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<p> WACKER E155 RELEASE AGENT PRODUCT DISTRIBUTED BY / PRODUIT DISTRIBUÉ PAR Brenntag Canada Inc. WHMIS Number: 00066194 43 Jutland Road. Index: HCI5334/07B Toronto, Ontario Effective Date: 2007 April 05 M8Z 2G6 Date of Revision: 2007 April 05 (416) 259-8231 Website: http://www.brenntag.ca _______________________________________________________________________________________________ EMERGENCY TELEPHONE NUMBERS / EN CAS D'URGENCE Toronto, ON (416) 226-6117 Montréal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827 Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036 _______________________________________________________________________________________________ This document consists of an English MSDS. Le présent document comprend une fiche signalétique en anglais. READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT. LIRE LA FICHE SIGNALÉTIQUE EN ENTIER POUR UNE ÉVALUATION COMPLÈTE DES DANGERS QUE REPRÉSENTE CE PRODUIT Material Safety Data Sheet Material: 70702235 E155 RELEASE AGENT Version: 1.11 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 1/10 1 Product and company identification 1.1 Identification of the substance or preparation: Commercial product name: E155 RELEASE AGENT Use of substance / preparation: Industrial. release agent . 1.2 Company/undertaking identification: Manufacturer/distributor: Wacker Chemical Corporation 3301 Sutton Road Adrian, MI 49221-9397 USA Customer information: Customer Care Center: Tel (517) 264-8240, Fax (517) 264-8740Hours of operation: Monday - Friday, 8 am to 5 pm (eastern standard time) Corporate website www.wackersilicones.com Emergency telephone no. (24h): (517) 264-8500 Transportation emergency: (800) 424-9300 (CHEMTREC, USA) (703) 527-3887 (CHEMTREC, international)(613) 996-6666 (CANUTEC, Canada) This MSDS was prepared by the Regulatory Affairs and Product Safety Department (RAPS) of Wacker Chemical Corporation. 2 Composition/information on ingredients 2.1 Chemical characterization (preparation): Chemical characteristics Polydimethylsiloxane + Polydimethylsiloxane with functional groups 2.2 Information on ingredients: Type CAS No. Substance Content [wt. %] Note Lower Upper INHA 67923-07-3 amino functional polydimethyl siloxane >=5.0 <=10.0 VERU 556-67-2 Octamethyl cyclotetrasiloxane >=0.1 <=1.0 R Type: HYD - by-product upon hydrolysis, INHA - ingredient, NEBE - by-product, MONO - residual monomer, VERU - impurity, VUL - by-product upon vulcanization. *** Note: C1 - IARC carcinogen, C2 - NTP carcinogen, C3 - OSHA carcinogen, NH - non-hazardous, R - reproductive toxin. Substances listed in the Subsections "HAPS" and "California Proposition 65 Carcinogens / Reproductive Toxins" that are not listed in Section 2 are only present at quantities below 0.1% for California Proposition 65 listed toxins or below 1% for non-carcinogenic HAPS or they are inextricably bound in the product. 3 Hazards identification 3.1 Hazards classifications HMIS® rating (product as packaged): Health: 2 Fire: 1 Reactivity: 0 PPE: G Material Safety Data Sheet Material: 70702235 E155 RELEASE AGENT Version: 1.11 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 2/10 Note: Respiratory protection is only recommended in the event that ventilation or engineering controls are unable to maintain exposures below recommended levels; or in the event of a spill or other emergency response situation. (HMIS codes are based on contact with the product as packaged and any hydrolysis by-products, if present.) Hazardous Materials Identification System and HMIS are registered trademarks of the National Paint and Coatings Association. Canadian WHMIS Classification: D2A, D2B 3.2 Emergency overview and potential hazards Signal Word: WARNING Physical Hazards: No known physical hazards. Acute health effects Route of entry or possible contact: eyes , skin , inhalation (aerosol) Eye contact: Causes eye irritation. Skin contact: Causes skin irritation. Inhalation: May cause lung damage if inhaled as an aerosol. Aerosol exposure may be hazardous to health based on animal studies. Inhalation caused reproductive effects in animals. See Sect. 3.3 "Chronic health effects". Mucous membrane contact: No known mucous membrane hazards. Ingestion: Small amounts of the liquid aspirated into the respiratory tract during ingestion or vomiting may cause damage to lungs. Additional information on acute health effects: Depending on method of application/use, exposure to hazardous ingredients may be possible. This hazard evaluation is based in part on toxicological testing of the material. This material can enter the lungs during swallowing or vomiting & cause lung inflammation and/or damage (aspiration hazard). 3.3 Further information: Chronic health effects: Prolonged or repeated inhalation of vapors may have adverse effects on the reproductive system, based on animal testing of a component of this material. Medical conditions which may be aggravated by exposure: Overexposure may cause or aggravate pre-existing lung conditions and diseases such as asthma, emphysema, silicosis, or cancer. Target organs affected: Lungs . Liver and Female Reproductive System. Signs and Symptoms of Exposure: Refer to Acute Health Effects, listed above. Carcinogens/Reproductive toxins: Based on animal tests. This material contains between 0.1% and 1% of a known reproductive toxin. This material contains >= 0.1% of a substance which may cause cancer. However, the relevance to humans has not been determined. See Section 11 for Toxicological Information, if any. Material Safety Data Sheet Material: 70702235 E155 RELEASE AGENT Version: 1.11 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 3/10 4 First-aid measures 4.1 General information: Get medical attention if irritation occurs or if breathing becomes difficult. Remove contaminated clothing and shoes. 4.2 After inhalation: If inhaled remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult give oxygen. 4.3 After contact with the skin: For skin contact, immediately wipe away excess material. Use a waterless hand cleaner to remove as much of the remaining material as possible. Wash with soap and water. 4.4 After contact with the eyes: If contact with eyes, immediately hold eyelids apart and flush with plenty of water for at least 15 min. 4.5 After swallowing: For ingestion, if conscious, give several glasses of water but do not induce vomiting. If vomiting does occur, give additional fluids. Danger of aspiration. 4.6 Advice for the physician: Treat symptomatically. 5 Fire-fighting measures 5.1 Flammable properties: Method Flash point..........................: 138 °C (280 °F) (ASTM D93) Boiling point / boiling range........: not determined Lower explosion limit (LEL)..........: not determined Upper explosion limit (UEL)..........: not determined Ignition temperature ................: not determined NFPA Hazard Class (comb./flam.liquid): IIIB 5.2 Fire and explosion hazards: Material supports combustion. This material does not present any unusual fire or explosion hazards. 5.3 Recommended extinguishing media: Dry chemical. Carbon dioxide. AFFF alcohol compatible foam. Water - Use Fine Spray or Fog. 5.4 Unsuitable extinguishing media: None. 5.5 Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases: Hazardous decomposition products: carbon dioxide , carbon monoxide , formaldehyde , silicon dioxide , nitrogen oxides and incompletely burnt hydrocarbons . 5.6 Fire fighting procedures: Fire fighters should wear full protective clothing including a self-contained breathing apparatus. Cool endangered containers with water. Material Safety Data Sheet Material: 70702235 E155 RELEASE AGENT Version: 1.11 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 4/10 6 Accidental release measures 6.1 Precautions: Wear personal protection equipment (see section 8). Keep unprotected persons away. Avoid contact with eyes and skin. Avoid inhaling mists and vapours. If material is released indicate risk of slipping. HAZWOPER PPE Level: C 6.2 Containment: Prevent material from entering surface waters, drains or sewers and soil. Contain any fluid that runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked containers. Spills of material which could reach surface waters must be reported to the United States Coast Guard National Response Center's toll free phone number (800) 424-8802. 6.3 Methods for cleaning up: Do not flush away with water. For small amounts: Absorb with a liquid binding material such as diatomaceous earth and dispose of according to local/state/federal regulations. Contain larger amounts and pump up into suitable containers. Clean any slippery coating that remains using a detergent / soap solution or another biodegradable cleaner. Exhaust vapours. 6.4 Further information: Eliminate all sources of ignition. 7 Handling and storage 7.1 Handling Precautions for safe handling: Avoid formation of aerosols. In case of aerosol formation special protective measures are required (exhausting by suction, respiratory protection). Ensure adequate ventilation. Keep away from incompatible substances in accordance with section 10.2. Spilled substance increases risk of slipping. Precautions against fire and explosion: Product can separate methanol. Vapours may form in closed rooms with air mixtures, leading to explosion in the presence of sources of ignition, even in empty, uncleaned vessels. Keep away from sources of ignition and do not smoke. Take precautionary measures against electrostatic charging. Cool endangered containers with water. 7.2 Storage Conditions for storage rooms and vessels: none known Advice for storage of incompatible materials: Avoid contact with acids. Further information for storage: Protect against moisture. Keep container tightly closed and store in a cool, well ventilated place. 8 Exposure controls and personal protection 8.1 Engineering controls Ventilation: General ventilation sufficient to provide 1 CFM per square foot of floor area or 6 room air exchanges per hour is recommended. Local exhaust: If spraying or other aerosol generating operations are performed, local exhaust ventilation designed to capture mists and sprays, such as a paint spray booth, is recommended. Material Safety Data Sheet Material: 70702235 E155 RELEASE AGENT Version: 1.11 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 5/10 8.2 Associate substances with specific control parameters such as limit values Further information: Maximum concentration at workplace recommended by producer: octamethylcyclotetrasiloxane (D4, CAS no. 556-67-2) = 10 ppm (123 mg/m3) 8.3 Personal protection equipment (PPE) Respiratory protection: If spraying or other operations which generate an aerosol mist are conducted, respiratory protection for exposed personnel is recommended. A NIOSH approved air purifying respirator equipped with universal multi-contaminant, multi-gas/vapor cartridges and at least P-99 solid/aerosol particulate filters is recommended if overexposure to dusts, mists, or vapors could occur. If eye-irritating dusts or vapors are present, a full-face respirator should be worn. Hand protection: butyl rubber protective gloves Eye protection: Safety glasses with side shields. Additional eye and face protection, splash-proof goggles, hood, full-faced respirator, or face shield is recommended if splashing could occur. Other protective clothing or equipment: Provide eye bath and safety shower. Additional skin protection, such as SARANEX coated Tyvek apron, over-sleeves, lab coat, coveralls, or protective suit should be worn if splashing could occur. 8.4 General hygiene and protection measures: Avoid contact with eyes, skin and clothing. Avoid breathing dust/vapor/mist/gas/aerosol. Wash thoroughly after handling. 9 Physical and chemical properties 9.1 Appearance Physical state / form................: liquid Colour...............................: clear Odour................................: weak, fishy, Garlic, onion 9.2 Safety parameters Method Melting point / melting range........: not determined Boiling point / boiling range........: not determined Flash point..........................: 138 °C (280 °F) (ASTM D93) Ignition temperature ................: not determined Lower explosion limit (LEL)..........: not determined Upper explosion limit (UEL)..........: not determined Vapour pressure......................: 0.177318 hPa Density..............................: 0.968 g/cm³ Water solubility / miscibility.......: insoluble pH-Value.............................: not determined Viscosity (dynamic)..................: not determined 9.3 Further information Percent Volatiles ...................: < 1 % VOC .................................: 0.648 g/l (calculated value) VOC Released During Cure.............: 19.4 g/l (Estimated Value) Material Safety Data Sheet Material: 70702235 E155 RELEASE AGENT Version: 1.11 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 6/10 10 Stability and reactivity 10.1 Conditions to avoid: moisture 10.2 Materials to avoid: Reacts with: water , basic substances and acids . Reaction causes the formation of: methanol . 10.3 Hazardous decomposition products: Methanol is released upon contact with water. (in small amounts) Measurements have shown the formation of small amounts of formaldehyde at temperatures above about 150 °C (302 °F) through oxidation. 10.4 Further information: Hazardous polymerization cannot occur. 11 Toxicological information 11.1 General information: Toxicological testing has been conducted with this material. 11.2 Toxicological data: Acute toxicity (LD50/LC50-values relevant to classification): Exposition Value/value range Species Source oral > 34600 mg/kg rat dermal > 10200 mg/kg rabbit by inhalation > 1.9 mg/l/4h (spray / dust) rat test report Primary irritation: Exposition Effect Species/Testsystem Source to skin mildly irritating rabbit to eyes mildly irritating rabbit Sensitization: Exposition Effect Test method Species Source to skin not sensitizing Skin Sensitization guinea-pig Reference points for mutagenic (carcinogenic) potential: Test system Effect Source Bacterial Reverse Mutation Test not mutagenic Additional information / remarks: Oral toxicity: Large oral doses (1600 mg/day for 14 days) of OMCTS/D4 caused an increase in the number of liver cells (hyperplasia) in laboratory rats. Ingestion of OMCTS/D4 is not expected in industrial use. Ingestion of methanol or methanol releasing compounds may result in delayed damage to the optic nerves, causing permanent blindness, and if untreated may cause other potentially fatal toxic effects. Inhalation toxicity: Two groups of five male and five female albino Sprague rats were exposed for 4 hours, using whole-body exposure methods to aerosol concentrations of 1.2 and 1.9 mg/l of Release Agent E155 (an amino-functional siloxane material). The maximum obtainable concentration was 1.9 mg/l. The 4-hour LC50 was considered to be greater than 1.9 mg/l. If concentrations higher than 1.9 mg/l could be generated and extrapolated upward from the two available datapoints, the 4-hour LC50 would be approximately 4 mg/l. No deaths occurred during testing at this exposure level. Since there were no mortalities an LD50 cannot be assigned, but it would have to be greater than the tested exposure. Material Safety Data Sheet Material: 70702235 E155 RELEASE AGENT Version: 1.11 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 7/10 Toxicity to reproduction/fertility: In a female rat gender-specific range finding study (inhalation exposure) with octamethylcyclotetrasiloxane (OMCTS/D4), decreases in mean live litter size and in the number of implantation sites were seen at the 700 ppm exposure level. In a two generation reproductive study with rats, decreased mean live litter size and prolonged labor (dystocia) were observed at the 500 and 700 ppm exposure levels. These same effects were not seen at the lower dose levels of 70 and 300 ppm. Previous inhalation developmental studies did not show birth defects at doses ranging up to 700 ppm in rats and 500 ppm in rabbits. The significance of these effects in humans can not be determined at this time. However, because these effects are only seen at very high exposure levels, it is unlikely that industrial, commercial and consumer uses of products containing OMCTS/D4 would result in a sign ificant risk to humans. In a two generation reproductive study via inhalation with OMCTS/D4 in rats, decreased mean live litter size and prolonged labor (dystocia) were observed at the 500 ppm and 700 ppm exposure levels. These same effects were not seen at the lower dose levels of 70 ppm and 300 ppm. Previous inhalation developmental studies did not show birth defects at doses ranging up to 700 ppm in rats and 500 ppm in rabbits. Because these effects are only seen at very high exposure levels, it is unlikely that industrial, commercial and/or consumer uses of products containing OMCTS/D4 would result in a significant risk to humans. Chronic toxicity / carcinogenicity: In a two year combined chronic toxicity and carcinogenicity inhalation study with octamethylcyclotetrasiloxane (OMCTS/D4) in rats, an increased incidence of (uterine) endometrial cell hyperplasia and endometrial adenomas were observed at the highest exposure level of 700 ppm in female rats. These same effects were not seen at the other dose levels of 10, 30, and 150 ppm. Since these effects only occurred at 700 ppm, a level that greatly exceeds typical workplace or consumer exposure, it is unlikely that industrial, commercial or consumer uses of products containing OMCTS/D4 would result in a significant risk to humans. Additional information / remarks: Inhalation toxicity: In a 90-day subchronic inhalation study with OMCTS/D4, female rats at the highest dose level of 300 ppm showed a reversible increase in liver and ovary weights. Rats exposed to inhalation concentrations of 5 ppm and 10 ppm, which are more typical of industrial exposure, did not show any toxic effects. Further studies in laboratory guinea pigs and rabbits have shown no liver effects due to D4 inhalation exposure. In a female rat gender-specific range finding study (inhalation exposure) with OMCTS/D4 decreases in mean live litter size and in the number of implantation sites were seen at the 700 ppm exposure level. Experience with man: - 12 Ecological information 12.1 Information on elimination (persistence and degradability) Biodegradation / further information: Biologically not degradable. Further information: Elimination by adsorption to activated sludge. 12.2 Behaviour in environmental compartments Mobility Absorbed by floating particles. Separation by sedimentation. Further information: Bioaccumulation is not expected to occur. 12.3 Ecotoxicological effects: No data known. Effects in sewage treatment plants (bacteria toxicity: respiration-/reproduction inhibition): According to current knowledge adverse effects on water purification plants are not expected. Material Safety Data Sheet Material: 70702235 E155 RELEASE AGENT Version: 1.11 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 8/10 12.4 Additional information Other harmful effects - General information: According to our present knowledge no further data known. 13 Disposal considerations 13.1 Product disposal Recommendation: Dispose of according to regulations by incineration in a special waste incinerator. Observe local/state/federal regulations. 13.2 Packaging diposal Recommendation: Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used. Observe local/state/federal regulations. 14 Transport information 14.1 US DOT & CANADA TDG SURFACE Valuation....................: Not regulated for transport Corrosive to Steel or Aluminum: Not corrosive to steel or aluminum. 14.2 Transport by sea IMDG-Code Valuation....................: Not regulated for transport 14.3 Air transport ICAO-TI/IATA-DGR Valuation....................: Not regulated for transport 15 Regulatory information 15.1 U.S. Federal regulations TSCA inventory status and TSCA information: This material or its components are listed on or are in compliance with the requirements of the TSCA Chemical Substance Inventory. TSCA 12(b) Export Notification: This material does not contain any TSCA 12(b) regulated chemicals. CERCLA Regulated Chemicals: This material does not contain any CERCLA regulated chemicals. SARA 302 EHS Chemicals: This material does not contain any SARA extremely hazardous substances. SARA 311/312 Hazard Class: Immediate (acute) health hazard. SARA 313 Chemicals: This material does not contain any SARA 313 chemicals above de minimus levels. HAPS (Hazardous Air Pollutants): 67-56-1 Methanol 15.2 U.S. State regulations California Proposition 65 Carcinogens: This material does not contain any chemicals known to the state of California to cause cancer. California Proposition 65 Reproductive Toxins: This material does not contain any chemicals known to the state of California to cause reproductive effects. Material Safety Data Sheet Material: 70702235 E155 RELEASE AGENT Version: 1.11 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 9/10 Massachusetts Substance List: This material contains no listed components. New Jersey Right-to-Know Hazardous Substance List: This material contains no listed components. Pennsylvania Right-to-Know Hazardous Substance List: This material contains no listed components. 15.3 Canadian regulations This product has been classified in accordance with the Hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS Hazard Classes: D2A, D2B DSL Status: This material or its components are listed on the Canadian Domestic Substances List. Canadian Ingredient Disclosure List: This material contains no listed components. 15.4 Other international regulations EU Risk Phrases: R-Phrase Description R- - EU Safety Phrases: S-Phrase Description S- - Details of international registration status Listed on or in accordance with the following inventories: IECSC - China TSCA - USA PICCS - Philippines ENCS - Japan ECL - Korea DSL - Canada AICS - Australia EINECS - Europe 16 Other information 16.1 Additional information: This Material Safety Data Sheet (MSDS) meets the requirements of the Federal OSHA Hazard Communication Standard (29 CFR 1910.1200). This product has been classified according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is to the best of our knowledge and belief accurate and reliable as of the date compiled. However, no representation, warranty or guarantee expressed or implied, is made as to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending a license under valid patents. This MSDS provides selected regulatory information on this product, including its components. This is not intended to include all regulations. It is the responsibility of the user to know and comply with all applicable rules, regulations and laws relating to the product being used. Material Safety Data Sheet Material: 70702235 E155 RELEASE AGENT Version: 1.11 (US) Date of print: 06/07/2007 Date of last alteration: 04/05/2007 Page: 10/10 Vertical lines in the left-hand margin indicate changes compared with the previous version. 16.2 Glossary of Terms: ACGIH - American Conference of Governmental Industrial Hygienists DOT - Department of Transportation hPa - Hectopascals mPa*s - Milli Pascal-Seconds OSHA - Occupational Safety and Health Administration PEL - Permissible Exposure Limit ppm - Parts per Million SARA - Superfund Amendments and Reauthorization Act STEL - Short Term Exposure Limit TSCA - Toxic Substances Control Act TWA - Time Weighted Average WHMIS - Canadian Workplace Hazardous Materials Identification System Flash point determination methods Common name ASTM D56 Tagliabue (Tag) closed cup ASTM D92, DIN 51376, ISO 2592 Cleveland open cup ASTM D93, DIN 51758, ISO 2719 Pensky-Martens closed cup ASTM D3278, DIN 55680, ISO 3679 Setaflash or Rapid closed cup DIN 51755 Abel-Pensky closed cup 16.3 Conversion table: Pressure: Viscosity: 1 hPa * 0.75 = 1 mm Hg = 1 Torr; 1 bar = 1000 hPa 1 mPa*s = 1 Centipoise (Cp) </p>
