EXOSET UNO A.pdf

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Material SECTION m respirable dust mg m respirable HAZARD Data
2 mg/m3
Acidic
SECTION II- HAZARDOUS INGREDIENTS
General
Chemical
Formula
Aluminum Phosphate
Graphite
Zirconium Silicate***
Fused Silica***
Amorphous Silica***
Cristobalite***
Ingredients (checked)
Quartz***
Material Safety Data Sheet
PLIBRICO COMPANY LLC
Refractory Engineers
1010 N. Hooker Street
Chicago, Illinois 60622
Phone: (312) 337-9000
Fax: (312) 337- 9003
SECTION I - MATERIAL IDENTIFICATION
Date:
Page 1 of 2
Percent
By Weight
TLV (ACGIH)
C.A.S. No.
Special Notes:  *** Greater amounts of Quartz and Cristobalite may be formed after firing.
                         Major portion of the crystalline silica present in the product as manufactured is not fine enough to
                         normally be considered respirable.
SECTION III- PHYSICAL DATA
4/17/2007
SECTION IV- FIRE AND EXPLOSION HAZARD DATA
C
1446446-1
69012-64-2
60676-86-0
14940-68-2
7782-42-5
7784-30-7
14808-60-7
SiO 2
SiO 2
SiO 2
SiO 2
ZrSiO4
2 mg/m   (respirable dust)
3
0.1 mg/m   (respirable dust)
3
5 mg/m3
2.5 mg/m3
SECTION V- REACTIVITY DATA
Chemical Name and Synonyms: High Temperature Cements
0.03
 
2.5
 
 
 
 
Chemical/Mineral Family:
Manufactureres Code I.D. : L -
Alumino Silicate
2960
Trade Name and Synonyms:
17436
Exo-set Uno A
Product Number:
85.3
2.7
%
%
SiO 2
Al   O
2
3
-
-
X
 
X
 
 
 
 
AlH  PO4
3
 
-
Stability:
Hazardous Polymerization:
Incompatibility:
N/A
Materials to avoid: N/A
Stable
May not occur
Hazardous Decomposition:
Silicon Carbide
409-21-2
 
SiC
10 mg/m  (respirable dust)
3
o
Improper mixing and bake-out of materials may result in steam spalling during initial heating.
                                       Refer to mixing instructions and bake-out schedules for proper procedures.
Unusual Fire and
Explosive Hazards:
 
Ceramic Fiber
142844-00-6
 
N/A
 
5 mg/m  (respirable dust),
15mg/m  (total),  0.5 fiber/ cc
3
3
 Boiling Point ( ):
 Solubility in Water:
 Appearance and Odor:
 Specific Gravity:
 Percent Volatile by Volume (%):
N/A
<15%
Granular aggregate & fine solid mix, off white in color
3.70
N/A
 pH:
0.025 mg/m   (respirable dust)
3
0.025 mg/m   (respirable dust)
3
SECTION VI- HEALTH HAZARD DATA
SECTION VII- SPILL OR LEAK PROCEDURES
SECTION VIII - SPECIAL PROTECTION INFORMATION
Exo-set Uno A
Primary Route of Entry: Inhalation, Ingestion, Skin Contact
Page 2 of 2
SECTION X - SPECIAL PRECAUTIONS
SECTION IX - TRANSPORT INFORMATION
Trade Name and Synonyms:
DOT Proper Shipping Name (29 CFR 172.101): Not Regulated
DOT Hazard Class (29 CFR 172.101): Not Regulated
UN/NA Code (49 CFR 172.101): Not applicable
DOT Labels Required (49 CFR 172.101): Not applicable
DOT Placards Required (49 CFR 172.504): Not applicable
Land Transport ADR/RID (cross-border): Not regulated
Maritime Transport IMDG: Not regulated
Air Transport ICAO-TI and IATA-DGR: Not regulated
Date:
4/17/2007
Effects of overexposure:
2. Chronic: Long term inhalation of respirable quartz, cristobalite, fused silica and/or amorphous silica may
    cause silicosis (delayed lung injury) and other respiratory disorders.
3. Prolonged contact with skin may cause irritation.
5. Canadian WHMIS : D2A
1. Acute: Exposure to nuisance dust may cause temporary irritation or discomfort to skin, eyes, nose, throat
    or lungs and may aggravate bronchial disorders.
4. IARC: sufficient evidence for the carcinogenicity of crystalline silca to humans. (Group 1)
Emergency and first aid procedures:
Rinse affected areas with water. For eye contact, flush with water and get medical attention
For excessive inhalation - remove to fresh air.
For skin contact - wash with soap and water.
If irritation persits, call a physician.
Steps to be taken in case material is released or spilled:
     Use routine housekeeping procedures, avoid dusting, collect material in closed containers or bags.
Waste Disposal Method:
     According to the EPA (40CFR 261.3) wastes are not hazardous wastes. Wastes may be disposed of in a landfill,
     however, in accordance with federal, state, and local regulations.
Ventilation:
     Local and Mechanical: follow OSHA STD 29 CFR 1910.94.
     Protection Gloves: Protective gloves recommended.
     Eye Protection: Safety glasses/goggles.
     Other Protective Equipment: As required to meet applicable OSHA standards.
Respiratory Protection:
     Good ventilation should be provided if dust is created when working with materials.  Used material, which is being
     removed, should be dampend to reduce dust.  In addition, when dust is present, workers should employ repirator
     protection.  Recommended: NIOSH approved respirator for dusts and mists, including silica, in compliance with
     OSHA STD 29.CFR1910.134.
Precautions to be taken in handling and storage:  To ensure product qualilty, store in a dry place.
     Additional Notes: The data provided herein is believed to be correct and is obtained from sources believed to be
reliable.  Plibrico Company shall not be liable for injury arising by either misuse of materials, or failure to follow safety 
procedures as outlined in the material safety data sheet.