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TRADE MSDS #1C Page 1 of 3 Material Safety Data Sheet MSDS: 0001C Status: Date Approved: 12/20/2002 Clairol, A Division of P&G One Blachley Road Stamford, CT 06922 Emergency Telephone Number: Transportation Emergency: (203) 357-5678 Call Chemtrec 1-800-424-9300 This sheet has been prepared in accordance with the Requirements of the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Section I - Categorization Category: Ammoniacal Oxidation (Permanent) Hair Colors, Flammable. Pertinent Text Oxidation Hair Colors contain low concentrations of dye intermediates in an aqueous base. They are mixed with the developer (hydrogen peroxide) before use. A separate MSDS exists for hydrogen peroxide. Product Names: Miss Clairol Professional, MC Max (except shades 2PR, 3R, 4PR and 6PR), Crème Toner, Summer Blonde, Complements Gel Color Permanent, Balsam Color, Nice n Easy, Beautiful Collection Permanent Section II - Ingredients Ammoniacal Oxidation (Permanent) Hair Colors, Flammable generally contain the following hazardous ingredients: CTFA NAME CAS# M-AMINOPHENOL 591275 N,N-BIS(2-HYDROXYETHYL)-P-PHENYLENEDIAMINE SULFATE 58262445 RESORCINOL 108463 P-PHENYLENEDIAMINE 106503 PROPYLENE GLYCOL 57556 AMMONIUM HYDROXIDE 1336216 ETHOXYDIGLYCOL 111900 ETHANOLAMINE 141435 NONOXYNOL-4 7311275 HEXYLENE GLYCOL 107415 OLEIC ACID 112801 SOYTRIMONIUM CHLORIDE 61790418 ISOPROPYL ALCOHOL 67630 NONOXYNOL-2 27176938 4-AMINO-2-HYDROXYTOLUENE 2835952 PEG-15 COCOPOLYAMINE 977159208 FRAGRANCE 999999999 STEARETH-21 977080811 OLEAMIDE MIPA 111057 POLYQUATERNIUM-22 53694170 CYCLOMETHICONE 69430246 OLETH-2 5274657 OLETH-10 24871349 POLYQUATERNIUM-6 26062793 C12-15 PARETH-3 98000085 P-AMINOPHENOL 123308 OLETH-5 5353275 DILINOLEIC ACID 6144281 TRADE MSDS #1C Page 2 of 3 Section II – Ingredients (continued) SOYTRIMONIUM CHLORIDE 61790418 COCAMIDOPROPYL BETAINE 61789400 1-NAPHTHOL 90153 TRISODIUM EHTYLENEDIAMINE DISUCCINATE 178949821 SODIUM LAURYL SULFATE 151213 STEARYL ALCOHOL 112925 OLEALKONIUM CHLORIDE 37139994 Section III - Physical/Chemical Characteristics Specific Gravity (H2O=1): 0.995 -1.009 pH: 9.5 - 10.8 Solubility in Water: Partly soluble. Appearance and Odor: Fragranced liquids. Ammoniacal odor. Section IV - Fire and Explosion Hazard Data Flashpoint: 75° to 120° Unit: Fahrenheit Type: For products containing alcohol. Method: closed cup Fire Fighting Procedures: Extinguish fires with ABC all-purpose extinguisher. The type of extinguisher used should be in conformance with local fire regulations. Fire fighters should use self contained breathing apparatus in enclosed areas. Unusual Fire and Explosion Hazards: Not applicable. Physical Hazards: According to OSHA, these products are considered to be flammable. Section V - Reactivity Data Stability: Stable. Conditions to Avoid: Heat and sunlight. Incompatibility (Materials to Avoid): Acids. Hazardous Decomposition or By Products: May form toxic materials (carbon dioxide, carbon monoxide and ammonia). Section VI - Health Hazards and Hazard Data The TLV of the mixture has not been established. 1. Effects of Acute Accidental Exposure Eye Contact: CAUTION. Unmixed oxidation hair colors are eye irritants. When oxidation hair colors are mixed with developers (hydrogen peroxide),the mixture may cause severe irritation and possible permanent eye injury. Skin Contact: May cause skin irritation or sensitization in sensitized individuals. Inhalation: Inhalation of ammonia vapors may result in respiratory irritation. Ingestion: Moderately toxic. 2. Effects of Chronic Exposure A composite mixture of oxidation dyes has been tested in prolonged topical exposure studies of laboratory animals. No adverse effects on growth, reproduction or general health were observed. In topical studies no target organ toxicity was observed other than limited effect on treated skin. 3. Carcinogen Status: OSHA: No NTP: No IARC: No 4. Route of Entry: Inhalation: Yes Ingestion: Yes Skin: Yes 5. Pre-existing dermatitis would likely be made worse by exposure to these products. TRADE MSDS #1C Page 3 of 3 Section VI - Health Hazards and Hazard Data 6. Emergency and First Aid Procedures Eye Contact: Remove contact lenses. Flush immediately with plenty of water for 15 minutes. Get medical attention IMMEDIATELY. Skin Contact: If spilled, wash skin immediately with soap and water (do not use solvents). Change into clean clothing. If skin irritation or sensitization develops, contact dermatologist. Inhalation: Remove person to fresh air. Increase ventilation. Ingestion: Rinse out mouth with water and administer large amounts of milk. Contact Poison Control Center. Section VII - Precautions for Safe Handling and Use Steps to be taken in Case Material is released or Spilled: Contain spill and promptly clean up. Flush with water and wipe with towel or rinse to drain. Floor can be slippery when wet. Waste Disposal Method: Products covered by this MSDS, in their original form, are considered non-hazardous waste according to RCRA (40 CFR 261.21(a) (1) ). Additionally, disposal should be in accordance with all applicable Local, State and Federal Regulations. Precautions to be Taken in Handling and Storage: Follow flammable liquid handling and storage requirements. Do not store any hair color after it has been mixed with developer. Decomposition of hydrogen peroxide may occur with increase in pressure and possible container rupture. Keep away from heat and other ignition sources. Section VIII - Control Measures Ventilation: Exhaust system ventilation should be adequate to avoid buildup of vapors. Hand Protection: Use impervious gloves to avoid possible skin irritation/sensitization. Eye Protection: Avoid contact with eyes. Use protective eyewear, if splashing is possible. Other Types of Protection: Not applicable. Respiratory Protection: Avoid inhalation. Work Hygienic Practices: Always follow good hygienic work practices. Avoid all skin, eye, and clothing contact with products. In case of contact, rinse thoroughly with water. Promptly clean up all spills. Section IX - Transportation Information DOT Class: Consumer Commodity ORM-D IMDG: Ethanol Solutions (Limited Quantity) 3.3 UN1170, PGIII (Flash Point: 880-920F) Oxidizing Solid N.O.S., 5.1, UN 1479, PG II or III. Limited Quantity applies only to the following products: Balsam Color 598, 599, Summer Blonde Lightener for Canada, and Nice ‘n Easy 87, 88, 89, 97, 97, 130, 101B, 103B, 106B, 114C, 166B, 118B, 118C, 120C, and 126C. IATA/ICAO: Consumer Commodity Class: 9, ID 8000 Packing Instruction 910. Not Authorized For Air Transportation applies only to the following products: Balsam Color 598, 599, Summer Blonde Lightener for Canada and Nice ‘n Easy 87, 88, 89, 97, 97, 130, 101B, 103B, 106B, 114C, 166B, 118B, 118C, 120C, and 126C.