Polybutene

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MSDS
155
<p>MATERIAL SAFETY DATA SHEET
POLYBUTENE (DAELIM), LIQUID
3. HAZARDS IDENTIFICATION
Low hazard for usual industrial or commercial handling. Can decompose at high temperatures forming 
toxic gases. Contents may develop pressure on prolonged exposure to heat.
EMERGENCY OVERVIEW:
POTENTIAL HEALTH EFFECTS
Vapour from warmed or heated material may cause nausea and dizziness. Exposure to aerosols or 
particulates from heated material may cause adverse lung effects if high concentrations are inhaled. 
See "Other Health Effects" Section.
Inhalation:
Prolonged, confined (especially under the finger nails, under rings or watch bands) or repeated 
exposure may cause skin irritation. May cause defatting, drying and cracking of the skin. Prolonged and 
repeated contact may lead to dermatitis. At processing temperatures :   Burns (thermal) can occur if not 
promptly removed.
Skin Contact:
Not likely to be absorbed through the skin.
Skin Absorption:
This product may cause mild, transient irritation. At processing temperatures :   This product causes 
immediate pain, severe burns and permanent corneal damage which may result in blindness.
Eye Contact:
This product may cause mild gastrointestinal discomfort.
Ingestion:
EMERGENCY TELEPHONE NUMBERS (FOR EMERGENCIES INVOLVING CHEMICAL SPILLS OR RELEASE)
Toronto, ON  (416) 226-6117                     Montreal, QC (514) 861-1211                     Winnipeg, MB (204) 943-8827
Edmonton, AB (780) 424-1754                  Calgary, AB  (403) 263-8660                       Vancouver, BC (604) 685-5036
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Brenntag Canada Inc.
43 Jutland Rd.
Toronto, ON
M8Z 2G6
(416) 259-8231
Website:  http:\\www.brenntag.ca
WHMIS#:
00065919
Index: 
2006 October 31
PRODUCT IDENTIFICATION
Polybutene (Daelim), Liquid.
Product Name:  
2006 October 31
Date of Revision:
Effective Date:
HCI5059/06D
Polybutene.
Chemical Name:
Polybutene PB1300; Butene, homopolymer; Butene, Polymers; Polybutylene.
Synonyms:
Polybutene.
Chemical Family:
(CH3)3-C-[CH2-(CH3)2-C-]n-CH=(CH3)2.
Molecular Formula:
Plasticizer in plastics, adhesives and coatings. Chemical intermediate. Additive for lubricants and paints.
Product Use:
WHMIS Classification / Symbol:
READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.
Not regulated.
Ingredient
CAS#
ACGIH TLV
% Concentration
2. COMPOSITION, INFORMATION ON INGREDIENTS (Not Intended As Specifications)
Polybutene
9003-29-6
--- 
100
Polybutene (Daelim), Liquid
Brenntag Canada Inc.
Date of Revision:
2006 October 31
WHMIS Number :
00065919
Page 2 of 7
4. FIRST AID MEASURES
FIRST AID PROCEDURES
If respiratory problems arise, move the victim to fresh air.  Give artificial respiration ONLY if breathing 
has stopped.  Give cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse.  Obtain 
medical advice IMMEDIATELY.
Inhalation:
Start flushing while removing contaminated clothing. Wash affected areas thoroughly with soap and 
water. If irritation, redness, or a burning sensation develops and persists, repeat flushing and obtain 
medical attention.
At processing temperatures :   Flush skin with running water for a minimum of 20 minutes.  Start 
flushing while removing contaminated clothing.  If irritation persists, repeat flushing.  Obtain medical 
attention IMMEDIATELY. For thermal skin burns, remove clothing, any jewelry, and gross debris from 
the burned area.  Immediately flush the affected area with large amounts of water.  Do not attempt to 
peel polymer from skin.  Leave the blisters intact.  Cover the wounded area with gauze dressing 
moistened with cool water; keep the dressing moist.  Seek medical attention immediately.
Skin Contact:
Immediately flush eyes thoroughly for 5 minutes with running water.  Hold eyelids open during flushing.  
If irritation persists, repeat flushing.  Obtain medical attention.
At processing temperatures :   Immediately flush eyes with running water for a minimum of 20 minutes.  
Hold eyelids open during flushing.  If irritation persists, repeat flushing.  Obtain medical attention 
IMMEDIATELY.
Eye Contact:
Do not attempt to give anything by mouth to an unconscious person. If victim is alert and not 
convulsing, rinse mouth out and give 1/2 to 1 glass of water to dilute material.  DO NOT induce 
vomiting.  If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing 
in of vomitus, rinse mouth and administer more water.  Obtain medical attention IMMEDIATELY.
Ingestion:
This product contains materials that may cause severe pneumonitis if aspirated.  If ingestion has 
occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to 
prevent aspiration.  Observe patient for respiratory difficulty from aspiration pneumonitis.  Give artificial 
resuscitation and appropriate chemotherapy if respiration is depressed.
At processing temperatures :   Treatment for thermal, surface burns:
1. Immerse the burned part immediately in ice water to relieve pain and to prevent swelling and 
blistering.  Place cold packs, ice or wet cloths on the burned area if immersion is not possible.
2. Remove anything that is constrictive, such as rings, bracelets or footwear, beforeswelling begins.
3. Cover the burn with a clean, preferably sterile, lint-free dressing.
4. For severe burns, immediately seek medical attention and monitor breathing andtreat for shock.
Medical conditions that may be aggravated by exposure to this product include diseases of the skin, 
eyes or respiratory tract.
Note to Physicians:
Effects (irritancy) on the skin and eyes may be delayed.  Strict adherence to first aid measures following 
any exposure is essential.
Other Health Effects:
5. FIRE-FIGHTING MEASURES
Flashpoint (°C)
AutoIgnition 
Temperature (°C)
LEL
UEL
Flammability Limits in Air (%):  
> 135  (3)
Not available.
Not available.
Not available.
Not regulated.
Flammability Class (WHMIS):
Thermal decomposition products are toxic and may include butene, oxides of carbon and irritating 
gases.
Hazardous Combustion 
Products:
Do not direct a solid stream of foam into hot, burning pools.  This may cause spattering and increase 
fire intensity. Closed containers exposed to heat may explode. Spilled material may cause floors and 
contact surfaces to become slippery.
Unusual Fire or Explosion 
Hazards:
Not expected to be sensitive to mechanical impact.
Sensitivity to Mechanical Impact:
Not available.
Rate of Burning:
Polybutene (Daelim), Liquid
Brenntag Canada Inc.
Date of Revision:
2006 October 31
WHMIS Number :
00065919
Page 3 of 7
Not available.
Explosive Power:
Not expected to be sensitive to static discharge.
Sensitivity to Static Discharge:
EXTINGUISHING MEDIA
Use carbon dioxide or dry chemical media for small fires.  If only water is available, use it in the form of 
a fog. Do not use high volume water jet.
Fire Extinguishing Media:
FIRE FIGHTING 
INSTRUCTIONS
Isolate materials that are not involved in the fire and protect personnel.  Cool containers with flooding 
quantities of water until well after the fire is out.
Instructions to the Fire Fighters:
Use self-contained breathing apparatus and protective clothing.
Fire Fighting Protective 
Equipment:
6. ACCIDENTAL RELEASE MEASURES
Information in this section is for responding to spills, leaks or releases in order to prevent or minimize the adverse effects on persons, 
property and the environment.  There may be specific reporting requirements associated with spills, leaks or releases, which change from 
region to region.
In all cases of leak or spill contact vendor at Emergency Number shown on the front page of this MSDS. 
Wear protective clothing. Collect product for recovery or disposal.  Ventilate enclosed spaces.  Notify 
applicable government authority if release is reportable or could adversely affect the environment.
Containment and Clean-Up 
Procedures:
7. HANDLING AND STORAGE
HANDLING
Use normal "good" industrial hygiene and housekeeping practices. Containers exposed to heat may be 
under internal pressure.  These should be cooled and carefully vented before opening.  A face shield 
and apron should be worn. Vent container frequently, and more often in warm weather, to relieve 
pressure.
Handling Practices:
See Section 8, "Engineering Controls".
Ventilation Requirements:
Use only with adequate ventilation and avoid breathing aerosols ( vapours or mists ). Avoid contact with 
eyes, skin or clothing.  Wash thoroughly with soap and water after handling.  Wash contaminated 
clothing thoroughly before re-use.
Other Precautions:
STORAGE
See below.
Storage Temperature (°C):
General exhaust is acceptable.
Ventilation Requirements:
Store in a cool, well-ventilated area.  Keep away from heat, sparks and flames.  Keep containers 
closed.  Do not expose sealed containers to temperatures above 40° C. A potentially flammable 
atmosphere may be generated if material is held hot for prolonged periods.
Storage Requirements:
Confirm suitability of any material before using.
Special Materials to be Used for 
Packaging or Containers:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Recommendations listed in this section indicate the type of equipment, which will provide protection against overexposure to this 
product.  Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific 
protective devices at your workplace.
ENGINEERING CONTROLS
General exhaust is acceptable. Local exhaust ventilation preferred. Make up air should be supplied to 
balance air that is removed by local or general exhaust ventilation. Ventilate low lying areas such as 
sumps or pits where dense vapours may collect.
Engineering Controls:
PERSONAL PROTECTIVE 
EQUIPMENT (PPE)
Safety glasses with side shields are recommended to prevent eye contact. Use chemical safety goggles 
when there is potential for eye contact. Contact lenses should not be worn when working with this 
material.
Eye Protection:
Polybutene (Daelim), Liquid
Brenntag Canada Inc.
Date of Revision:
2006 October 31
WHMIS Number :
00065919
Page 4 of 7
Gloves and protective clothing made from nitrile rubber should be impervious under conditions of use.   
Prior to use, user should confirm impermeability. Discard contaminated gloves. Skin protection should 
be insulated against hot or high temperatures.
Skin Protection:
No specific guidelines available. Respiratory protection should not be necessary unless the material is 
heated or a mist created. A NIOSH/MSHA-approved air-purifying respirator equipped with organic 
vapour cartridges for concentrations up to 1 000 ppm organic vapours. An air-supplied respirator if 
concentrations are higher or unknown.
Respiratory Protection:
Wear regular work clothing. The use of coveralls is recommended. Locate safety shower and eyewash 
station close to chemical handling area. Take all precautions to avoid personal contact.
Other Personal Protective 
Equipment:
None established for this product.
EXPOSURE GUIDELINES
Liquid.
Water-white liquid.
Mild odour.
Not available.
250 (decompose).
Not available.
Not available.
Not available.
0.85 - 0.92.
850 - 920 kg/m3
Not available.
Not available.
Not soluble in water.
Not available.
Not available.
Not available.
Not available.
Physical State:
Appearance:
Odour:
Odour Threshold (ppm):
Boiling Range (°C):
Melting/Freezing Point (°C):
Vapour Pressure (mm Hg at 20° C):
Vapour Density (Air = 1.0):
Relative Density (g/cc):
Bulk Density:
Viscosity:
Evaporation Rate (Butyl Acetate = 1.0):
Solubility:
% Volatile by Volume:
pH:
Coefficient of Water/Oil Distribution:
Volatile Organic Compounds (VOC):
9. PHYSICAL AND CHEMICAL PROPERTIES  (Not intended as Specifications)
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL DATA:
SUBSTANCE
LD50 (Oral, Rat)
LD50 (Dermal, Rabbit)
LC50 (Inhalation, Rat, 4h)
Polybutene
> 34 600 mg/kg (3)
> 10 250 mg/kg (3)
4 820 mg/m3 (3)
The ingredient(s) of this product is (are) not classed as carcinogenic by ACGIH, IARC, OSHA or NTP. 
See "Other Studies Relevant to Material".
Carcinogenicity Data:
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY
Stable.
Under Normal Conditions:
Not flammable.
Under Fire Conditions:
Will not occur.
Hazardous Polymerization:
High temperatures, sparks, open flames and all other sources of ignition.
Conditions to Avoid:
Strong oxidizers. Strong acids. Sulphuric Acid. Nitric Acid. Acidic Clays.
Materials to Avoid:
Thermal decomposition products are toxic and may include butene, oxides of carbon and irritating 
gases.
Decomposition or Combustion 
Products:
Polybutene (Daelim), Liquid
Brenntag Canada Inc.
Date of Revision:
2006 October 31
WHMIS Number :
00065919
Page 5 of 7
No adverse reproductive effects are anticipated.
Reproductive Data:
No adverse mutagenic effects are anticipated.
Mutagenicity Data:
No adverse teratogenic effects are anticipated.
Teratogenicity Data:
None known.
Respiratory / Skin Sensitization 
Data:
None known.
Synergistic Materials:
Polybutenes:  A range of similar materials have been tested for eye and skin irritation.  For eye irritation, 
none of these materials have produced scores exceeding 8.0 out of a possible total of 110 with 
complete disappearance of effects in 72 hour (rabbits).  Consequently, this material may be a slight eye 
irritant.  When applied to the skin of rabbits, similar materials scored 1.5 out of a possible total of 8.0, 
indicating that this product may be a slight skin irritant.  Similar materials were practically non-toxic 
when tested in acute oral, dermal and inhalation studies.  (3)
    Male Wistar rats were exposed to polybutene at concentration ranges of 65 to 72 or 692 to 743 
mg/M3, 7 hours a day, 5 days a week for 2 weeks.  Three of four rats exposed to the high concentration 
of polybutene died.  The major pathological finding was an increase in numbers of alveolar 
macrophages and increased macrophage vacuolation in the lungs of rats.  It was concluded that 
inhalation exposure to polybutene causes toxic effects in the lungs.  (4)
    An epoxidized polybutene was found to be non-mutagenic and non-toxic to the microorganisms used 
in the Ames mutagenicity assay, Salmonella typhimurium.  (3)
Other Studies Relevant to 
Material:
12. ECOLOGICAL INFORMATION
Polybutenes:
96-hour LC50 (Rainbow Trout)  = Above 10,000 mg/L (3)
96-hour LC50 (Fathead Minnow) = Above  1,000 mg/L (3)
    Polybutenes have very low solubility in water so aquatic studies refer to the amount of chemical 
added to the test system, not the amount dissolved in water.  Most acute aquatic toxicity studies have 
used the water-accommodated fraction, obtained by mixing the test chemical in water for 20 to 24 
hours, then siphoning the water for use in the test.  (3)
    Test of the freshwater invertebrate Daphnia magna suggest that these chemicals are not toxic, 
although globules of undissolved test material may trap individuals.  (3)
    Polybutenes are not expected to adversely affect microbial activity.  Following a modified OECD 
Method 209, bacterial inhibition using activated sludge microbes was tested with several grades of 
polybutenes.  The tests showed no bacterial inhibition at polybutene loadings of up to 25 mg/L, 
measured through oxygen consumption (respiration).  (3)
Ecotoxicity:
Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds, or rivers. 
Polybutenes:  In separate tests, the biological oxygen demand (BOD) of microorganisms was 
measured.  In these tests, there was no evidence of bacterial toxicity, even at loadings of polybutenes 
of about 200,000 mg/L.  For all grades of polybutene, BOD was small and it decreased with increasing 
polybutene chain length.  The reduced capacity of the microorganisms to decompose higher molecular 
weight polybutenes is probably due to the increased size of the polybutene molecules.  (3)  
    Polybutenes are not expected to be readily biodegradable, although test have not been conducted 
using current OECD or US EPA test methods.  Polybutenes are poorly soluble in water and many 
organic solvents, and their molecular size minimized bioavailablity.  The weight of evidence from toxicity 
tests, comparisons with structurally similar chemicals and professional judgment indicates that 
polybutenes are non-hazardous to the environment.  (3)
    Using the calculation method represented in the German Water Classification procedure, 
polybutenes have been assigned a WGK classification of zero.  This classification indicates that 
polybutenes are not water endangering.  (3)
Environmental Fate:
13. DISPOSAL CONSIDERATIONS
None required.
Deactivating Chemicals:
Polybutene (Daelim), Liquid
Brenntag Canada Inc.
Date of Revision:
2006 October 31
WHMIS Number :
00065919
Page 6 of 7
This information applies to the material as manufactured. Reevaluation of the product may be required 
by the user at the time of disposal since the product uses, transformations, mixtures and processes 
may influence waste classification. Dispose of waste material at an approved (hazardous) waste 
treatment/disposal facility in accordance with applicable local, provincial and federal regulations.  Do not 
dispose of waste with normal garbage, or to sewer systems.
Waste Disposal Methods:
See "Waste Disposal Methods".
Safe Handling of Residues:
Empty containers retain product residue. No special treatment required. Empty package may be 
disposed of with normal garbage.
Disposal of Packaging:
14. TRANSPORTATION INFORMATION
CANADIAN TDG ACT SHIPPING DESCRIPTION:
ELEVATED TEMPERATURE LIQUID, N.O.S. (Polybutene), Class 9, UN3257, PG III.
Label(s):  Miscellaneous Products, Substances or Organisms.          Placard:  Miscellaneous Products, Substances or Organisms.
ERAP Index: -----.
Exemptions: None known.
THIS MATERIAL IS NOT REGULATED BY TRANSPORT WHEN SHIPPED AT A TEMPERATURE LESS THAN 100 °C.
US DOT CLASSIFICATION (49CFR 172.101, 172.102):
ELEVATED TEMPERATURE LIQUID, N.O.S. (Polybutene), Class 9, UN3257, PG III.
Label(s):  Miscellaneous Hazardous Materials.          Placard:  Miscellaneous Hazardous Materials.
CERCLA-RQ: None known.
Exemptions: None known.
THIS MATERIAL IS NOT REGULATED BY TRANSPORT WHEN SHIPPED AT A TEMPERATURE LESS THAN 100 °C.
15. REGULATORY INFORMATION
CANADA
All constituents of this product are included on the DSL.
CEPA - NSNR:
Not included.
CEPA - NPRI:
Controlled Products Regulations Classification (WHMIS):
Not regulated.
USA
All constituents of this product are included on the TSCA inventory.
Environmental Protection Act:
Not regulated.
OSHA HCS (29CFR 1910.1200):
Text22:
NFPA:  0 Health,   1 Fire,   0 Reactivity   (8)
Text22:
HMIS:   Health,    Fire,    Reactivity   (Not available.)
INTERNATIONAL
Polybutene is found on the following inventories:   EINECS (European Inventory of Existing Commercial Chemical Substances), ACOIN 
(Australia), MITI (Japan) and Korea.
16.  OTHER INFORMATION
REFERENCES
RTECS-Registry of Toxic Effects of Chemical Substances, Canadian Centre for Occupational Health and Safety RTECS 
database.
1.
Clayton, G.D. and Clayton, F.E., Eds., Patty's Industrial Hygiene and Toxicology, 3rd ed., Vol. IIA,B,C, John Wiley and Sons, 
New York, 1981.
2.
Supplier's Material Safety Data Sheet(s)
3.
CHEMINFO, through "CCINFOdisc", Canadian Centre for Occupational Health and Safety, Hamilton, Ontario, Canada.
4.
Guide to Occupational Exposure Values, 2005, American Conference of Governmental Industrial Hygienists, Cincinnati, 2005.
5.
Regulatory Affairs Group, Brenntag Canada Inc.
6.
Polybutene (Daelim), Liquid
Brenntag Canada Inc.
Date of Revision:
2006 October 31
WHMIS Number :
00065919
Page 7 of 7
The British Columbia Drug and Poison Information Centre, Poison Managements Manual, Canadian Pharmaceutical 
Association, Ottawa, 1981.
7.
NFPA 325M Fire Hazard Properties of Flammable Liquids, Gases, and Volatile Solids, 1994 Edition, Quincy, MA, 1994.
8.
____________________________________________________________________________________________________________
The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith 
by technically knowledgeable personnel.  It is not intended to be all-inclusive and the manner and conditions of use and handling may 
involve other and additional considerations.  No warranty of any kind is given or implied and Brenntag Canada Inc. will not be liable for 
any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained 
herein.  This Material Safety Data Sheet is valid for three years.
____________________________________________________________________________________________________________
To obtain revised copies of this or other Material Safety Data Sheets, contact your nearest Brenntag Canada Regional office.
British Columbia:  20333-102B Avenue, Langley, BC, V1M 3H1
         Phone:  (604) 513-9009         Facsimile:  (604) 513-9010
Alberta:   6628 - 45 th. Street, Leduc, AB, T9E 7C9
         Phone:  (780) 986-4544         Facsimile:  (780) 986-1070
Manitoba:  681 Plinquet Street, Winnipeg, MB, R2J 2X2
         Phone:  (204) 233-3416         Facsimile:  (204) 233-7005
Ontario:  43 Jutland Road, Toronto, ON, M8Z 2G6
         Phone:  (416) 259-8231         Facsimile:  (416) 259-6175
Quebec:  2900 Jean Baptiste Des., Lachine, PQ, H8T 1C8
         Phone:  (514) 636-9230         Facsimile:  (514) 636-0877
Atlantic:  A-105 Akerley Boulevard, Dartmouth, NS, B3B 1R7
         Phone:  (902) 468-9690         Facsimile:  (902) 468-3085
____________________________________________________________________________________________________________
Prepared By:  Regulatory Affairs Group, Brenntag Canada Inc., (416) 259-8231.
</p>