
AutoIgnition
Temperature (°C)
LEL
UEL
Flammability Limits in Air (%):
260. (3)
330. (3)
Not available.
Not available.
Not regulated.
Flammability Class (WHMIS):
Above 177 °C: Thermal decomposition products are toxic and may include acetaldehyde, Acetone,
Acetic Acid, Formic Acid, hydrogen chloride, hydrocarbons and oxides of carbon and irritating gases.
Above 300 °C: Thermal decomposition products are toxic and may include formaldehyde and acrolein.
Hazardous Combustion
Products:
This product may be capable of forming flammable dust clouds in air. Minimize air borne spreading of
dust. Spilled material may cause floors and contact surfaces to become slippery. Spilled molten material
may be hot, but will solidify on cooling.
Most resins melt when they burn. Fire spread is accelerated by burning and dripping of flaming melt.
Once fire becomes established it will develop rapidly and application of large quantities of water at early
stage is necessary to effect extinguishment. (4)
Unusual Fire or Explosion
Hazards:
Not expected to be sensitive to mechanical impact.
Sensitivity to Mechanical Impact:
Not available.
Rate of Burning:
Polyethylene (All Grades), Solid
Brenntag Canada Inc.
Date of Revision:
2009 March 23
WHMIS Number :
00062057
Page 4 of 9
Not available.
Explosive Power:
High voltage static electricity build-up is possible when significant quantities of dust are present.
Sensitivity to Static Discharge:
EXTINGUISHING MEDIA
Foam. Dry chemical, carbon dioxide or water spray.
Fire Extinguishing Media:
FIRE FIGHTING
INSTRUCTIONS
Isolate materials that are not involved in the fire and protect personnel. Clean up immediately to
eliminate slipping hazard. Do not allow to enter sewers or watercourses. Avoid accumulation and
dispersion of dust to reduce explosion potential.
Instructions to the Fire Fighters:
Use self-contained breathing apparatus and protective clothing.
Fire Fighting Protective
Equipment:
6. ACCIDENTAL RELEASE MEASURES
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons,
property and the environment. There may be specific reporting requirements associated with spills, leaks or releases, which change from
region to region.
In all cases of leak or spill contact vendor at Emergency Number shown on the front page of this MSDS.
Avoid accumulation and dispersion of dust to reduce explosion potential. Wear respirator, protective
clothing and gloves. Avoid dry sweeping. Do not use compressed air to clean surfaces. Vacuuming or
wet sweeping is preferred. Return all material possible to container for proper disposal. Spilled material
may cause floors and contact surfaces to become slippery. Any recovered product can be used for the
usual purpose, depending on the extent and kind of contamination. Where a package (drum or bag) is
damaged and / or leaking, repair it, or place it into an over-pack drum immediately so as to avoid or
minimize material loss and contamination of surrounding environment. Replace damaged containers
immediately to avoid loss of material and contamination of surrounding atmosphere. Recover spilled
material on non-combustible absorbents, such as sand or vermiculite, and place in covered containers
for disposal. Use spark-resistant tools. Eliminate all sources of ignition. Collect product for recovery or
disposal. For release to land, or storm water runoff, contain discharge by constructing dykes or applying
inert absorbent; for release to water, utilize damming and/or water diversion to minimize the spread of
contamination. Ventilate enclosed spaces. Notify applicable government authority if release is
reportable or could adversely affect the environment.
In order to prevent marine species and birds from ingesting pellets, emphasis should be placed on total
containment of plastic pellets through their lifespan. This should be accomplished through rapid cleanup
of spills, providing appropriate containment systems to prevent pellet discharge from a facility, and
ensuring proper securement of pellets during shipping, return or disposal. Avoid contaminating soil or
releasing this material into sewage and drainage systems and bodies of water. (3)
Containment and Clean-Up
Procedures:
7. HANDLING AND STORAGE
HANDLING
Polyethylene (All Grades), Solid
Brenntag Canada Inc.
Date of Revision:
2009 March 23
WHMIS Number :
00062057
Page 5 of 9
Post signs warning of high temperatures (i.e. molten materials and hot equipment). This product may be
capable of forming flammable dust clouds in air. Minimize air borne spreading of dust. Ground and bond
equipment and containers to prevent a static charge buildup. Use spark-resistant tools and avoid
"splash-filling" of containers. Use normal "good" industrial hygiene and housekeeping practices. Clean
up immediately to eliminate slipping hazard. Spilled material may cause floors and contact surfaces to
become slippery.
Static neutralisers may be added when the powders are pneumatically conveyed. Pneumatic conveying
of this product can generate fines and dust particles that can, under certain conditions, pose an
explosion hazard. We recommend that the conveying system used be: (1) equipped with filters of
adequate size; (2) operated and maintained in such a manner to ensure that no leaks develop; and (3)
adequately grounded.
Provide adequate mechanical ventilation at the points of extrusion where the polymer is at elevated
temperatures coming from extruder into dies, molds etc. (3)
At ambient temperatures, material is a coarsely divided solid and is inert and essentially harmless. It can
present a slippage hazard. Under normal processing conditions, the material is a hot polymer. Contact
with hot molten materials cause severe burns to skin contact areas and eyes. Generally, it is
recommended not to remove material that has hardened in contact with skin, but to cool it by gently
flooding the area with copious quantities of cool water. In all such cases, immediately seek medical
attention.
In order to avoid autoignition / hazardous decomposition of hot thick masses of plastic, purging should
be collected in small, flat shapes or thin strands to allow for rapid cooling, followed immediately by a
quench in water. (3) Spilled molten material may be hot, but will solidify on cooling.
Handling Practices:
Provide adequate mechanical ventilation at the points of extrusion where the polymer is at elevated
temperatures coming from extruder into dies, molds etc. (3) The HVAC (heating, ventilation and air
conditioning system) must be regularly inspected and maintained to avoid contaminants build-up in air
filters. This build-up reduces the effectiveness of the ventilation. Volatile constituents of this product may
gradually degrade canvas, cloth or plastic components such as seals and flexible tube coverings of
adjustable point source ventilation equipment. Preventative programs should consider this. See Section
8, "Engineering Controls".
Ventilation Requirements:
Use only with adequate ventilation and avoid breathing dusts ( fumes or vapours ). Risk of spontaneous
ignition may arise if freshly manufactured material is not allowed to cool thoroughly before stacking in
bulk. (4) Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling.
Wash contaminated clothing thoroughly before re-use. Install non-slip surfaces around machinery and
equipment where spills may occur. Install drip pans. Provide duckboards or other non-slip footing in
frequently wet areas.
Avoid dry sweeping. Avoid air blowing.
Other Precautions:
STORAGE
The typical shelf life of this product is 5 years. (3)
Storage Temperature (°C):
Ventilation should be explosion proof.
Ventilation Requirements:
Store in a cool, dry and well-ventilated area. Keep away from heat, sparks and flames. Keep containers
closed. Avoid moisture contamination. Prolonged storage may result in lumping or caking. Do not
expose sealed containers to temperatures above 40 Deg. Celcius. Avoid direct sunlight. Protect against
physical damage.
Storage Requirements:
Materials of construction for storing the product include: Multi-layer polyethylene bags or sacks; fiber
drum. Confirm suitability of any material before using.
Special Materials to be Used for
Packaging or Containers:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this product.
Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective
devices at your workplace.
ENGINEERING CONTROLS
At ambient temperatures: Local exhaust ventilation required. Ventilation should be explosion proof. Make
up air should be supplied to balance air that is removed by local or general exhaust ventilation.
At elevated temperatures: Ventilate low lying areas such as sumps or pits where dense vapours may
collect.
Volatile constituents of this product may gradually degrade canvas, cloth or plastic components such as
seals and flexible tube coverings of adjustable point source ventilation equipment. Preventative
programs should consider this.
Engineering Controls:
Polyethylene (All Grades), Solid
Brenntag Canada Inc.
Date of Revision:
2009 March 23
WHMIS Number :
00062057
Page 6 of 9
PERSONAL PROTECTIVE
EQUIPMENT (PPE)
Contact lenses should not be worn when working with this material. At ambient temperatures: Safety
glasses with side shields are recommended to prevent eye contact. Use dust-tight chemical safety
goggles when there is potential for eye contact.
At elevated temperatures: Use full face-shield and chemical safety goggles when there is potential for
contact.
Eye Protection:
At ambient temperatures: Gloves and protective clothing made from nitrile rubber, cotton, canvas or
rubber or plastic should be impervious under conditions of use.
At elevated temperatures: Skin protection should be insulated against hot or high temperatures.
Skin Protection:
At ambient temperatures: A NIOSH/MSHA-approved air-purifying respirator equipped with high-efficiency
particulate filters cartridges for concentrations up to 100 mg/m³.
At elevated temperatures: A NIOSH/MSHA-approved air-purifying respirator equipped with dust, mist,
fume cartridges for concentrations up to 1 000 ppm. An air-supplied respirator if concentrations are
higher or unknown.
If while wearing a respiratory protection, you can smell, taste or otherwise detect anything unusual, or in
the case of a full facepiece respirator you experience eye irritation, leave the area immediately. Check to
make sure the respirator to face seal is still good. If it is, replace the filter, cartridge or canister. If the
seal is no longer good, you may need a new respirator. (4)
Respiratory Protection:
Wear regular work clothing. The use of coveralls is recommended. Locate safety shower and eyewash
station close to chemical handling area. Take all precautions to avoid personal contact.
Other Personal Protective
Equipment:
Particulate Not Otherwise Classified:
ACGIH OSHA
10 mg/m³ - Inhalable particulate 50 mppcf* or 15 mg/m³ - Total Dust
3 mg/m³ - Respirable particulate 15 mppcf* or 5 mg/m³ - Respirable Fraction
* mppcf = million particles per cubic foot
EXPOSURE GUIDELINES
Solid.
Transparent to opaque, colourless or white pellets, flakes, granules or powder. Pellets
are approximately 1/8 inches long. Also comes in an assortment of colours.
Hydrocarbon odour.
Not available.
Not applicable.
104 - 138. (3)
Not applicable.
Not applicable.
0.85 - 0.98. (3)
Not available.
650 mPa.s @ 140 C. (3)
Not available.
Insoluble in almost all solvents at room temperature; Soluble in many organic solvents
above 93 Degrees Celsius; May "swell" by absorption of solvents below 60 Degrees
Celsius. (4)
Negligible.
Not applicable.
Not applicable.
Not applicable.
Physical State:
Appearance:
Odour:
Odour Threshold (ppm):
Boiling Range (°C):
Melting/Freezing Point (°C):
Vapour Pressure (mm Hg at 20° C):
Vapour Density (Air = 1.0):
Relative Density (g/cc):
Bulk Density:
Viscosity:
Evaporation Rate (Butyl Acetate = 1.0):
Solubility:
% Volatile by Volume:
pH:
Coefficient of Water/Oil Distribution:
Volatile Organic Compounds (VOC):
9. PHYSICAL AND CHEMICAL PROPERTIES (Not intended as Specifications)
260. (3)
Flashpoint (°C):
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY
Stable.
Under Normal Conditions:
Not readily flammable, but will support combustion. This product may be capable of forming flammable
dust clouds in air.
Under Fire Conditions:
Polyethylene (All Grades), Solid
Brenntag Canada Inc.
Date of Revision:
2009 March 23
WHMIS Number :
00062057
Page 7 of 9
11. TOXICOLOGICAL INFORMATION
Meaningful toxicological test data could not be found for this product.
TOXICOLOGICAL DATA:
SUBSTANCE
LD50 (Oral, Rat)
LD50 (Dermal, Rabbit)
LC50 (Inhalation, Rat, 4h)
Ethene, Homopolymer
> 2 000 mg/kg (3)
---
---
Polyethylene
> 5 000 mg/kg (3)
> 2 000 mg/kg (3)
---
The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP.
Carcinogenicity Data:
No adverse reproductive effects are anticipated.
Reproductive Data:
No adverse mutagenic effects are anticipated.
Mutagenicity Data:
No adverse teratogenic effects are anticipated.
Teratogenicity Data:
None known.
Respiratory / Skin Sensitization
Data:
None known.
Synergistic Materials:
Acute oral doses of 7.95 g/Kg fed to rats showed no evidence of adverse effects. Dietary levels of 1.25,
2.5 or 5 percent Polyethylene (Ethene, Homopolymer) for 90 days produced no adverse effects in rats.
(3)
Pure polyethylene seems to be biologically inert and does not affect the body during normal exposure.
Solid polyethylene (films, prosthetic devices, contraceptive devices) may have non-specific "irritating
effects" when implanted into the body for prolonged periods which can cause malignant tumours at the
site of implantation. This process is called "solid state carcinogenesis." (4)
Some cases of dermatitis among workers heat-sealing polyethylene bags are possibly due to acrolein,
formaldehyde and other chemicals released during the operation. (4)
Polyethylene is considered non-toxic to animals by inhalation of the dust and ingestion of the solid. (4)
Inhalation of polyethylene dusts and thermal degradation products from polyethylene caused rats to
develop mild inflammatory changes in the lungs and neurological effects, respectively. (3) Carbon
Monoxide and heat are the principal hazardous agents. (4)
Other Studies Relevant to
Material:
12. ECOLOGICAL INFORMATION
Not available. Ecotoxicity is expected to be low based on the low water solubility. In the case of seabirds,
some marine biologists believe that ingestion of pellets by the fowl may cause intestinal blockage, false
feelings of satiation or reduction in absorption of nutrients, causing malnutrition and starvation. (3)
Ecotoxicity:
Not readily biodegradable. Low bioaccumulation potential. Do not contaminate domestic or irrigation
water supplies, lakes, streams, ponds, or rivers. In order to prevent marine species and birds from
ingesting pellets, emphasis should be placed on total containment of plastic pellets through their
lifespan. This should be accomplished through rapid cleanup of spills, providing appropriate
containment systems to prevent pellet discharge from a facility, and ensuring proper securement of
pellets during shipping, return or disposal. Avoid contaminating soil or releasing this material into
sewage and drainage systems and bodies of water. (3)
Environmental Fate:
Will not occur.
Hazardous Polymerization:
High temperatures, sparks, open flames and all other sources of ignition. Decomposes at temperatures
above 177 °C. Minimize air borne spreading of dust. Dust can explode violently above 390 Degrees
Celsius at airborne levels above 20 g/m³. (4) Clean up immediately to eliminate slipping hazard. Avoid
direct sunlight.
Conditions to Avoid:
Strong oxidizers. Strong acids. Alkalies. Fluorine Gas. Oxidizing agents. Nitrates. Nitric Acid. Chlorates.
Perchloric Acid. Peroxides. Halogens. Attacked by organic solvents such as benzene, petroleum ether,
gasoline, lubricating oils, chlorinated and aromatic hydrocarbons. (4) Solid material is softened by
hydrocarbons. (3)
Materials to Avoid:
Above 177 °C: Thermal decomposition products are toxic and may include acetaldehyde, Acetone,
Acetic Acid, Formic Acid, hydrogen chloride, hydrocarbons, oxides of carbon and irritating gases.
Above 300 °C: Thermal decomposition products are toxic and may include formaldehyde and acrolein.
Decomposition or Combustion
Products:
Polyethylene (All Grades), Solid
Brenntag Canada Inc.
Date of Revision:
2009 March 23
WHMIS Number :
00062057
Page 8 of 9
13. DISPOSAL CONSIDERATIONS
None required. See Section 6, "Containment and Clean-up Procedures".
Deactivating Chemicals:
This information applies to the material as manufactured. Reevaluation of the product may be required
by the user at the time of disposal since the product uses, transformations, mixtures and processes may
influence waste classification. Dispose of waste material at an approved (hazardous) waste
treatment/disposal facility in accordance with applicable local, provincial and federal regulations. Do not
dispose of waste with normal garbage, or to sewer systems.
Waste Disposal Methods:
See "Waste Disposal Methods".
Safe Handling of Residues:
Recycling is encouraged. Treat package in the same manner as the product. Dispose of waste material
at an approved waste incineration facility or landfill site in accordance with applicable local, provincial
and federal regulations.
Disposal of Packaging:
14. TRANSPORTATION INFORMATION
CANADIAN TDG ACT SHIPPING DESCRIPTION:
This product is not regulated by TDG.
Label(s): Not applicable. Placard: Not applicable.
ERAP Index: -----.
Exemptions: None known.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
This product is not regulated by DOT.
Label(s): Not applicable. Placard: Not applicable.
CERCLA-RQ: Not available.
Exemptions: None known.
15. REGULATORY INFORMATION
CANADA
All constituents of this product are included on the DSL.
CEPA - NSNR:
Not included.
CEPA - NPRI:
Controlled Products Regulations Classification (WHMIS):
16. OTHER INFORMATION
REFERENCES
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS
database.
1.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons, New
York, 1981.
2.
USA
All constituents of this product are included on the TSCA inventory.
Environmental Protection Act:
Not regulated.
OSHA HCS (29CFR 1910.1200):
Text22:
NFPA: 0 Health, 1 Fire, 0 Reactivity (3)
Text22:
HMIS: 0 Health, 2 Fire, 0 Reactivity (3)
INTERNATIONAL
Ethene, Homopolymer (9002-88-4) is found on the following inventories: EINECS (European Inventory of Existing Commercial Chemical
Substances), Australia (ACOIN), Korea (ECL), Philippines Inventory of Chemicals and Chemical Substances (PICCS), China Inventory
(IECS).
Polyethylene, High Density (25213-02-9) is found on the following inventories: Australia (ACOIN), China Inventory (IECS), EINECS
(European Inventory of Existing Commercial Chemical Substances), Japan (MITI), Korea (ECL), Philippines Inventory of Chemicals and
Chemical Substances (PICCS).
Not regulated.
Polyethylene (All Grades), Solid
Brenntag Canada Inc.
Date of Revision:
2009 March 23
WHMIS Number :
00062057
Page 9 of 9
Supplier's Material Safety Data Sheet(s).
3.
CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
4.
Guide to Occupational Exposure Values, 2007, American Conference of Governmental Industrial Hygienists, Cincinnati, 2007.
5.
Regulatory Affairs Group, Brenntag Canada Inc.
6.
The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical Association,
Ottawa, 1981.
7.
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The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith by
technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions of use and handling may involve
other and additional considerations. No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for any
damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained herein.
This Material Safety Data Sheet is valid for three years.
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To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia: 20333-102B Avenue, Langley, BC, V1M 3H1
Phone: (604) 513-9009 Facsimile: (604) 513-9010
Alberta: 6628 - 45 th. Street, Leduc, AB, T9E 7C9
Phone: (780) 986-4544 Facsimile: (780) 986-1070
Manitoba: 681 Plinquet Street, Winnipeg, MB, R2J 2X2
Phone: (204) 233-3416 Facsimile: (204) 233-7005
Ontario: 43 Jutland Road, Toronto, ON, M8Z 2G6
Phone: (416) 259-8231 Facsimile: (416) 259-5333
Quebec: 2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8
Phone: (514) 636-9230 Facsimile: (514) 636-0877
Atlantic: A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7
Phone: (902) 468-9690 Facsimile: (902) 468-3085
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Prepared By: Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.