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SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 02/24/2009 Date Updated: 02/23/2009 Version 1.4 Section 1 - Product and Company Information Product Name 1-ETHYL-2-(3-(1-ETHYLNAPHTHO-(1,2-D)- & Product Number E9379 Brand SIAL Company Sigma-Aldrich Canada, Ltd Address 2149 Winston Park Drive Oakville ON L6H 6J8 CA Technical Phone: 9058299500 Fax: 9058299292 Emergency Phone: 800-424-9300 Section 2 - Composition/Information on Ingredient Substance Name CAS # SARA 313 'STAINS-ALL'* 7423-31-6 No Formula C30H27N2S2.Br Section 3 - Hazards Identification EMERGENCY OVERVIEW Caution: Avoid contact and inhalation. HMIS RATING HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0 NFPA RATING HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0 For additional information on toxicity, please refer to Section 11. Section 4 - First Aid Measures ORAL EXPOSURE If swallowed, wash out mouth with water provided person is conscious. Call a physician. INHALATION EXPOSURE If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. DERMAL EXPOSURE In case of contact, immediately wash skin with soap and copious amounts of water. EYE EXPOSURE In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes. Section 5 - Fire Fighting Measures FLASH POINT N/A AUTOIGNITION TEMP N/A FLAMMABILITY N/A EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. FIREFIGHTING Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits toxic fumes under fire conditions. Section 6 - Accidental Release Measures PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear respirator, chemical safety goggles, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete. Section 7 - Handling and Storage HANDLING User Exposure: Use protective clothing, gloves, and mask. Avoid breathing dust. Avoid contact with eyes, skin, and clothing. STORAGE Suitable: Keep container closed. Store in a cool dry place. Store at 2-8°C SPECIAL REQUIREMENTS Light sensitive. Section 8 - Exposure Controls / PPE ENGINEERING CONTROLS Mechanical exhaust required. Safety shower and eye bath. PERSONAL PROTECTIVE EQUIPMENT Eye: Chemical safety goggles. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Wash contaminated clothing before reuse. Section 9 - Physical/Chemical Properties Appearance Color: Deep green Form: Powder SIAL - E9379 www.sigma-aldrich.com Page 2 Property Value At Temperature or Pressure Molecular Weight 559.6 AMU pH N/A BP/BP Range N/A MP/MP Range N/A Freezing Point N/A Vapor Pressure N/A Vapor Density N/A Saturated Vapor Conc. N/A SG/Density N/A Bulk Density N/A Odor Threshold N/A Volatile% N/A VOC Content N/A Water Content N/A Solvent Content N/A Evaporation Rate N/A Viscosity N/A Surface Tension N/A Partition Coefficient N/A Decomposition Temp. N/A Flash Point N/A Explosion Limits N/A Flammability N/A Autoignition Temp N/A Refractive Index N/A Optical Rotation N/A Miscellaneous Data N/A Solubility N/A N/A = not available Section 10 - Stability and Reactivity STABILITY Conditions of Instability: May discolor on exposure to light. Materials to Avoid: Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Nitrogen oxides, Sulfur oxides, Hydrogen bromide gas. Section 11 - Toxicological Information ROUTE OF EXPOSURE Skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Section 12 - Ecological Information No data available. Section 13 - Disposal Considerations SIAL - E9379 www.sigma-aldrich.com Page 3 APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations. Section 14 - Transport Information DOT Proper Shipping Name: None Non-Hazardous for Transport: This substance is considered to be non-hazardous for transport. IATA Non-Hazardous for Air Transport: Non-hazardous for air transport. Section 15 - Regulatory Information EU ADDITIONAL CLASSIFICATION S: 24/25 Safety Statements: Avoid contact with skin and eyes. US CLASSIFICATION AND LABEL TEXT US Statements: Caution: Avoid contact and inhalation. UNITED STATES REGULATORY INFORMATION SARA LISTED: No CANADA REGULATORY INFORMATION WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR. DSL: No NDSL: Yes Section 16 - Other Information DISCLAIMER For R&D use only. Not for drug, household or other uses. WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Inc., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Copyright 2009 Sigma-Aldrich Co. License granted to make unlimited paper copies for internal use only. SIAL - E9379 www.sigma-aldrich.com Page 4